• Title/Summary/Keyword: carbon Fibers

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Polyhydroxyamic Acid from 3,3′ - Dihydroxybenzidine and Pyromellitic Dianhydride as a Fire-safe Polymer

  • Park, Seung Koo;Farris, Richard J.;Kantor, Simon W.
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.83-88
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    • 2004
  • In order to assess the potential of the hydroxy-containing polyamic acid (PHAA) synthesized from 3,3'-dihydroxy benzidine and pyromellitic dianhydride for a fire-safe polymer, the cyclization pathway of PHAA has been investigated using a model compound prepared from 2-aminophenol and phthalic anhydride. The reaction was monitored. by $^1{H-nuclear}$ magnetic resonance. N-(2-hydroxyphenyl) phthalamic acid is converted to N-(2-hydroxyphenyl) phthalimide at ca. 175$^{\circ}C$, showing endothermic reaction. The imide structure is rearranged to the benzoxazole structure over ca. $400^{\circ}C$. These results are similar with that of PHAA. According to pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) data, water and carbon dioxide are released during the cyclization and rearrangement reaction. One DMAc molecule is complexed with one carboxyl acid group in PHAA, which accelerates the imidization process to release more easily the flame retardant, water.

Short-chain fatty acids, including acetate, propionate, and butyrate, elicit differential regulation of intracellular Ca2+ mobilization, expression of IL-6 and IL-8, and cell viability in gingival fibroblast cells

  • Kim, So Hui;Kim, Min Seuk
    • International Journal of Oral Biology
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    • v.45 no.2
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    • pp.64-69
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    • 2020
  • Short-chain fatty acids (SCFAs) such as acetate, propionate, and butyrate are secondary metabolites produced by anaerobic fermentation of dietary fibers in the intestine. Intestinal SCFAs exert various beneficial effects on intestinal homeostasis, including energy metabolism, autophagy, cell proliferation, immune reaction, and inflammation, whereas contradictory roles of SCFAs in the oral cavity have been reported. Herein, we found that low and high concentrations of SCFAs induce differential regulation of intracellular Ca2+ mobilization and expression of pro-inflammatory cytokines, such as interleukin (IL)-6 and IL-8, respectively, in gingival fibroblast cells. Additionally, cell viability was found to be differentially regulated in response to low and high concentrations of SCFAs. These findings demonstrate that the physiological functions of SCFAs in various cellular responses are more likely dependent on their local concentration.

Development of new heat dissipated material in metal core PCB for LED backlight source

  • Ban, K.Y.;Lee, D.Y.;Lee, M.J.;Han, C.J.;Han, J.I.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1432-1435
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    • 2006
  • We report on carbon nano-fibers (CNFs) for applying to epoxy as a highly thermal conductive adhesive. In order to fabricate CNFs, electro-spinning process was performed with polyacrylonitrile (PAN) solutions. The sample was stabilized at the annealing temperature of $360^{\circ}C$, and carbonized from 900 to $1100^{\circ}C$. It is shown that the synthesized CNFs have a good thermal conductivity of several hundred W/m K. LED backlight units (BLUs) fabricated with MPCB using CNF-mixed epoxy give a better heat dissipation and higher performance than normal LED BLUs. On the basis of SEM, XRD, and FTIR, the characteristics of CNFs are described.

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Thermal conductivity of PLA-bamboo fiber composites

  • Takagi, Hitoshi;Kako, Shuhei;Kusano, Koji;Ousaka, Akiharu
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.377-384
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    • 2007
  • 'Green' composites were fabricated from poly lactic acid (PLA) and bamboo fibers by using a conventional hot pressing method. The insulating properties of the PLA-bamboo fiber 'green' composites were evaluated by determination of the thermal conductivity, which was measured using a hot-wire method. The thermal conductivity values were compared with theoretical estimations. It was demonstrated that thermal conductivity of PLA-bamboo fiber 'green' composites is smaller than that of conventional composites, such as glass fiber reinforced plastics (GFRPs) and carbon fiber reinforced plastics (CFRPs). The thermal conductivity of PLA-bamboo fiber 'green' composites was significantly influenced by their density, and was in fair agreement with theoretical predictions based on Russell's model. The PLA-bamboo fiber composites have low thermal conductivity comparable with that of woods.

A Study on the Inspection of Orthotropy Composite Laminate plates Using Ultrasonics (직교이방성 복합적층판의 초음파 탐사에 관한 연구)

  • 나승우;임광희;양인영
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.583-586
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    • 2000
  • This work ethibits how susceptive the shear ultrasonic waves are to a little misoriented plies according to the angle variation of shear ultrasoic waves $0^\circ$ , $45^\circ$ and $90^\circ$. Also, it is shown that shear waves, particularly the transmission mode with the transmitter and receiver perpendicular to each other, have high sensitivity for detecting anomalies in fiber orientation and ply layup sequence that may occur in the manufacturing of composite laminates. Experimental results are agreed with modeling solutions which were based on decomposition of shear wave polarization vector as it propagates through the composite laminates. This wave appeared considerably to be sensitive to CFRP composites to the thickness direction along in-plane fibers.

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An Experimental Study on Shear Strengthening of Concrete Deep Beams with Glass Fiber Sheets (유리섬유보강재를 이용한 Deep Beam의 전단보강에 관한 실험적 연구)

  • Jo, Byoung-Wan;Kim, Young-Jin;Kim, Do
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.609-614
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    • 1997
  • Recently, many researchers have performed R&D about strengthening of R/C with steel plates, carbon fiber sheets. aramid fiber sheets and glass fiber sheets, and so on. However most of research were limited in study of flexural strengthening of R/C beams. This paper shows the results of an experimental study on shear reinforcement of deep beams using Glass Fiber Sheet in relation to shear-span ratio. strengthening orientation and anchorage. The results prove that shear failure is governed by reinforced orientation. adherence and anchorage. Additional anchorage of fibers does not only cause the improvement in the internal resistance, but also control the brittle shear failure of specimen after reaching the maximum load.

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The Improvement of Experimental Method of Textiles, Home Economics in High School (고등학교 가정과목의 피복재료 실험 방법 개선)

  • 유복현;이전숙
    • Journal of Korean Home Economics Education Association
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    • v.7 no.1
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    • pp.1-10
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    • 1995
  • This study was intended to provide an improved method for testing textiles in high school. Four kinds of test subjects were selected and applied to the classes. Problems of the methods in the textbooks were corrected as follows: 1)Burning test: The number of specimen is reduced to 3 kinds of fibers(cotton, wool, and polyester) and recommends are given to make result by comparing with the burning characteris-tics of paper and hair. 2) Absorbency test: Test Method is changed to drop test. The result is recorded by measuring time required for the water drops absorbed to the specimen. 3) Wrinkle recovery test: A glass is provided instead of metal weight. The method of measuring angle which is made by the specimen is shown in figure. 4) Effects of Detergent: 0.2% of detergent solution is provided before class. The amount of oil and carbon black is specified. Students have generally agreed that the improved methods were better than those in the text-books after they made the above 4 recommendable experiments(p<.001)

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Characteristics of high energy density hybrid capacitor using metal oxide electrode (금속산화물 전극을 사용한 고 에너지밀도 하이브리드 커패시터 특성)

  • Yoon, Hong-Jin;Shin, Yoon-Sung;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.329-334
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    • 2011
  • The electrochemical performances of an asymmetric hybrid capacitor were investigated using $LiFePO_4$ as the positive electrode and active carbon fibers(ACF) as the negative electrode. The electrochemical behaviors of a nonaqueous hybrid capacitor were characterized by constant current charge/discharge test. The specific capacitance using $LiFePO_4$/ACF electrode turned out to be $0.87F/cm^2$ and the unit cell showed excellent cycling performance. This hybrid capacitor was able to deliver a specific energy as high as 178 Wh/kg at a specific power of 1,068 W/kg.

Electrical Characterization of Electronic Materials Using FIB-assisted Nanomanipulators

  • Roh, Jae-Hong;You, Yil-Hwan;Ahn, Jae-Pyeong;Hwang, Jinha
    • Applied Microscopy
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    • v.42 no.4
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    • pp.223-227
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    • 2012
  • Focused Ion Beam (FIB) systems have incorporated versatile nanomanipulators with inherent sophisticated machining capability to characterize the electrical properties of highly miniature components of electronic devices. Carbon fibers were chosen as a model system to test the applicability of nanomanipulators to microscale electronic materials, with special emphasis on the direct current current-voltage characterizations in terms of electrode configuration. The presence of contact resistance affects the electrical characterization. This resistance originates from either i) the so-called "spreading resistance" due to the geometrical constriction near the electrode - material interface or ii) resistive surface layers. An appropriate electrode strategy is proposed herein for the use of FIB-based manipulators.

Fatigue damage detection of CFRP using the electrical resistance change method

  • Todoroki, Akira;Mizutani, Yoshihiro;Suzuki, Yoshiro;Haruyama, Daichi
    • International Journal of Aeronautical and Space Sciences
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    • v.14 no.4
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    • pp.350-355
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    • 2013
  • Electrical resistance change measurements were performed, to detect fatigue damage of a quasi-isotropic CFRP and cross-ply CFRP laminates. A four-probe method was used to measure the exact electrical resistance change. A three-probe method was used to measure the electrical contact resistance change, during long cyclic loading. The specimen side surface was observed using a video-microscope to detect damage. The measured electrical resistance changes were compared with the observed damage. The results of this study show that the electrical resistance increase of the quasi-isotropic laminate was caused by a delamination crack between ${\pm}45^{\circ}$ plies. Matrix cracking caused a small electrical resistance increase of the cross-ply laminate, but the decreased electrical resistance caused by the shear-plastic deformation impedes matrix-cracking detection.