• Structural Engineering and Mechanics
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• v.75 no.4
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• pp.455-464
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• 2020

Reinforcement corrosion is one of the major problems in the durability of reinforced concrete structures exposed to aggressive environments. Deterioration caused by reinforcement corrosion reduces the durability and the safety margin of concrete structures, causing excessive costs in managing these structures safely. This paper aims to investigate the effects of reinforcement corrosion on the load bearing capacity deterioration of the corroded reinforced concrete structures. A new analytical method is proposed to predict the crack growth of cover concrete and evaluate the residual strength of concrete structures with corroded reinforcement failing in bond. The structural performance indicators, such as concrete crack growth and flexural strength deterioration rate, are assumed to be a stochastic process for lifetime distribution modelling of structural performance deterioration over time during the life cycle. The Weibull life evolution model is employed for analysing lifetime reliability and estimating remaining useful life of the corroded concrete structures. The results for the worked example show that the proposed approach can provide a reliable method for lifetime performance assessment of the corroded reinforced concrete structures.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.4 no.2
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• pp.10-15
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• 2005

For the development of compensation machining program, ultra precision grinding used in ultra precision machine and corrective machining was studied. We explored a new rough grinding technique on optical material such as zerodur. The facility used is a polishing machine with a custom grinding module and a range of diamond resin bond wheel. Surface roughness and form accuracy are measured by surface measurement equipment(Form Talysurf series2). Our compensation machining program has complied with a target of producing surface roughness better than $0.05{\mu}m$ Ra and form accuracy of around $0.05{\mu}m$ Rt and has been unveiled as a work-hour model.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05a
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• pp.250-253
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• 2006

This paper presents experimental studies on investigating the seismic retrofit performance of reinforced concrete circular columns with poor lap-splice details using GFRP wrapping. Four 1/2 scale-down model columns have been tested. The as-built column is expected to suffer brittle failure due to the bond failure of lap-spliced longitudinal reinforcement. The retrofitted columns using GFRP wrapping showed significant improvement of seismic performance.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.772-775
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• 2006

Cinnamate polymers are well known photoreactive polymers due to [2+2] cycloaddition reaction of cinnamate side group. In this work, we have found that the cinnamate side groups could be also reacted by thermal energy, and this reaction is presumed to attribute to the radical reaction of carbon double bond in the cinnamate groups. Contrary to the photocycloaddition reaction of the cinnamate side groups, the thermal reaction of cinnamate side group was closely related to the flexibility of polymer backbone. The difference of the mechanism between the photocycloaddition reaction and thermal crosslinking reaction was confirmed by $^1H-NMR$$ and $^{13}C-NMR$ analysis of the model compound.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.451-454
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• 2011

The traditional BCS superconductors $AOs_2O_6$ (A=K, Rb, and Cs) were investigated to find the relationship between their structures and superconducting transition temperatures. The $T_c$ decreases with increasing the unit cell parameter of $AOs_2O_6$. This is in contrast to the case of conventional BCS superconductivity in a single bond model, where $T_c$ may increase with increasing the the unit cell parameter since the DOS at Fermi level increases as the unit cell parameter increases. Instead, the $T_c$ of a $\beta$-pyrochlore oxide is proportional to the lattice softness of the compound.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2301-2305
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• 2011

The potential energy surface (PES) for the loss of HCN or HNC from the pyrazine molecular ion was determined based on quantum chemical calculations using the G3//B3LYP method. Four possible dissociation pathways to form four $C_3H_3N^{+{{\bullet}}$ isomers were examined. A Rice-Ramsperger-Kassel-Marcus quasi-equilibrium theory model calculation was performed to predict the dissociation rate constant and the product branching ratio on the basis of the obtained PES. The resultant rate constant for the HCN loss agreed with the previous experimental result. The kinetic analysis predicted that the formation of $CH=CHN{\equiv}CH^{+{\bullet}}+HCN$ was predominant, which occurred by three consecutive steps, a C-C bond cleavage to form a linear intermediate, a rearrangement to form an H-bridged intermediate, and elimination of HCN.

• Journal of the Korean Chemical Society
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• v.64 no.2
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• pp.61-66
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• 2020

In this study, we investigate the structural and electronic properties of copper oxide clusters, Cu_nO_n (n = 9 - 15). To find the lowest energy structures of copper oxide clusters, we use ReaxFF and density functional theory calculations. We calculate many initial copper oxide clusters using ReaxFF quickly. Then we calculate the lowest energy structures of copper oxide clusters using B3LYP/LANL2DZ model chemistry. We examine the atomization energies per atom, average bond angles, Bader charges, ionization potentials, and electronic affinities of copper oxide clusters. In addition, the second difference in energies is investigated for relative energies of copper oxide clusters.

• Journal of Integrative Natural Science
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• v.8 no.2
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• pp.81-88
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• 2015

c-Jun N-terminal kinase-3 (JNK3) is a member of the mitogen-activated protein kinase family (MAPK), and plays an important role in neurological disorders. Therefore, identification of selective JNK3 inhibitor may contribute towards neuroprotection therapies. In this work, we performed hologram quantitative structure-activity relationship (HQSAR) on a series of thiophene trisubstituted derivatives. The best predictions were obtained for HQSAR model with $q^2=0.628$ and $r^2=0.986$. Statistical parameters from the generated QSAR models indicated the data is well fitted and have high predictive ability. HQSAR result showed that atom, bond and chirality descriptors play an important role in JNK3 activity and also shows that electronegative groups is highly favourble to enhance the biological activity. Our results could be useful to design novel and selective JNK3 inhibitors.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.175-178
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• 2007

The mode transition from cone-jet to dripping in colloid thruster operation has been analytically investigated. The transition has been predicted by the dynamic behavior of a liquid drop at the tip of the cone-jet. Conservation laws are applied to determine the upward motion of the drop, and an instability model of electrified jets is used to determine the jet breakup. Finally, for the first time, the analysis enables prediction of the transition in terms of the Weber number and electric Bond number. The predictions are in good agreement with experimental data.

• Proceedings of the KSR Conference
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• 2009.05a
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• pp.433-441
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• 2009

We have studied a weird phenomenon on the High Voltage Impulse Track Circuit (HVITC). The biggest problem is that can not recognize the fault states, despite the fact the rail is broken. This study has shown that current HVITC systems can be operated even an ill-contact state of impedance bond lead wire. This study was carried out using various methods, such as measurements using an oscilloscope with voltage and current probes, simulations using PSCAD/EMTDC software tool, and analysis of measured data. Especially, we have simulated the fault state through bypass circuits using PSCAD/EMTDC software tool. We made a model of track circuit and simulated various types of fault states.