• Title/Summary/Keyword: blending rate

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High-Rate Blended Cathode with Mixed Morphology for All-Solid-State Li-ion Batteries

  • Heo, Kookjin;Im, Jehong;Lee, Jeong-Seon;Jo, Jeonggeon;Kim, Seokhun;Kim, Jaekook;Lim, Jinsub
    • Journal of Electrochemical Science and Technology
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    • v.11 no.3
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    • pp.282-290
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    • 2020
  • In this article, we report the effect of blended cathode materials on the performance of all-solid-state lithium-ion batteries (ASLBs) with oxide-based organic/inorganic hybrid electrolytes. LiFePO4 material is good candidates as cathode material in PEO-based solid electrolytes because of their low operating potential of 3.4 V; however, LiFePO4 suffers from low electric conductivity and low Li ion diffusion rate across the LiFePO4/FePO4 interface. Particularly, monoclinic Li3V2(PO4)3 (LVP) is a well-known high-power-density cathode material due to its rapid ionic diffusion properties. Therefore, the structure, cycling stability, and rate performance of the blended LiFePO4/Li3V2(PO4)3 cathode material in ASLBs with oxidebased inorganic/organic-hybrid electrolytes are investigated by using powder X-ray diffraction analysis, field-emission scanning electron microscopy, Brunauer-Emmett-Teller sorption experiments, electrochemical impedance spectroscopy, and galvanostatic measurements.

Uptake and Recovery of Urea-15N Blended with Different Rates of Composted Manure (퇴비의 혼합 시비율에 따른 Urea-15N의 이용율 및 회수율)

  • Ro, Hee-Myong;Choi, Woo-Jung;Yun, Seok-In
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.6
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    • pp.376-383
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    • 2003
  • To utilize composts more efficiently, combining composts with fertilizer to meet crop requirements is an appealing alternative. A pot experiment was conducted to study the effect of application rate of composted pig manure blended with fertilizer on the availability and loss of fertilizer-N. Chinese cabbage (Brassica campestris L. cv. Samjin) plants were cultivated for 30 and 60 days. 15N-Labeled urea ($5.24\;^{15}N\;atom\;%$) was added to soil at $450mg\;N\;kg^{-1}$, and unlabeled compost ($0.37\;^{15}N\;atom\;%$) was added at 0, 200, 400, and $600mg\;N\;kg^{-1}$. The amount of plant-N derived from urea was not affected by compost application at rate of $200mg\;N\;kg^{-1}$. However, compost application at 400 and $600mg\;N\;kg^{-1}$ significantly (P<0.05) increased plant assimilation of N from urea irrespective of sampling time, probably because of physicochemical changes in the soil properties allowing urea-N to be assimilated more efficiently. The amount of immobilized urea-N increased with increasing rate of compost application at both growth periods, as the results of increased microbial activities using organic C in the compost. Total recovery of urea-N (as percentage of added N) by Chinese cabbage and soil also increased with increasing rate of compost from 71.5 to 95.6% and from 67.0 to 88.2% at the 30- and 60-days of growth, respectively. These results suggest that increasing rate of compost blending increases plant uptake of fertilizer-N and enhances immobilization of fertilizer-N, which leads to decrease in loss of fertilizer-N. However, information about the fate of immobilized N during future crop cultivation is necessary to verify long-term effect of compost blending.

Study on Algorithm of Micro Surface Roughness Measurement Using Laser Reflectance Light (레이저 반사광을 이용한 미세 표면 거칠기 측정 알고리즘에 관한 연구)

  • Choi, Gyu-Jong;Kim, Hwa-Young;Ahn, Jung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.4
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    • pp.347-353
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    • 2008
  • Reflected light can be decomposed into specular and diffuse components according to the light reflectance theory and experiments. The specular component appears in smooth surfaces mainly, while the diffuse one is visible in rough surfaces mostly. Therefore, each component can be used in forming their correlations to a surface roughness. However, they cannot represent the whole surface roughness seamlessly, because each formulation is merely validated in their available surface roughness regions. To solve this problem, new approaches to properly blend two light components in all regions are proposed in this paper. First is the weighting function method that a blending zone and rate can be flexibly adjusted, and second is the neural network method based on the learning from the measurement data. Simulations based on the light reflectance theory were conducted to examine its performance, and then experiments conducted to prove the enhancement of the measurement accuracy and reliability through the whole surface roughness regions.

Dyeing Properties of CDP Fiber (I) - Dyeing Properties and Color Fastness of CDP Fiber - (CDP 섬유의 염색성( I ) - CDP 섬유의 염색성 및 견뢰도 -)

  • Shin Woo Young;Jeong Dong Seok;Lee Mun Cheul
    • Textile Coloration and Finishing
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    • v.17 no.3 s.82
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    • pp.1-7
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    • 2005
  • Cationic dyeable polyester(CDP) was produced through melt blending of cationic chips having $2mol\%$ of sodium salt of dimethyl ester of 5-sulfoisophthalic acid(DMS salt) and normal polyester chips in different proportions to obtain yarns having varying amount of comonomer in the fiber. The modified polyesters showed increased moisture regain, decreased viscosity, lower softening point and improved antistatic characteristics, according to the amount of modifier. In dyeing at $100^{\circ}C$ the dyeing rate of cationic dyes with CDP fiber increased slowly than that of disperse dyes. In dyeing at $120^{\circ}C$ cationic dyes reached to equilibrium at 30min and disperse dyes at 10min. Cationic dyes in dyeing of CDP fabric have a better wash fastness compared with disperse dyes, also rubbing fastness of cationic dyes is better than that of disperse dyes. The light fastness of CDP fabric for cationic and disperse dyes is not good. The fastness of 75d/36f CDP fabric is higher than 75d/72f fabric. Solvent wicking fastness of CDP with cationic dyes is better than that of disperse dyes.

The Effect of MBS on the Compatibility of Scrap PVB/PMMA Blends (Scrap PVB/PMMA 블렌드에 미치는 MBS의 상용화효과(相溶化效果))

  • Choi, Hyeong-Ki;Lee, Yong-Moo;Yoon, Ju-Ho;Choi, Sei-Young
    • Elastomers and Composites
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    • v.31 no.1
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    • pp.23-32
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    • 1996
  • PVB was blended with PMMA in order to recycle scraped PVB material which recovered in the safety glass manufactories. The purpose of this research on PVB/PMMA blend was applied with excellent tackiness and transparency of PVB as a material of high strength to make the maximum use. Also, the blending of PVB with PMMA was aimed at the increase of impact strength of PMMA because the elastic property of PVB might decrease the brittleness of PMMA due to the lack of inner impact resistance. Izod impact resistance was propotional to increase the content of PVB, which was predominantly increased in the addition of 10phr above MBS. High rate impact resistance showed a tendency to Increase but it showed a tendency to decrease maximum load and energy if the contents of PVB increased. On the other hand total energy and ductile index showed a tendency to increase excellent impact resistance in the addition of MBS contents. As a result of observed surface of PVB/PMMA blends, the size of PVB domain increased distribution homogenuously, in the addited MBS contents increased it showed distribution homogeneously and partially a wetability.

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Shrink-Resist Effects and Properties of the Knitted Fabrics from Wool/Acrylic Fiber Blends (양모/아크릴 혼방사 편성물의 방축 효과 및 물성에 관한 연구)

  • Lee Youn-Hee;Kwak Soo Kyoung;Park Myung-Ja
    • The Research Journal of the Costume Culture
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    • v.12 no.6 s.53
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    • pp.945-952
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    • 2004
  • Shrink-resist effects and properties of the knitted fabrics from wool/acrylic(W/A) fiber blends were determined to find out an optimal blending ratio keeping the quality properties of wool products. The test fabrics were knitted by a weft knitting machine with all needle knitting structure ($0{\times}0$ rib) under the same knitting conditions with five different types of yarns: $W100\%,\;A100\%$, and W/A blended yarns(70/30, 50/50, 30/70). Shrinkage during repeated washing, electrostatic propensity, thermal resistance and pilling propensity of W/A knits. The shrink resistance was significantly enhanced on repeated washing of W/A knits, especially, over $50\%$ acrylic blended knits. Addition of strong physical force and alkali detergent applied in this washing experiment brought about superior effects with the low shrinkage rate although it was very severe washing conditions for wool fabrics. The results from the washing experiment implies that W/A blend knits can be machine washed at individual households with other ordinary laundry. There was some changes and variation found in thermal resistance, electrostatic propensity, and pilling. W/A 50/50 blended knits did not bring serious changes to other physical properties comparing with original wool, which helps consumers care wool knitted clothes more conveniently.

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Preparation and Characterization of Acidic Degreasing Agents for Aluminum (알루미늄용 산성탈지제의 제조 및 탈지특성)

  • Chung, Dong-Jin;Park, Hyong-Jin;Kim, Sung-Rae;Jung, Choong-Ho;Wu, Jong-Pyo;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.1
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    • pp.20-26
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    • 2003
  • Acidic degreasing agent(AADA) was prepared by blending sorbitol, Newpol PE-68, Na-dioctyl sulfosuccinate, Tetronix T-70l, MJU-100A, n-octanoic acid, and phosphoric acid, The physical properties of AADA tested with aluminum specimen showed the following results ; when 3wt% AADA-5 was performed at 70$^{\circ}C$, the degreasing rate was 95% which is comparitively good, and the percentage of etching was 0.277% which was found to be less than that of commercialized product. when 20wt% of AADA-5 was added at 65$^{\circ}C$, the percentage of derusting was 91% and the good defoaming effect proved by following low foaming power tests respectively : Ross and Miles, and Ross and Clark methods.

Effect of Forced Fermentation on Chemical and Sensory Properties in Burley Leaf Tobacco (속성발효가 버어리종 잎담배의 화학성분과 끽미에 미치는 영향)

  • 정기택;안대진;이종률;배성국
    • Journal of the Korean Society of Tobacco Science
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    • v.24 no.1
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    • pp.21-26
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    • 2002
  • This study was carried out to evaluate the effect of forced fermentation on chemical and sensory properties in burley leaf tobacco. Three process steps of burley leaf tobacco(green and redried leaves produced in 2000, and aged leaves in 1998) and four grades(BlT, B2T, C1W and C2W) of leaf for every step were used in this study. The leaves were moistened by 22% moisture content, packed under 200kg/㎥ condition and stored in chamber controlled 6$0^{\circ}C$ and 90% R.H. for 7 days. Nicotine contents in three steps of burley leaf tobacco were significantly decreased by forced fermentation. Except for aged leaf, pH values of green and redried leaves were significantly lowered. Nicotine, tar and CO contents of cigarette smoke showed little difference between cigarettes containing 23%, 26% and 29% of fermented burley leaf and controlled cigarette(containing 19% of aged burley leaf). The cigarette containing 26% of the redried and fermented leaf was significantly better taste and less irritation than controlled cigarette. The results suggest that the forced fermentation may be useful to increase the rate of burley tobacco in leaf blending and to shorten the period of storage for aging.

Effect of Changes of Bubble-based Leavening Agent and Bubble Mixing Ratio on Quality of Lightweight Concrete (기포계팽창재 및 기포혼입율 변화가 경량기포 콘크리트의 품질에 미치는 영향)

  • Kim, Min-Sang;Cha, Cheon-Soo;Park, Do-Yeong;Park, Yong-Kyu;Kim, Hyun-Woo;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.189-190
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    • 2016
  • Lightweight concrete is currently used at apartment buildings or housing construction sites causes some uneconomical problems due to excessive cracks and subsidences. So, it is in the situation that it is necessary to set up countermeasures against such subsidences. Therefore, in this study, it is intended to analyze the prevention of a subsidence inducing the expansion of the aluminum components depending on the changes of substitution rate and bubble mixing ratio by using the bubble-based Leavening Agent that Aluminum slag as an industrial by-product is substituted into some desulfurized plaster. As the results, it was found that the blending ratios, such as, the substitution ratio of bubble-based leavening agent (1%) and the bubble mixing ratio (65%) are appropriate while the flow property, subsidence depth and compression strength are considered.

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Cure Kinetics of amine-cured tetraglycidyl-4,4'-diaminodiphenylmethane epoxy blends with a new polyetherimide (반응성 열가소성 수지로 개질된 TGDDM/DDS 시스템의 Cure Kinetics)

  • Hwang Seungchul;Lee JungHoon;Kim Donghyon;Kim Woho;Kim Minyoung
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.214-217
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    • 2004
  • The cure kinetics of blends of epoxy(tetraglycidyl-4,4'-diaminodiphenylmethane ; TGDDM)/curing agent(diaminodiphenyl sulfone ; DDS) resin with amine terminated polyetherimide-CTBN-amine terminated polyetherimide triblock copolymer(ABA) were studied using differential scanning calorimetry under isothermal conditions to determine the reaction parameters such as activation energy and reaction constants. By increasing the amount of ABA in the blends, the final cure conversion was decreased. Lower values of the final cure conversions in the epoxy/ABA blends indicated that ABA hinders the cure reaction between the epoxy and curing agents. 1be value of the reaction order, m, for the initial autocatlytic reaction was not affected by blending ABA with epoxy resin, and the value was approximately 1.0. The value of n for the nth order component in the autocatalytic analysis was increased by increasing the amount of ABA in the blends, and the value increased from 2.0-3.4. A diffusion controlled reaction was observed as the cure conversion increased and the rate equation was successfully analyzed by incorporating the diffusion control term for the epoxy/DDS/ABA blends.

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