• 제목/요약/키워드: analytical methods

검색결과 3,062건 처리시간 0.036초

식품중의 Aflatoxins - 분석방법 및 이화학적 반응을 통한 저감화를 중심으로 - (Aflatoxins in Foods - Analytical methods and Reduction of Toxicity by Physicochemical Processes -)

  • 황준호;전향숙;이광근
    • Applied Biological Chemistry
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    • 제47권1호
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    • pp.1-16
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    • 2004
  • 이 논문에서는 식품 또는 식품원료 중의 aflatoxin에 관한 오염현황, 최신 분석법 그리고 저감화 시킬 수 있는 방안에 대해 조명하였다. Aflatoxin은 여러 곰팡이가 생성하는 2차 대사산물로서 곰팡이 독소 중 가장 독성이 강한 것으로 알려져 있다. 발암성을 포함한 독성 관계로 aflatoxin은 인간의 건강 측면 뿐 아니라 식품을 포함한 산업전반에 경제적으로 큰 영향을 끼치고 있다. 우리나라와 같은 식량 수입국에서는 식품의 안전성 확보를 위해 노출량 조사, 위해평가 및 관리가 체계적으로 이루어져야 하며 아울러 새로운 aflatoxin 분석 기술의 개발과 독성 저감화 기술의 개발이 병행되어야 한다고 판단된다.

대단면터널 특성을 고려한 지보설계 개선방안 연구 (Large-span Tunnel Support Design supplemented by Analytical Methods)

  • 정재호;이희석;허종석;윤상길
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2006년도 춘계 학술발표회 논문집
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    • pp.949-959
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    • 2006
  • Despite of the popularity of using empirical methods for support design, empirical rules suffer from the inherent problem of providing no indication of the safety degree of the design. For the support design of large span tunnel, it was considered that the empirical design guidelines should be augmented by more explicit design methods. This paper presents an overview of the analytical support design methodology that is used to refine initial empirical recommendations. The initial support design supplemented by analytical methods is validated by probabilistic and deterministic approach applied to stress-induced and structurally controlled gravity-driven instability problem each. As a result, the extent of the potential failure zone is sorted out and numerical parametric studies were performed to gain insight into the overall behavior of tunnel in the potential failure zone. Concequently, it was decided that additional conservation techniques have to be planed as a reserved support pattern.

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쇄빙시뮬레이션을 위한 반해석적 빙하중 계산법 고찰 (Study on the Semi-Analytical Ice Load Calculation Methods for the Ice-Breaking Simulation)

  • 김정환;장범선;김유일
    • 대한조선학회논문집
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    • 제57권6호
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    • pp.353-364
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    • 2020
  • This paper presents the semi-analytical ice load calculation methods that are useful to simulate the ice-breaking process. Since the semi-analytical methods rely on the previously developed closed form equations or numerical analysis results, the user's exact understanding for the equations must be supported in order to use the methods properly. In this study, various failure modes of ice such as local crushing, in-plane splitting failure, out-of-plane bending failure and radial or circumferential cracking with rotation of the broken ice floe are considered. Based on the presented methods, the fracture modes were evaluated according to the size and thickness of ice. In addition, time series analysis for the ice-breaking process was performed on several ice conditions and the results were analyzed.

Analysis of Zirconium and Nickel Based Alloys and Zirconium Oxides by Relative and Internal Monostandard Neutron Activation Analysis Methods

  • Shinde, Amol D.;Acharya, Raghunath;Reddy, Annareddy V.R.
    • Nuclear Engineering and Technology
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    • 제49권3호
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    • pp.562-568
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    • 2017
  • Background: The chemical characterization of metallic alloys and oxides is conventionally carried out by wet chemical analytical methods and/or instrumental methods. Instrumental neutron activation analysis (INAA) is capable of analyzing samples nondestructively. As a part of a chemical quality control exercise, Zircaloys 2 and 4, nimonic alloy, and zirconium oxide samples were analyzed by two INAA methods. The samples of alloys and oxides were also analyzed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and direct current Arc OES methods, respectively, for quality assurance purposes. The samples are important in various fields including nuclear technology. Methods: Samples were neutron irradiated using nuclear reactors, and the radioactive assay was carried out using high-resolution gamma-ray spectrometry. Major to trace mass fractions were determined using both relative and internal monostandard (IM) NAA methods as well as OES methods. Results: In the case of alloys, compositional analyses as well as concentrations of some trace elements were determined, whereas in the case of zirconium oxides, six trace elements were determined. For method validation, British Chemical Standard (BCS)-certified reference material 310/1 (a nimonic alloy) was analyzed using both relative INAA and IM-NAA methods. Conclusion: The results showed that IM-NAA and relative INAA methods can be used for nondestructive chemical quality control of alloys and oxide samples.

Analytical Studies for SASW Measurements Underwater

  • Lee, Byung-Sik
    • 한국지반공학회지:지반
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    • 제13권3호
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    • pp.53-62
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    • 1997
  • 주파수영역 표면파기법 (SASW)을 수중지반탐사에 적용하기 위한 일련의 해석적 연구가 실시되었다. SASW실험으로 지반강도분포를 정밀히 예측하기 위해서는 실험조건, 고차모드의 영향, 응답파의 정리 기법 등, 실험결과에 영향을 미치는 모든 제반 요소들을 고려한 정확하고도 경제적인 이론분산곡선을 결정해야만 한다. 따라서, 본 논문에서는 수중 표면파의 이론분산곡선을 구하기 위한 해석기법들을 개발하고 그 이론적 배경을 설명하였다. 또한, 개발된 해석기법들을 수중지반에서 실제로 실시된 SASW실험결과의 분석에 적용하여 수중지반의 강도특성을 예측하는 예를 보였다. 이 결과로부터 개발된 해석기법들과 더불어서 수중지반탐사를 위한 SASW 실험방법의 적용성이 검토되었다.

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Thermal Analysis on a Satellite Box during Launch Stage by Analytical Solution

  • Choi, Joon-Min;Kim, Hui-Kyung;Hyun, Bum-Seok
    • International Journal of Aeronautical and Space Sciences
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    • 제4권2호
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    • pp.17-25
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    • 2003
  • Simple methods are developed to predict temperatures of a satellite box during launch stage. The box is mounted on outer surface of satellite and directly exposed to space thermal environment for the time period from fairing jettison to separation. These simple methods are to solve a 1st order ordinary differential equation (ODE) which is simplified from the governing equation after applying several assumptions. The existence of analytical solution for the 1st order ODE is determined depending on treatment of time-dependent molecular heating term. Even for the case that the analytical solution is not available due to the time dependent term, the 1st order ODE can be solved by relatively simple numerical techniques. The temperature difference between two different approaches (analytical and numerical solutions) is relatively small (Jess than $1^{\circ}C$ along the time line) when they are applied to STSAT-I launch scenario. The present methods can be generally used as tools to quickly check whether a satellite box is safe against space environment during the launch stage for the case that the detailed thermal analysis is not available.

Analytical and numerical simulation on charging behavior of no-insulation REBCO pancake coil

  • Quach, Huu Luong;Kim, Ji Hyung;Chae, Yoon Seok;Moon, Jae Hyung;Ko, Jung Hyup;Kim, Hyung-Wook;Kim, Seog-Whan;Jo, Young-Sik;Kim, Ho Min
    • 한국초전도ㆍ저온공학회논문지
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    • 제20권4호
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    • pp.16-19
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    • 2018
  • This paper presents analytical and numerical simulation approaches on charging characteristics of no-insulation (NI) REBCO pancake coil by using the equivalent circuit model to estimate magnetic performance response in the coil. The analytical methods provide closed form or definite solution in the form of complete mathematical expressions but they are hard to solve the complex problems. Numerical methods have become popular with the development of the computing capabilities to solve the problems which are impossible or very hard to solve analytically. First of all, the equivalent circuit model are proposed to develop the simulation code for both analytical and numerical method. The charging test was performed under critical current to obtain magnetic field induced and terminal voltage through the radial as well as spiral current paths within the coil. To verify the validity of both proposed methods, the simulation results were compared and discussed with the experimental results.

Solving the contact problem of functionally graded layers resting on a HP and pressed with a uniformly distributed load by analytical and numerical methods

  • Yaylaci, Murat;Sabano, Bahar Sengul;Ozdemir, Mehmet Emin;Birinci, Ahmet
    • Structural Engineering and Mechanics
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    • 제82권3호
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    • pp.401-416
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    • 2022
  • The aim of this study is to examine the frictionless double receding contact problem for two functionally graded (FG) layers pressed with a uniformly distributed load and resting on a homogeneous half plane (HP) using analytical and numerical methods. The FG layers are made of a non-homogeneous material with an isotropic stress-strain law with exponentially varying properties. It is assumed that the contact at the FG layers and FG layer-HP interface is frictionless. The body force of the FG layers and homogeneous HP are ignored in the study. Firstly, an analytical solution for the contact problem has been realized using the theory of elasticity and the Fourier integral transform techniques. Then, the problem modeled and two-dimensional analysis was carried out by using the ANSYS package program based on FEM. Numerical results for contact lengths and contact pressures between FG layers and FG layer-HP were provided for various dimensionless quantities including material inhomogeneity, distributed load width, the shear module ratio, and the heights of the FG layers for both methods. The results obtained using FEM were compared with the results found using the analytical formulation. It was found that the results obtained from analytical formulation were in perfect agreement with the FEM study.

폴리염화비페닐류 함유 액상폐기물 시험방법별 분석결과 비교 (Comparison of three analytical methods for PCBs-containing liquid wastes)

  • 김교근;윤성규;배우근
    • 분석과학
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    • 제23권3호
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    • pp.278-283
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    • 2010
  • 본 연구에서는 국제적으로 관심의 대상이 되고 있는 폴리염화비페닐류 함유 액상폐기물의 효율적인 관리를 위해 국내에서 사용되고 있는 L2000DX을 이용한 스크리닝, 신속 GC/ECD 및 기존 GC/ECD 분석방법을 절연유 15건에 적용하였다. 분석 결과 L2000DX을 이용한 경우에는 4.4~182.8 mg/L의 농도 범위로 Aroclor 1242 환산농도가 검출된 반면, 기존 GC/ECD 및 신속 GC/ECD를 이용한 분석 결과 각각 불검출~14.63 mg/L 및 불검출~13.03 mg/L로 나타났다. GC/ECD 분석방법들 간에는 약 4 mg/L이하에서 거의 차이가 없었으나, 국내의 규제농도인 2 mg/L부근의 검출농도에서는 일부 시료의 경우 기존 GC/ECD 분석결과(2.71 mg/L)에 비해 신속 GC/ECD 방법이 다소 낮은(2.49 mg/L) 측정치를 보여 국내 규제기준 2 mg/L부근에서 저평가되는 경향이 있는 것으로 나타났다.

국내 대기 중 독성 휘발성 유기화합물의 오염 특성(I) - 측정 방법론 평가 - (Characteristics of Atmospheric Concentrations of Toxic Volatile Organic Compounds in Korea ( I ) - Evaluation of Sampling and Analytical Methodology)

  • 백성옥;김미현;김수현;박상곤
    • Environmental Analysis Health and Toxicology
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    • 제17권2호
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    • pp.95-107
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    • 2002
  • This study was designed to investigate the characteristics of atmospheric concentrations of toxic volatile organic compounds (VOCs) in Korea. Target compounds included 1,3-butadiene, aromatics such as BTEX, and a number of carbonyl compounds. In this paper, as the first part of the study, the performance of sampling and analytical methods was evaluated for the measurement of selected VOCs and carbonyl compounds in the ambient air. VOCs were determined by the adsorbent tube sampling and automatic thermal desorption coupled with GC/MSD analysis, while carbonyls by the DNPH-silica cartridge sampling with HPLC analysis. The methodology was investigated with a wide range of performance criteria such as repeatability, linearity. lower detection limits, collection efficiency, thermal conditioning, breakthrough volume and calibration methods using internal standards. In addition, the sampling and analytical methods established in this study were applied to real field samples duplicately collected in various ambient environments. Precisions for the duplicate samples appeared to be comparable with the performance criteria recommended by USEPA TO-17. The overall precision of the sampling and analytical methods was estimated to be within 20 ∼ 30% for major aromatic VOCs such as BTEX, whereas the precision for major carbonyl compounds such as formaldehyde and acetaldehyde was within 10 ∼ 20% for field samples. This study demonstrated that the adsorbent sampling and thermal desorption method can be reliably applied for the measurement of BTEX in ppb levels frequently occurred in common indoor and ambient environments.