• 제목/요약/키워드: alpha-case

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전이금속염 첨가에 의한 판상 α-Al2O3 결정체 제조 (Preparation of Flaky α-Al2O3 Crystals by Transition Metal Salts Addition)

  • 송효경;박병기;이정민
    • 한국세라믹학회지
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    • 제42권6호
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    • pp.384-390
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    • 2005
  • [ ${\alpha}-Al_2O_3$ ] precursor was synthesised by sol-gel method using aluminum sulfate, sodium sulfate and sodium carbonate as law materials. The flaky ${\alpha}-Al_2O_3$ crystals were prepared by heating using precursor about $1,050^{\circ}C$. In this study, the effect of some transition-metal sulfate ($FeSO_4,\;SnSO_4,\;ZnSO_4$) addition have been investigated. When iron sulfate was added, it could see that act on impurities in crystal growth process. In case of tin sulfate, distribution of Platelets was very broad. When flaky ${\alpha}-Al_2O_3$ crystals were prepared zinc sulfate addition, thickness, size, and distribution of platelets was suited to industrial application. The average diameter of flaky ${\alpha}-Al_2O_3$ crystals was about 20 $\mu$m, and its thickness was about 0.3 $\mu$m. Increasing addition of zinc sulfate, thickness of ${\alpha}-Al_2O_3$ platelet was decreased.

고온가압소결한 $\alpha-SiC-ZrB_2$ 복합체의 전기전도기구 (Electrical Conductive Mechanism of Hot-pressed $\alpha-SiC-ZrB_2$ Composites)

  • 신용덕;주진영;권주성
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권2호
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    • pp.104-108
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    • 1999
  • The electrical conductive mechanism and temperature dependence of electrical resistivity of $\alpha-SiC-ZrB_2$ composites with $ZrB_2$ contents were investigated. The electrical resistivity of hot-pressed composites was measured by the Pauw method form $25^{\circ} to 700^{\circ}C$. The electrical resistivity of the composites follow the electrical conduction model for a homogeneous mixture of two kind of particles with different conductivity. Also, the electrical resistivity versus temperature curves indicate the formation of local chains of $ZrB_2$ particles. In case of $\alpha-SiC-ZrB_2$ composites containing above 39vol.% $ZrB_2$ showed positive temperature coefficient resistance(PTCR), whereas the electrical resistivity of $\alpha-SiC-21vol.% ZrB_2$ showed negative temperature coefficient resistance(NTCR).

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The Minimum Dwell Time Algorithm for the Poisson Distribution and the Poisson-power Function Distribution

  • Kim, Joo-Hwan
    • Communications for Statistical Applications and Methods
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    • 제4권1호
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    • pp.229-241
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    • 1997
  • We consider discrimination curve and minimum dwell time for Poisson distribution and Poisson-power function distribution. Let the random variable X has Poisson distribution with mean .lambda.. For the hypothesis testing H$\_$0/:.lambda. = t vs. H$\_$1/:.lambda. = d (d$\_$0/ if X.leq.c. Since a critical value c can not be determined to satisfy both types of errors .alpha. and .beta., we considered discrimination curve that gives the maximum d such that it can be discriminated from t for a given .alpha. and .beta.. We also considered an algorithm to compute the minimum dwell time which is needed to discriminate at the given .alpha. and .beta. for the Poisson counts and proved its convergence property. For the Poisson-power function distribution, we reject H$\_$0/ if X.leq..'{c}.. Since a critical value .'{c}. can not be determined to satisfy both .alpha. and .beta., similar to the Poisson case we considered discrimination curve and computation algorithm to find the minimum dwell time for the Poisson-power function distribution. We prosent this algorithm and an example of computation. It is found that the minimum dwell time algorithm fails for the Poisson-power function distribution if the aiming error variance .sigma.$\^$2/$\_$2/ is too large relative to the variance .sigma.$\^$2/$\_$1/ of the Gaussian distribution of intensity. In other words, if .ell. is too small, we can not find the minimum dwell time for a given .alpha. and .beta..

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The Fekete-Szegö Problem for a Generalized Subclass of Analytic Functions

  • Deniz, Erhan;Orhan, Halit
    • Kyungpook Mathematical Journal
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    • 제50권1호
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    • pp.37-47
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    • 2010
  • In this present work, the authors obtain Fekete-Szeg$\ddot{o}$ inequality for certain normalized analytic function f(z) defined on the open unit disk for which $\frac{(1-{\alpha})z(D^m_{{\lambda},{\mu}}f(z))'+{\alpha}z(D^{m+1}_{{\lambda},{\mu}}f(z))'}{(1-{\alpha})D^m_{{\lambda},{\mu}}f(z)+{\alpha}D^{m+1}_{{\lambda},{\mu}}f(z)}$ ${\alpha}{\geq}0$) lies in a region starlike with respect to 1 and is symmetric with respect to the real axis. Also certain applications of the main result for a class of functions defined by Hadamard product (or convolution) are given. As a special case of this result, Fekete-Szeg$\ddot{o}$ inequality for a class of functions defined through fractional derivatives is obtained. The motivation of this paper is to generalize the Fekete-Szeg$\ddot{o}$ inequalities obtained by Srivastava et al., Orhan et al. and Shanmugam et al., by making use of the generalized differential operator $D^m_{{\lambda},{\mu}}$.

6H-SiC로부터 제작한 SiC 세라믹스의 열전변환 특성 (Thermoelectric Conversion Characteristics of SiC Ceramics Fabricated from 6H-SiC Powder)

  • 배철훈
    • 한국세라믹학회지
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    • 제27권3호
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    • pp.412-422
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    • 1990
  • Porous SiC ceramics were proposed to be promising materials for high-temperature thermoelectric energy conversion. Throughthe thermoelectric property measurements and microstructure observations on the porous alpha SiC and the mixture of $\alpha$-and $\beta$-SiC, it was experimentally clarified that elimination of stacking faults and twin boundaries by grain growth is effective to increase the seebeck coefficient and increasing content of $\alpha$-SiC gives rise to lower electrical conductivity. Furthermore, the effects of additives on the thermoelectric properties of 6H-SiC ceramics were also studied. The electrical conductivity and the seebeck coefficient were measured at 35$0^{\circ}C$ to 105$0^{\circ}C$ in argon atmospehre. The thermoelectric conversion efficiency of $\alpha$-SiC ceramics was lower than that of $\beta$-SiC ceramics. The phase homogeneity would be needed to improve the seebeck coefficient and electrical conductivity decreased with increasing the content of $\alpha$-phase. In the case of B addition, XRD analysis showed that the phase transformation did not occur during sintering. On the other hand, AlN addiiton enhanced the reverse phase transformation from 6H-SiC to 4H-SiC, and this phenomenon had a great effect upon the electrical conductivity.

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보헤마이트 졸겔법에 의한 알루미나 세라믹스의 저온소결 I. 상전이 및 소결거동 (Low Temperature Sintering of Alumina by Boehmite Sol-Gel Method I. Phase Transformation and Sintering Behavior)

  • 이형민;이홍림
    • 한국세라믹학회지
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    • 제34권11호
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    • pp.1187-1197
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    • 1997
  • Dry gel composed of primary particles more homogeneous than starting boehmite powder was prepared by dispersing and gelling the boehmite powder. The transformation temperatures of boehmite powder, dry gel seeded with 0, 1, 3, 5 wt% $\alpha$-Al2O3, and ball milled gel were 1192$^{\circ}C$, 1184$^{\circ}C$, 1141$^{\circ}C$, 1119$^{\circ}C$, 1117$^{\circ}C$, and 1106$^{\circ}C$, respectively. Sintering behavior of dry gel without seed was similar to that of boehmite powder, but the sintered density of dry gel was improved as much as 10%~15% than boehmite powder. In the case of dry gel seeded with 5 wt% $\alpha$-Al2O3, sintering behavior was much improved. The relative density of the gel seeded with 5 wt% $\alpha$-Al2O3 was 96% when sintered at 140$0^{\circ}C$ for 1h. On the other hand, ball milling of the non-seeded sol for 48h resulted in the relative density of 97% when sintered at 130$0^{\circ}C$ for 1h. The size and amount of $\alpha$-Al2O3 particles added by ball milling were 0.107 ${\mu}{\textrm}{m}$ and 0.5 wt%.

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Analysis of Propagating Crack Along Interface of Isotropic-Orthotropic Bimaterial by Photoelastic Experiment

  • 이광호;;;;황재석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집A
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    • pp.102-107
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    • 2001
  • Interfacial cracks between an isotropic and orthotropic material, subjected to static far field tensile loading are analyzed using the technique of photoelasticity. The fracture parameters are extracted from the full-field isochromatic data and the same are compared with that obtained using boundary collocation method. Dynamic Photoelasticity combined with high-speed digital photography is employed for capturing the isochromatics in the case of propagating interfacial cracks. The normalized stress intensity factors for static crack is greater when $\alpha=90^{\circ}C$ (fibers perpendicular to the interface) than when $\alpha=0^{\circ}C$ (fiber parallel to the interface) and those when $\alpha=90^{\circ}C$ are similar to ones of isotropic material. The dynamic stress intensity factors for interfacial propagating crack are greater when $\alpha=0^{\circ}C$ than $\alpha=90^{\circ}C$. The relationship between complex dynamic stress intensity factor $|K_D|$ and crack speed C is similar to that for isotropic homogeneous materials, the rate of increase of energy release rate G or $|K_D|$ with crack speed is not as drastic as that reported for homogeneous materials.

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A New Flow Equation for Thixotropic Systems

  • Sohn, Dae-Won;Kim, Eung-Ryul;Hahn, Sang-Joon;Ree, Tai-Kyue
    • Bulletin of the Korean Chemical Society
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    • 제7권4호
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    • pp.257-262
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    • 1986
  • Thixotropy is a time-dependent shear-thinning phenomenon. We derived a new thixotropic formula which is based on the generalized viscosity formula of Ree and Eyring, $f={\Sigma}\frac{X_i}{{\alpha}_i}sinh^{-1}$ () (Refer to the text concerning the notation.) The following is postulated: (1) thixotropy occurs when small flow units attached to a large flow unit separate from the latter under stress (2) elastic energy(${\omega}$) is stored on the large flow unit during the flow process, and (3) the stored energy contributes to decrease the activation energy for flow. A new thixotropic formula was derived by using these postulations, $f={\frac}{X_0{\beta}_0}{\alpha_0}{\dot{s}}+{\frac}{X_1{\beta}_1}{{\alpha}_1}{\dot{s}}+{\frac}{X_2}{{\alpha_x}}sinh^{-1}$[$({\beta}_0)_2$ exp $(-C_2{\dot{s}}^2/RT){\cdot}{\dot{s}}$] f is the shear stress, and s is the rate of shear. In case of concentrated solutions where the Newtonian flow units have little contribution to the viscosity of the system, the above equation becomes, $f=\frac{X_2}{\alpha_2}sinh^{-1}$[$({\beta}_0)_2$ exp $(-C_2{\dot{s}}^2/RT){\cdot}{\dot{s}}$]. In order to confirm these formulas, we applied to TiO2(anatase and rutile)-water, printing ink and mayonnaise systems. Good agreements between the experiment and theory were observed.

벽면에 근접해서 회전하는 원주의 유동장 특성 (The Flow Field Characteristics of a Rotating Circular Cylinder near a Plane Wall)

  • 강명훈;김광석;노기덕
    • Journal of Advanced Marine Engineering and Technology
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    • 제31권2호
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    • pp.166-172
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    • 2007
  • The flow around a rotating circular cylinder near a plane wall is investigated by the measurement of the lift acting on the cylinder and by the flow visualization using the hydrogen bubble technique in the circulating water tank. The experimental parameters are the rotating direction of the cylinder. the space ratios $H/D(H/D=0.05{\sim}0.5)$ between cylinder and plane wall and the velocity ratios ${\alpha}({\alpha}=0{\sim}{\pm}2.0)$. In the case of clockwise, the lift on the rotating circular cylinder was increased with the reduction of the space ratios and with the velocity ratios, the upper separation point was more shifted in the rotating direction with them. In the case of anticlockwise, the absolute value of the lift on the rotating circular cylinder was increased with increasing the space ratios and the velocity ratios. the lower separation point was more shifted in the rotating direction with them.

복합조직의 파괴거동과 파괴혁성에 관한 연구 I

  • 송삼홍;김규생
    • 대한기계학회논문집
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    • 제5권2호
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    • pp.110-121
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    • 1981
  • In order to study on the fracture behavior and the fracture thoughness of combined structure, the specimens, structural steel (SM28C) and 6:4 brass are annealed for ductility and investigated for the befavior of fracture and the absorbed energy at the variation of the impact velocity. The results obtained by this study are as follows: (1)The maximum load increases with the impact velocity, but in the condition of constant impact velocity it decreases as the ductility increases. (2)The absorbed energy increases with the impact velocity, but in the condition of constant impact velocity it is constant as the ductility increases. (3)In the case of the combined structure of peralite and ferrite, the microcracks initiates and propagates mainly in the ferrite structure intergranular in accompany with the slip, and the slip concentration phenomena occur in the boundary of pearlite structure However, in case of the combined structure of .alpha. and ..betha. phase, the microcracks initiates and propagares mainly in the .alpha. phase intergranularly, and slip concentration phenomena not ocur in the boundary of .betha. phase.