Low Temperature Sintering of Alumina by Boehmite Sol-Gel Method I. Phase Transformation and Sintering Behavior

보헤마이트 졸겔법에 의한 알루미나 세라믹스의 저온소결 I. 상전이 및 소결거동

  • 이형민 (연세대학교 세라믹공학과) ;
  • 이홍림 (연세대학교 세라믹공학과)
  • Published : 1997.11.01

Abstract

Dry gel composed of primary particles more homogeneous than starting boehmite powder was prepared by dispersing and gelling the boehmite powder. The transformation temperatures of boehmite powder, dry gel seeded with 0, 1, 3, 5 wt% $\alpha$-Al2O3, and ball milled gel were 1192$^{\circ}C$, 1184$^{\circ}C$, 1141$^{\circ}C$, 1119$^{\circ}C$, 1117$^{\circ}C$, and 1106$^{\circ}C$, respectively. Sintering behavior of dry gel without seed was similar to that of boehmite powder, but the sintered density of dry gel was improved as much as 10%~15% than boehmite powder. In the case of dry gel seeded with 5 wt% $\alpha$-Al2O3, sintering behavior was much improved. The relative density of the gel seeded with 5 wt% $\alpha$-Al2O3 was 96% when sintered at 140$0^{\circ}C$ for 1h. On the other hand, ball milling of the non-seeded sol for 48h resulted in the relative density of 97% when sintered at 130$0^{\circ}C$ for 1h. The size and amount of $\alpha$-Al2O3 particles added by ball milling were 0.107 ${\mu}{\textrm}{m}$ and 0.5 wt%.

Keywords

References

  1. Alumina Chemicals;Science and Technology Handbook Nomenclature, Preparation and Properties of Aluminum Oxides, Oxide Hydroxides and Trihydroxides K. Wefers;L.D. Hart(ed.)
  2. Alumina as a Ceramic Material W.H. Gitzen
  3. Progress in Ceramic Science v.3 Sintering in Ceramics R.L. Coble;J.E. Burke;J.E. Burke(ed.)
  4. Powder Metall. Int. v.5 no.3 Sol-gel Process-A Curiosity or a Technique? M.E. Hermans
  5. J. of Non-Cryst. Solids v.100 Prospect of Sol-Gel Processes D.R. Ulrich
  6. Am. Ceram. Soc. Bull. v.64 no.12 Sol-Gel Processing of Ceramics and Glass D.W. Jonson, Jr.
  7. Am. Ceram. Soc. Bull. v.70 no.9 Sol-Gel Process-Principles and Applications C.W. Turner
  8. Sintering and Related Phenomena, Materials Science Research v.6 P.A. Badkar;J.E. Bailey;H.A. Barker;G.C. Kuczynski(ed.)
  9. Processing of Crystalline Ceramics, Materials Science Research v.11 P.F. Becher;J.H. Somers;B.A. Bender;B.A. McFarlane;H. Palmour;R.F. Davis;T. Hare
  10. U.S. Pat. 4,314,827 Non-fused Aluminum Oxide-based Abrasive Mineral M.A. Leitheiser;H.G. Sowman
  11. J. Am. Ceram. Soc. v.67 no.11 Enhanced Densification of Boehmite Sol-gels by α-Alumina Seeding M. Kumagai;G.L. Messing
  12. J. Am. Ceram. Soc. v.68 no.9 Controlled Transformation and Sintering of a Boehmite Sol-Gel by α-Alumina Seeding M. Kumagai;G.L. Messing
  13. Science of Ceramic Chemical Processing Seeded Transformations for Microstructural Control in Ceramics G.L. Messing;M. Kumagai;R.A. Shelleman;J.L. McArdle;L.L. Hench(ed.);D.R. Ulrich(ed.)
  14. J. Am. Ceram. Soc. v.71 no.10 Low-Temperature Sintcring of Aluminum Oxide T. Yeh;M.D. Sacks
  15. Am.Ceram.Soc.Bull. v.73 no.10 Low-Temperature Sintering of Alumina-seeded Boehmite Gels G.L. Messing;M. Kumagai
  16. 공업기반기술 과제 최종 보고서 Sol-Gel 법에 의한 Alumina Spinel 재료의 제조 이영서 (외)
  17. Introduction to the Principles of Ceramic Processing J.S. Reed