• Title/Summary/Keyword: alkali-activated binder

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Development of Prototype System for Microwave Heating in a Manufacture Process of Alkali Activted Hwangtoh Binder (알칼리 활성 황토 결합재 제조를 위한 프로토타입의 마이크로파 가열 시스템 개발)

  • Kim, Baek-Joong;Lu, Yang;Yi, Chong-Ku;Kang, Kyung-In
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.25-26
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    • 2011
  • The objective of this study is to develop the prototype system for microwave heating in a manufacture process of alkali activated Hwangtoh binder as replacement materials for the cement in concrete. In order to achieve this, four research phases are carried out as follows: 1) establishment of a system concept 2) deduction of a system element 3) design of the entire system 4) making of the prototype system for microwave heating.

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The Properties of Hardened Slag by Alkali and Curing Method (알칼리 첨가 및 양생방법에 따른 슬래그 경화체의 특성)

  • 김원기;소정섭;배동인
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.27-32
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    • 2002
  • In this research influences of type and concentration of alkali activator and curing condition on the hydration, and properties of alkali activated blast furnace slag(AAS) concrete were investigated. Sodium carbonate and sulfate were used as alkali activators and their concentration were 4~10 weight percent with Na$_2$O equivalent to binder. The curing conditions were standard curing using 23$^{\circ}C$ water and activated curing chamber at $65^{\circ}C$. Results show that in case of sodium carbonate addition high early strengths were gained by activation of early hydration, but later strength gained was slight. On the other side sodium sulfate strengths were continuously increased with adding amount and ages. Steam curing activated early hydration so that early strengths were improved but later strengths were similar to standard curing. The strength reduction of AAS mortar with sodium sulfate was less than OPC mortar in 5% sulfuric acid solution so that AAS concrete can be useful for acid-resistance concrete.

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Laboratory investigations on the effects of acid attack on concrete containing portland cement partially replaced with ambient-cured alkali-activated binders

  • Ramagiri, Kruthi K.;Patil, Swaraj;Mundra, Harsh;Kar, Arkamitra
    • Advances in concrete construction
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    • v.10 no.3
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    • pp.221-236
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    • 2020
  • To reduce the CO2 emissions associated with the manufacture of portland cement (PC), an efficient alternative like an alkali-activated binder (AAB) is the requirement of the industry. To promote the use of AAB in construction activities, a practically implementable mix proportion is required. Owing to the several raw ingredients of AAB concrete and their associated uncertainties, partial replacement of PC by AAB may be adopted instead of complete replacement as per industrial requirements. Hence, the present study aims to determine an optimal proportion for partial replacement of PC with AAB and recommend a technique for it based on site conditions. Three modes of partial replacement are followed: combining all the dry ingredients for AAB and PC followed by the addition of the requisite liquids (PAM); combining the PC and the AAB concrete in two horizontal layers (PAH); and two vertical layers (PAV). 28-day old specimens are exposed to 10% v/v solutions of HCl, H2SO4, and HNO3 to evaluate changes in mechanical, physical, and microstructural characteristics through compressive strength, corrosion depth, and microscopy. Based on deterioration in strength and integrity, PAH or PAV can be adopted in absence of acid attack, whereas PAM is recommended in presence of acid attack.

Characteristics of Soil Pavement by Red Mud Content and Binder Type (레드머드 대체율에 따른 결합재별 흙포장재의 특성)

  • Kang, Suk-Pyo;Kang, Hye-Ju;Kim, Jae-Hwan;Kim, Byeong-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.37-44
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    • 2017
  • Red mud is an inorganic by-product produced from the mineral processing of alumina from Bauxite ores. The development of alkali-activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. This study is to investigate the optimum water content, compressive strength, water absorption and efflorescence of alkali-activated slag-red mud soil pavement according to binder type. The results showed that the optimum water content, moisture absorption coefficient and efflorescence area of alkali-activated slag-red mud soil pavement increased but the compressive strength of that decreased as the redmud content increased.

Evaluation of the Flowability and Compressive Strength of Alkali-Activated Blast Slag Mortar (고로슬래그 알칼리 활성 모르타르의 유동성 및 압축강도 평가)

  • Ryu, Gum-Sung;Kang, Hyun-Jin;Koh, Kyung-Taek;Lee, Jang-Hwa;Kang, Su-Tae
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.613-616
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    • 2008
  • Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash and blast slag, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effect reduction of CO$_2$ gas. In this study, we investigated the influence of the workability and compressive strength of mortar on water reducing agent, alkaline activator and curing method in oder to develop cementless blast slag based alkali-activated mortar. In view of the results, we found out that the flowability of mortar was lowered as increasing to mole concentration of NaOH, but not large the loss of flowability to 9M NaOH, most of water reducing agent was not effect. The compressive strength was improved as increasing to mole concentration of NaOH, was the most effect in 9M NaOH. The curing temperature and curing conditions on compressive strength of blast slag based alkali-activated mortar didn't influence.

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Basic Research of Self Compacting Concrete Using Alkali-Activated Slag Binder (알칼리 활성 슬래그 결합재를 이용한 자기충전 콘크리트의 기초 연구)

  • Song, Keum-Il;Shin, Gyeong-Sik;Gong, Min-Ho;Song, Jin-Kyu
    • Journal of the Korea Concrete Institute
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    • v.25 no.6
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    • pp.657-665
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    • 2013
  • The purpose of this study is the basic research of self-compacting concrete using Alkali-Activated Slag (AAS) binder in order to emphasize the durability of structures and facilitate casting the fresh concrete in field. The AAS binder emitted low carbon dioxide ($CO_2$) is eco friendly material of new concept because AAS products not only emit little $CO_2$ during production but also reuse the industrial by-products such as ground granulated blast-furnace slag (GGBS) of the steel mill. Until now, almost of domestic and foreign research are using Ordinary Portland Cement (OPC) for self-compacting concrete, and also, nonexistent research about AAS. The self-compacting concrete must get the performance of flowability, segregation resistance, filling and passing ability. Nine concrete mixes were prepared with the main parameter of unit amount of binder (400, 500, 600 $kg/m^3$) and 3 types of water-binder (W/B) ratio. The results of test were that fresh concretes were satisfied with flowability, segregation resistance, and filling ability of JSCE. But the passing ability was not meet the criteria of EFNARC because of higher viscosity of AAS paste than OPC. This high viscosity of AAS paste enables the manufacturing of self compacting concrete, segregation of which does not occur without the using of viscosity agent. It is necessary that the development of high fluidity AAS binders of higher strength and the study of better passing ability of AAS concrete mixes in order to use self compacting AAS concrete in field.

The Compressive Strength Development of Briquette Ash by Alkali Activated Reaction (알칼리 활성반응에 의한 Briquette ash의 강도 발현 특성)

  • Seo, Myeong-Deok;Lee, Su-Jeong;Park, Hyun-Hye;Kim, Yun-Jong;Lee, Su-Ok;Kim, Taik-Nam;Cho, Sung-Baek
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.463-469
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    • 2008
  • Non-sintering cement was manufactured with briquette ash. Alkali activator for compression bodies used a NaOH solution. In order to apply alkali-activated briquette ash and the non-sintering cement to concrete, several experimental studies were performed. It was necessary to study the binder obtained by means of a substitute for the cement. This study concentrated on strength development according to the concentration of NaOH solution, the curing temperature, and the curing time. The highest compressive strength of compression bodies appeared as $353kgf/cm^2$ cured at $80^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is needed to get a higher strength body. Also, geopolymerization was examined by SEM and XRD analysis after the curing of compression bodies. According to SEM and XRD, the main reaction product in the alkali activated briquette ash is aluminosilicate crystal.

Compressive Strength and Shrinkage Strain of Slag-Based Alkali-Activated Mortar with Gypsum (석고가 첨가된 슬래그 기반 알카리활성 모르터의 압축강도 및 건조수축 변형률)

  • Yang, Keun-Hyeok;Sin, Jae-Il
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.1
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    • pp.57-62
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    • 2008
  • Twelve mortars were mixed and tested to explore the effect of gypsum on the compressive strength development and shrinkage strain of alkali-activated mortars. Powder typed sodium silicate and ground granulated blast-furnace slag were employed as alkaline activator and source material, respectively, to produce cementless mortar. The main variables investigated were alkali quality coefficient combining the concentration of activator and main compositions in source material, and the adding amount of gypsum ranged between 1 and 5% with respect to the weight of binder. Initial flow, compressive strength development, modulus of rupture, and shrinkage strain behavior of mortar specimens were measured. In addition, the hydration production of alkali-activated pastes with gypsum was traced using X-ray diffraction and energy-dispersive X-ray analysis combined with scanning electron microscope image. Test results showed that the initial flow of slag-based alkali-activated mortar was little influenced by the adding amount of gypsum. On the other hand, the effect of gypsum on the compressive strength of mortar specimens was dependent on the alkali quality coefficient, indicating that the compressive strength increased with the increase of the adding amount of gypsum until a certain limit, beyond which the strength decreased slowly. Shrinkage strain of mortar tested was little influenced by the adding amount of gypsum because no ettringite as hydration product was generated. However, the adding of gypsum had a beneficial effect on reducing the microcrack in the alkali-activated mortar.

The Fundamental Properties of Alkali-Activated Slag Cement (AASC) Mortar with Different Water-Binder Ratios and Fine Aggregate-Binder Ratios (물-결합재 비와 잔골재-결합재 비에 따른 알칼리 활성화 슬래그 모르타르의 기초특성)

  • Kim, Tae-Wan;Hahm, Hyung-Gil;Lee, Seong-Haeng;Eom, Jang-Sub
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.5
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    • pp.77-86
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    • 2013
  • This study investigates the fundamental properties of the water-binder (W/B) ratio and fine aggregate-binder (F/B) ratio in the alkali-activated slag cement (AASC) mortar. The W/B ratios are 0.35, 0.40, 0.45, and 0.50, respectively. And then the F/B ratios varied between 1.00 and 3.00 at a constant increment of 0.25. The alkali activator was an 2M and 4M NaOH. The measured mechanical properties were compared, flow, compressive strength, absorption, ultra sonic velocity, and dry shrinkage. The flow, compressive strength, absorption, ultra sonic velocity and dry shrinkage decreased with increases W/B ratio. The compressive strength decreases with increase F/B ratio at same W/B ratio. Also, at certain value of F/B ratio significant increase in strength is observed. And S2 (river sand 2) had lower physical properties than S1 (river sand 1) due to the fineness modulus. The results of experiments indicated that the mechanical properties of AASC depended on the W/B ratio and F/B ratio. The optimum range for W/B ratios and F/B ratios of AASC is suggested that the F/B ratios by 1.75~2.50 at each W/B ratios. Moreover, the W/(B+F) ratios between 0.13 and 0.14 had a beneficial effect on the design of AASC mortar.

Effects of Alkali-Activated Soil Stabilizer Binder Based on Recycling BP By-Products on Soil Improvement (BP부산물을 재활용한 알칼리활성화 지반개량재의 지반개량효과에 관한 연구)

  • Lee, Yeong-Won;Kang, Suk-Pyo;Kim, Jae-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.2
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    • pp.158-165
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    • 2014
  • The enormous quantity of 'Bayer-Process by-products' (BP by-products) discharged by industries producing alumina from bauxite represents an environmental and economical problem. As it is mainly composed of $Fe_2O_3$, $Al_2O_3$, $SiO_2$, CaO and $Na_2O$, it is thought that using BP by-products as a construction material is an effective way to consume such a large quantity of alkaline waste. In this study, This study evaluates the effect of alkali-activated binder based on recycling BP by-products on soil improvement through the evaluation of slope stability and seepage flow numerical analysis. The results of analysis of ground slope safety at dry season and wet season meet standard (Ministry of Land, Infrastructure and Transport, 2006) Especially, when wet season, the ground used soil improving material meet standard, while the ground used soil-nailing method doesn't. Also, permeability coefficient of improved soil is smaller than that of natural soil and saturation depth of reinforced ground surface with improve soil is lower than that of natural soil.