• Title/Summary/Keyword: YBaCuO ceramics

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Liquid-Phase Sintering of $YBa_2Cu_3O_x$ Ceramic Superconductor and Grain Size Control Using $Y_2BaCuO_5$ ($YBa_2Cu_3O_x$초전도체의 액상 소결과 $Y_2BaCuO_5$를 이용한 입자 크기 제어)

  • 노광수;이정용;위당문
    • Journal of the Korean Ceramic Society
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    • v.27 no.3
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    • pp.423-429
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    • 1990
  • YBa2Cu3Ox ceramics superconductors fabricated using solid state reaction usually contain second phases, such as BaCuO2 and CuO. These second phases are located long the grain boundaries and enhance the abnormal growth of YBa2Cu3Ox grains and, consequently, generate the microcracks. These second phaases were reduced by adding Y2BaCuO5 into solid state reacted YBa2Cu3Ox ceramics. Y2BaCuO5 reacts with grain boundary second phases and reduces the grian size of the ceramics. It was observed the critical current density was improved by adding Y2BaCuO5 into solid state reacted YBa2Cu3Ox ceramic superconductor.

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Simplified fabrication method of Functional materials (기능성 재료의 간소화된 합성법)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1240-1241
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    • 2008
  • Superconducting ceramics of YBaCuO was fabricated on SrTiO substrate by chemical fabrication method using fine powder of YBaCuO having diameter less than 1um. The pattern of the fabricated superconducting bulk was linear and the thickness of it can be controlled in the range of 50um. The structure of the surface of film by diffraction pattern and composition. The tape like YBaCuO bulk with width of 10mm was formed on substrate using similar method. Tape like film is expected to utilize as material of superconducting tape.

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Crystalline Qualities and Surface Morphologies of As-Grown $YBa_2Cu_3O_{7-x}$ Thin Films on MgO(100) Substrate by Reactive Coevaporation Method (반응성 동시 증착법에 의한 As-grown $YBa_2Cu_3O_{7-x}$ 박막의 결정 특성 및 표면형상에 관한 연구)

  • Jang, Ho-Yeon;Watanabe, Yasuhiro;Doshida, Yutaka;Shimizu, Kenji;Okamoto, Yoichi;Akibama, Ryozo;Song, Jin-Tae
    • Korean Journal of Materials Research
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    • v.1 no.2
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    • pp.93-98
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    • 1991
  • The as-grown $YBa_2Cu_3O_{7-x}$ superconducting thin films on MgO(100) substrate have been prepared by a reactive coevaporation method. The superconducting transition temperature, surface morphology and crystalline quality were examined as a function of the substrate temperature ranging from $450^{\circ}C$ to $590^{\circ}C$. From the reflection high energy electron diffraction (RHEED) analysis, it was found the film consisted of almost amorphous phase with a halo pattern deposited at the substrate temperature of $450^{\circ}C$. The film deposited at the substrate temperature of $510^{\circ}C$ consisted of polycrystalline phase, showing a broad ring pattern. On the other hand, for the film deposited at $590^{\circ}C$, RHEED showed spotty pattern indicating that this film consisted of single crystal phase. It has rough film surface due to the surface outgrowth. The surface outgrowth increased as the substrate temperature increased from $510^{\circ}C$ to $590^{\circ}C$. the surface outgrowth may be due to the anisotropic growth rate. The highest transition temperature obtained in this study was $Tc_{zero}$ of 83K with $Tc_{onset}$ of 88K for the film deposited at $590^{\circ}C$ using activated RF oxygen plasma.

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Electromagnetic Characteristics of Superconducting Ceramics for Electrical Power Devices (전력기기 적용을 위한 초전도 세라믹의 전기자기적 특성)

  • Lee, Sang-Heon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.2
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    • pp.349-351
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    • 2011
  • The formation of oxide superconducting phase fabrication of superconducting wire materials and fabrication of precise superconducting material were studied for developing superconductor application technique. The $ZrO_2$ addition reduced the particle size $BaZrO_3$ trapped in the matrix after the sintering growth. The added $ZrO_2$ was converted to fine particles of $BaZrO_3$ which is the conventional sintering temperature for YBaCuO, $Y_2Ba_1Cu_1O_5$ and CuO are formed as by products of the reaction between $ZrO_2$ and YBaCuO phase. The formation of highly $BaZrO_3$ particle appears to be responsible for the refinement of $BaZrO_3$ phase after the citric acid sintering process.

Preparation of Magnetic Field Sensor with YBaCuO Superconducting Ceramics (YBaCuO계 초전도소결체 자기소자)

  • 이상헌
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2000.02a
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    • pp.109-111
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    • 2000
  • A magnetic field sensor is fabricated with superconducting ceramics of Y-Ba-Cu-O system. The prepared material shows the superconductivity at about 95K. The sensor at liquid nitrogen temperature shows the increase in electrical resistance by applying magnetic field. Actually, the voltage drop across the sensor is changed from zero to a value more than 100$\mu$V by the applied magnetic field. The change in electrical resistance depends on magnetic field. The sensitivity of this sensor is 2.9 ohm/T. The sensing limit is about $1.5\times$$10^{-5}$ (=1.5$\times$$10^{-1}$ G). The increase in electrical resistance by the magnetic field is ascribed to a modification of the Josephson junctions due to the penetrating magnetic flux into the superconducting material.

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A Study on the Fabrication and Electromagnetic Characteristics of High Tc Superconductor Using Pyrosis method for Electrical Equipment (열분해법에 의한 전력기기용 고온 초전도체의 합성 기술 및 전기 자기적 특성)

  • Lee, Sang-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.10
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    • pp.453-456
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    • 2005
  • We have fabricated superconducting ceramics by chemical process. A high Tc superconducting with a nominal composition of YBaCuO was prepared by the pyrolysis method. The electromagnetic properties in YBaCuO superconductor was studied. In the measurement of current-voltage characteristics, a voltage across the superconducting sample was observed on applying an external magnetic field. The voltage increases with increase in applied magnetic flux, but it becomes constant at about 10$^{-2}$T. The voltage continues to appear the removal of the magnetic field. The appearance of the voltage is ascribed to the trapping of magnetic flux. Depending on the direction of applied magnetic flux less than 2.5$\times$10$^{-5}$ T, the voltage in the magnetized sample increases or decreases.

The Influence of Calcining and Sintering Conditions on the Properties of $YBa_2Cu_3O_{7-x}$ Superconducting Ceramics Prepared by the Polymeric Precursor Process (Polymeric Precursor법으로 제조한 $YBa_2Cu_3O_{7-x}$초전도세라믹스의 특성에 대한 하소 및 소결조건의 영향)

  • 석상일;오재희
    • Journal of the Korean Ceramic Society
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    • v.28 no.1
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    • pp.37-45
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    • 1991
  • The critical current density, electrical conductivity, critical magnetic field, Meissner effect, apparent density, and microstructure of YBa2Cu3O7-x ceramic superconductor prepared by polymeric precursor, while varing calcining and sintering conditions, were investigated. The best superconducting properties could be obtained from the body sintered at 93$0^{\circ}C$ for 10h after calcining at 90$0^{\circ}C$ for 10h, which gave 383A/$\textrm{cm}^2$ of critical current density(Jc), 96K of onset temperature(Tonset), 94. 8K of zero temperature (Tzero) 225 Oe of critical magnetic field (Hc1), 72.8% of superconducting volume fraction measured by Meissner effect and 6.28g/㎤ of apparent density.

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Fabrication of $YBa_2Cu_3O_{7-{\delta}}$ Superconducting Coils with Polymer Binder (유기물 바인더를 사용한 $YBa_2Cu_3O_{7-{\delta}}$ 초전도 Coil의 제조)

  • 정해원;박승만;김재묵;김성수
    • Journal of the Korean Ceramic Society
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    • v.27 no.3
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    • pp.355-360
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    • 1990
  • One of the possible ways to make a flexible wire of high-Tc superconductiong ceramics is the extrusion of a mixture slurry of superconducting powder with an appropriate polymer binder. The fabrication procedure for $YBa_2Cu_3O_{7-{\delta}}$ superconducting coils with this plastic mass is described. The major factors limiting the formation of extruded wire are the binder content, powder size, and entrapped gas in the mixture slurries. The optimum content of binder for both good flexbility and strength of wire was estimated to be 30wt%. The finer the powder size is, the more homogeneous structure the extruded wire has. The vacuum degassing before extrusion was necessary to remove the entrapped gas in as-extruded wire. The formability of wire depends greatly on the wire radius and binder content. After burning out the binder and the successive sintering, the contacts between the superconducting grains could be made. The resistivity vs. temperature behavior measured in the final wire showed the transition temperature of 90K with narrow transition width. However, the critical current densities of these wires are much lower in comparison to those of conventional bulk specimens.

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Fabrication and Chracteristics of Magnetic Sensor using Ceramic Superconductor (산화물 초전도체를 이용한 자기센서의 제작 및 특성)

  • Lee, Sang-Heon
    • Journal of IKEEE
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    • v.3 no.2 s.5
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    • pp.243-249
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    • 1999
  • A magnetic field sensor is fabricated with superconducting ceramics of Y-Ba-Cu-O system. The prepared material shows the superconductivity at about 95K. The sensor at liquid nitrogen temperature shows the increase in electrical resistance by applying magnetic field. Actually, the voltage drop across the sensor is changed from zero to a value. more than $100{\mu}V$ by the applied magnetic field. The change in electrical resistance depends on magnetic field. The sensitivity of this sensor is 2.9 ohm/T. The sensing limit is about $1.5{\times}10^{-5}T(=1.5{\times}10^{-1}G)$. The increase in electrical resistance by the magnetic field is ascribed to a modification of the Josephson junctions due to the penetrating magnetic flux into the superconducting material.

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Properties of Ceramics Superconducting Tapes (산화물 초전도 선재의 기초물성)

  • Lee, Sang-Heon;Lee, Sung-Gap;Kim, Young-Kuk;Yoo, Jae-Mu;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.353-355
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    • 2004
  • YBaCuO thick films were fabricated by plasma enhanced chemical vapor deposition, and the crystallinity and the superconducting properties were investigated. The growth temperature to obtain the thick films was decreased by around $150^{\circ}C$ due to plasma enhancement. The zero resistivity temperatures for films grown at $590^{\circ}C$ and $620^{\circ}C$ were 55 and 80 K, resistively.

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