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Mechanochemically Synthesized Cu2Zn(Sn,Ge)S4 Nanocrystals and Their Application to Solar Cells (기계화학적 방법으로 합성한 Cu2Zn(Sn,Ge)S4 나노결정과 이를 이용하여 제조한 태양전지)

  • Park, Bo-In;Lee, Seung Yong;Lee, Doh-Kwon
    • Current Photovoltaic Research
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    • v.4 no.3
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    • pp.114-118
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    • 2016
  • $Cu_{1.8}Zn_{1.2}(Sn_{1-x}Ge_x)S_4$ (CZTGeS) nanocrystals were mechanochemically synthesized from elemental precursor powders without using any organic solvents and any additives. The composition of CZTGeS nanocrystals were systematically varied with different Ge mole fraction (x) from 0.1 to 0.9. The XRD, Raman spectroscopy, high-resolution TEM, and diffuse reflectance studies show that the as-synthesized CZTGeS nanocrystals exhibited consistent changes in various structural and optical properties as a function of x, such as lattice parameters, wave numbers for $A_1$ Raman vibration mode, interplanar distances (d-spacing), and optical bandgap energies. The bandgap energy of the synthesized CZTGeS nanocrystals gradually increases from 1.40 to 1.61 eV with increasing x from 0.1 to 0.9, demonstrating that Ge-doping is useful means to tune the bandgap of mechanochemically synthesized nanocrystals-based kesterite thin-film solar cells. The preliminary solar cell performance is presented with an efficiency of 3.66%.

GENERALIZED BROWDER, WEYL SPECTRA AND THE POLAROID PROPERTY UNDER COMPACT PERTURBATIONS

  • Duggal, Bhaggy P.;Kim, In Hyoun
    • Journal of the Korean Mathematical Society
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    • v.54 no.1
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    • pp.281-302
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    • 2017
  • For a Banach space operator $A{\in}B(\mathcal{X})$, let ${\sigma}(A)$, ${\sigma}_a(A)$, ${\sigma}_w(A)$ and ${\sigma}_{aw}(A)$ denote, respectively, its spectrum, approximate point spectrum, Weyl spectrum and approximate Weyl spectrum. The operator A is polaroid (resp., left polaroid), if the points $iso{\sigma}(A)$ (resp., $iso{\sigma}_a(A)$) are poles (resp., left poles) of the resolvent of A. Perturbation by compact operators preserves neither SVEP, the single-valued extension property, nor the polaroid or left polaroid properties. Given an $A{\in}B(\mathcal{X})$, we prove that a sufficient condition for: (i) A+K to have SVEP on the complement of ${\sigma}_w(A)$ (resp., ${\sigma}_{aw}(A)$) for every compact operator $K{\in}B(\mathcal{X})$ is that ${\sigma}_w(A)$ (resp., ${\sigma}_{aw}(A)$) has no holes; (ii) A + K to be polaroid (resp., left polaroid) for every compact operator $K{\in}B(\mathcal{X})$ is that iso${\sigma}_w(A)$ = ∅ (resp., $iso{\sigma}_{aw}(A)$ = ∅). It is seen that these conditions are also necessary in the case in which the Banach space $\mathcal{X}$ is a Hilbert space.

The Study on NOx Emission for Hydrogen Fueled Engine(1) (수소기관에서 NOx 특성에 관한 연구(1))

  • Lee, S.J.;Choi, G.H.
    • Journal of Hydrogen and New Energy
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    • v.8 no.2
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    • pp.91-97
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    • 1997
  • The goals of this research are to understand the $NO_x$ emission in direct injected diesel engine with premixed hydrogen fuel. Hydrogen fuel was supplied into the test engine through the intake pipe. Amount of hydrogen-supplemented fuel was 70 percent basis heating value of the total fuel. The effects of intake air temperature on $NO_x$ emission were studied. The intake air temperature was controlled by flow rate of liquid nitrogen. The major conclusions of this work include : (i) the tested engine was run without backfire under 70 percent hydrogen fuel supplemented. (ii) radicals of nitrogen gas in the intake pipe were increased by 30 percent and cylinder gas temperature was decreased by 24 percent as the intake air temperature were changed from $23^{\circ}C$ to $0^{\circ}C$ ; and (iii) $NO_x$ emission per unit heating value of supplied fuel was decreased by 45 percent with same decrease of intake air temperature.

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A Study on the Precipitates in Rapidly Solidified Al-(Fe, Ce) Alloys by Analysis of X-Ray Diffraction (급냉응고된 Al-(Fe, Ce) 합금에서 형성되는 석출상의 X-선적연구)

  • Park, Ik-Min;Lee, Kyu-Han;Choe, Jeong-Cheol;Jo, Hyung-Ho
    • Journal of Korea Foundry Society
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    • v.8 no.4
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    • pp.446-452
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    • 1988
  • To obtain detailed information on the metastable and the equilibrium phases in rapidly solidified Al-(Fe,Ce) alloys, analysis of X-ray diffraction pattern has been carried out. It has been found that the metastable phase formed in Al-Fe alloys including up to 6wt%Fe is $Al_6Fe$ and the equilibrium phase is $Al_3Fe$. Any X-ray diffraction peak corresponding to the equilibrium phase $Al_{13}Fe_4$ has not been observed during aging. In Al-4wt%Fe alloy, which is ribbon shape with thickness less than $70\;{\mu}m$, aged at $400^{\circ}C$ for 1h after rapid solidification, unidentified phase has been found. In Al-4wt%Ce alloy, only X-ray diffraction peak corresponding to the equilibrium phase, $Al_4Ce$ has been observed. It has been found that the metastable phase Formed in Al-Fe-Ce alloys including up to 6wt% Fe and 4wt% Ce is $Al_6Fe$ and the equilibrium phases are $Al_3Fe$ and $Al_{10}CeFe_2$.

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Seismic design rules for ductile Eurocode-compliant two-storey X concentrically braced frames

  • Costanzo, Silvia;D'Aniello, Mario;Landolfo, Raffaele
    • Steel and Composite Structures
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    • v.36 no.3
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    • pp.273-291
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    • 2020
  • Two-storey X-bracings are currently very popular in European practice, as respect to chevron and simple X bracings, owing to the advantages of reducing the bending demand in the brace-intercepted beams in V and inverted-V configurations and optimizing the design of gusset plate connections. However, rules for two-storey X braced frames are not clearly specified within current version of EN1998-1, thus leading to different interpretations of the code by designers. The research presented in this paper is addressed at investigating the seismic behaviour of two-storey X concentrically braced frames in order to revise the design rules within EN1998-1. Therefore, five different design criteria are discussed, and their effectiveness is investigated. With this aim, a comprehensive numerical parametric study is carried out considering a set of planar frames extracted from a set of structural archetypes that are representative of regular low, medium and high-rise buildings. The obtained results show that the proposed design criteria ensure satisfactory seismic performance.

Ferroelectric Phase Transition Behavior in $(Na_{1/2}Bi_{1/2})TiO_3-PbTiO_3$ System ($(Na_{1/2}Bi_{1/2})TiO_3-PbTiO_3$ 고용체의 강유전 상전이 거동)

  • 홍국선;조서용;박승익
    • Journal of the Korean Ceramic Society
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    • v.32 no.8
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    • pp.915-921
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    • 1995
  • The morphotropic phase boundary and phase transitions of the solid solutiion system, (1-x)(Na1/2Bi1/2)TiO3-PbTiO3+xPbTiO3 were studied by investigating changes in crystal structure, variations in permittivity with temperature, and calorimetric behavior. It was observed that the morphotropic phase boundary (MPB) of this solid solutiion system was at near 14 mol% of PbTiO3. Compositions containing less than 10mol% PbTiO3 (x<0.1) exhibited a phase transition, i.e. ferroelectric rhombohedrallongrightarrowparaelectric paraelectric cubic, with increasing temperature. Composition containing more than 14 mol% PbTiO3 (x 0.14) showed a phase transition from ferroelectric tetragonal to paraelectric cubic. In the composition range of 0.1$\varepsilon$ (T) curve, which coincided with a phase transition from ferroelectric rhombohedral to an intermediate phase, was also found.

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Aquatic Plants for Wastewater Treatment (수생식물을 이용한 수질정화에 관한 연구)

  • 나규환;권성환;이장훈
    • Journal of Environmental Health Sciences
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    • v.22 no.3
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    • pp.49-55
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    • 1996
  • Water parsley(Oenanthe javanica(Blume) DC) was raised with varying population density(S) in the laboratory aquarium unit to determine the growth equation. The population density was measure after 7 days. The resultant growth curve was well fit to the equation 1/S = A+B (1/S0) with a high correlation coefficient ($R^2$ = 0.999). The maximum specific absorption rate was $9.011 \times 10^{-5}$ kg $NO_x-N/kg$ water parsley$\cdot$day and $1.31 \times 10^{-5}$ kg $PO_4-P/kg$ water parsley$\cdot$day when the average population density was $2.62 kg/m^2$. The relationship between population density and nutrient absorption rate, the absorption rate of $NO_x-N$ was 5.04~5.24 mg/l$\cdot$day when the population density was $7.51~10.0 $mg/m^2\cdot day$ and the absorption rate of $PO_4-P$ was 0.56~0.78 mg/l$\cdot$day when the population density was 5.02~10.0 $kg/m^2\cdot day$. Taking into account the nutrient absorption rate and growth rate, the population density between $7.0 kg/m^2\cdot day$ and $8.0 kg/m^2 \cdot day$ was selected. The removal rate of nutrient was investigated after 7 days culture. Removal rate of $NO_x-N$ was 95.6~99.95% with initial concentration of 35 mg $NO_x-N/l$, and the removal rate of $PO_4-P$ was also high, indicating 80.24~98.9% with initial concentration of 5.95 mg $PO_x-P/l$.

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A Filtered-X LMS Algorithm by New Error Path Identification Method for Adaptive Active Noise Control (적응 능동소음제어를 위한 오차경로 인식 방법을 통한 filtered-X LMS 알고리듬)

  • 권기룡;송규익;김덕규;이건일
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.8
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    • pp.1528-1535
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    • 1994
  • In this paper, a filtered-X LMS algorithm by new error path identification method is proposed for active noise control system. The proposed algorithm identifies accurately the error path transfer function using three microphones and the control of error signal through double loop scheme with on-line. In the computer simulation using the sinusoidal and the practical duct noise, the proposed algorithm reduces noise level about 29.1dB and 10.4dB, respectively. We can observe the improvement of about 0.5dB and 2.5dB in noise level compared with that obtained using the filtered-X LMS algorithm of Eriksson model.

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Prediction of Biodiesel Combustion, CO and NOX Emission Characteristics in Accordance with Equivalence Ratio (당량비 변화에 따른 바이오디젤 연소 및 CO, NOX 생성 특성 예측)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of the Korean Society of Combustion
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    • v.21 no.1
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    • pp.1-7
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    • 2016
  • This study was performed to provide the basic information of the combustion, CO and $NO_X$ characteristics of biodiesel in accordance with equivalence ratio. The closed homogeneous reactor model used for the analysis. The analysis conditions were set to 900 K of the initial temperature, 20 atm of initial pressure and equivalence ratio was changes from 0.6 to 1.4. The results of analysis were predicted and compared in terms of combustion temperature, combustion pressure, CO and $NO_X$ emissions. The results of combustion characteristics showed that ignition delay was decreased and the combustion temperature and combustion pressure was increased in accordance with equivalence ratio. CO emission was decreased in lean condition(${\Phi}$ < 1.0), however, CO emission was increased in rich condition(${\Phi}$ > 1.0) because oxygen supply insufficient. $NO_X$ emission showed the largest amount in condition 0.8 of equivalence ratio because the oxygen concentration was sufficient.

CCSDS PN PROCESSING SPEED OPTIMIZATION

  • Ahn, Sang-Il;Kim, Tae-Hoon;Koo, In-Hoi
    • Proceedings of the KSRS Conference
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    • 2007.10a
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    • pp.537-539
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    • 2007
  • Telemetry processing system requires minimum bit transition level in data streams to maintain a bit synchronization while receiving telemetry signal. PN code has a capability of providing the bit transition and is widely used in the packet communication of CCSDS. CCSDS PN code that generator polynomial is $h(x)=x^{8}+x^{7}+x^{5}+x^{3}+1$, and the random bit sequence that is generated from this polynomial is repeated with the cycle of 255 bits. As the resolution of satellite image increases, the size and transmission rate of data increases. To process of huge and bulky size of satellite image, the speed of CCSDS PN Processing is very important. This paper introduces the way of improving the CCSDS PN Processing speed through processing 128 bits at one time using the feature of cyclic structure that repeats after first 255 bytes by grouping the random bit sequence with 1 byte and Intel Streaming SIMD Extensions 2. And this paper includes the comparison data of processing speed between SSE2-applied implementation and not-applied implementation, in addition, the measured value of speed improvement.

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