• Title/Summary/Keyword: Water sample

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Quantitative determination of 3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone (MX) in chlorinated drinking water using sample enrichment followed by liquid-liquid extraction and GC-MS (시료 농축 후 액-액-추출과 GC-MS를 이용한 염소 소독 음용수중 3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone(MX)의정량 분석)

  • Kim, Hekap;Song, Byeong yeol
    • Analytical Science and Technology
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    • v.29 no.1
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    • pp.29-34
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    • 2016
  • This study explores the means by which MX can be effectively extracted from chlorinated water 3-Chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone (MX), a potent mutagen commonly found in chlorinated drinking water at concentrations of up to a few hundred ng/L, was quantitatively determined using sample enrichment followed by liquid-liquid extraction (LLE), derivatization to methylated form, and analysis with GC-MS. A 4-L water sample was enriched to a concentration of 0.4 L using a vacuum rotary evaporator at 30 ℃. MX in the water was extracted using ethyl acetate (100 mL × 2) as a solvent and MX in the extract was methylated with 10 % H2SO4 in methanol. MX was recovered at a rate of 73.8 %, which was higher than that (38.1 %) for the resin adsorption method. The limit of quantification and repeatability (as relative standard deviation) were estimated to be 10 ng/L and 2.2 %, respectively. This result suggested that LLE can be used for the determination of MX in chlorinated water as an alternative to more time-consuming resin adsorption method.

Determination of Water-holding Capacity of Porcine Musculature Based on Released Water Method Using Optimal Load

  • Joo, Seon-Tea
    • Food Science of Animal Resources
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    • v.38 no.4
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    • pp.823-828
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    • 2018
  • The purpose of this study was to evaluate the suitability of the released water (RW) method for measuring water-holding capacity (WHC) by pressure and filter-paper absorption within two thin plastic films. One hundred fifty pork loins with considerable variations in WHC (three pork qualities: PSE, pale, soft, and exudative; RFN, reddish-pink, firm, and nonexudative; and DFD, dark, firm, and dry; 50 pork loins in each pork quality group) were used to measure drip loss (DL)% and RW % after applying different loads (1.5, 2.0, 2.5, 3.0 and 3.5 kg). Percentages of DL and RW were significantly (p<0.05) different among pork quality groups. The RW % of 2.5 kg load sample was significantly (p<0.05) higher than that of 2.0 kg or 1.5 kg load sample. However, there were no significant (p>0.05) differences in RW % among 2.5 kg, 3.0 kg, and 3.5 kg load samples for all three pork quality groups. The RW % was highly and positively correlated (r>0.95; p<0.001) with DL %. The highest correlation was observed between DL % and RW % of 2.5 kg load sample (r=0.97; p<0.001). Among all RW loads within each quality groups, the highest correlation between DL % and RW % was observed for 2.5 kg load sample (r=0.43, 0.66, and 0.46 for PSE, RFN and DFD quality groups, respectively, p<0.001). These results imply that applying 2.5 kg load is the best for determination of RW %. It is recommended as a reference method to assess DL % of pork muscles.

Measuring Benefits of Providing Water for Environmental Improvement in Yeongdok Ohsip River: Considering Protest Bids and Distance-Decay Function in the Application of CVM (영덕오십천 환경개선용수 공급의 경제적 편익측정: CVM 적용에 있어 저항응답의 처리와 거리소멸함수)

  • Eom, Young Sook
    • Environmental and Resource Economics Review
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    • v.24 no.2
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    • pp.435-461
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    • 2015
  • Recently, Korean development Institute includes water for environmental improvement as an additional water demand category in water resources development project. In response to this change, this paper is to measure benefits of providing additional water in Yeondok Ohsip River by applying contingent valuation method. This study extended the conventional CVM design by incorporating distance variable into WTP function of dichotonomous choice responses and treated protest bids by estimating sample-selection models. The empirical analysis exhibited that more than 30% of respondents were categorized as protest bids and the mean of WTP from sample selection models were three times higher than that of the whole sample. In addition, the distance variable had significantly negative impact on sample WTP regardless of variables forms, and the geographical market area were more 400km, which implies that beneficiaries of water service would the households from the whole nation.

Characteristics and Prediction of Shear Strength for Unsaturated Residual Soil (풍화잔적토의 불포화전단강도 예측 및 특성연구)

  • 이인모;성상규;양일순
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.377-384
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    • 2000
  • The characteristics and prediction model of the shear strength for unsaturated residual soils was studied. In order to investigate the influence of the initial water content on the shear strength, unsaturated triaxial tests were carried out varying the initial water content, and the applicability of existing prediction models for the unsaturated shear strength was testified. It was shown that the soil - water characteristic curve and the shear strength of the unsaturated soil varied with the change of the initial water content. A sample compacted in the lower initial water content needs a higher suction to get the same degree of saturation while the shear strength of a sample with the lower initial water content displays a lower value. In order to apply the existing prediction models of the unsaturated shear strength to granite residual soils, a correction coefficient, α, on the internal friction angle, ø'was added.

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Experimental Study on the Channel Type Heat Sink to Maintain Proper Temperature Cycle of Bio-Sample (바이오 시료의 적정온도 사이클 유지를 위한 채널형 히트싱크에 대한 실험적 연구)

  • Jeong-Gyu Hwang;Sang-Hee Park
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.1
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    • pp.183-191
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    • 2023
  • This study was conducted experimentally to investigate the surface temperature of the heat sink, the air temperature in the flow channel and the sample temperature by changing the channel number of channel type heat sink and the air flow rate when heating and cooling the bio sample. The target temperature of the sample was 15℃ or less as the minimum value and 82℃ or more as the maximum value. In this study, the channel number of the heat sink(N = 1, 2, 4, 5, 10) and the air flow rate(Q=25, 42, 54m3/min) were varied. The bio sample was replaced with water, and the volume of water is 4mL. The size of the heat sink is 80x73x150mm and the material is aluminum. When cooling the sample, the surface temperature, the air temperature and the sample temperature were highly dependent on the number of channels and the flow rate. However, when the sample is heated, the surface temperature, air temperature and sample temperature do not depend on the number of channels and the flow rate. It was found that the conditions for satisfying the minimum temperature of 15℃ or less when cooling the sample were the number of channels N≥5 and the flow rate Q≥42m3/min. When heating the sample, the conditions to satisfy the maximum temperature of 82℃ or more are the number of channels N≤5 and the air flow rate Q≤42m3/min.

Microbiological Pollution Investigation of Spring water in Seogwipo city of Jeju Island (제주도내 서귀포시 해안가 저지대용천수의 미생물학적 오염도 조사)

  • Han, Yong-Jae;Kim, Man-Chul;Moon, Yung-Gun;Heo, Moon-Soo
    • Proceedings of the KAIS Fall Conference
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    • 2010.11b
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    • pp.1025-1028
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    • 2010
  • The bacteriological examination of spring water in Seogwipo-city was conducted. A total 11 spring water samples were performed from January to April, 2010. During the study period, the range of temperature was from 0.7 to $15.4^{\circ}C$, and result of the analyses showed that hydrogen ion concentrations (pH) for spring water was 0.33 to 7.8. salinity levels for sample average of 0.5 to 1.04‰, as the result of measuring dissolved oxygen (DO) for spring water showed that water dissolved oxygen were 1.02 to 7.14 mg/${\ell}$. The range of total coliform of spring water sample at 11 stations located in the designated spring water were <1.8~>1,600 MPN/100mL. And the range of geometric mean of total coliform were 1.9~117.1 MPN/100mL, The range of fecal coliform of spring water sample at 11 stations located in the designated spring water were <1.8~>1,600 MPN/100mL. And the range of geometric mean of fecal coliform were 1.8~68.1 MPN/100mL, respectively. Level of microbial contamination was examined in 11 samples for indication of bacterial contamination such as heterophic bacteria, EscherichiacoliO157;H7, salmonella spp., Vibrio parahaemolyticus, Staphylococcus aureus, Shigella spp. Were frequently detected from the spring water. Salmonella spp., S.aureus were detected in the range of $0{\sim}1.0{\times}10^1$, $0{\sim}3.0{\times}10^1$ CFU/ml, respectively. And the Escherichia coli O157;H7, Vibrio parahaemolyticus, Shigella spp. Were not detected from the examined spring water samples.

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Physical Properties of the Dietary Fiber Prepared from Lentinus edodes Mycelia (표고버섯 균사체 식이섬유 소재의 물리적 특성)

  • Lee, Byung-Woo;Kim, Tae-Jong;Choi, Soo-Hyun;Im, Geun-Hyung;Yoo, Moo-Young
    • Korean Journal of Food Science and Technology
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    • v.27 no.2
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    • pp.147-150
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    • 1995
  • The industrial procedure for the preparation of dietary fiber material from Lentinus edodes by drying and grinding process was developed. The chemical composition of dietary fiber of mycelia was as follows; crude protein: 16.16%, crude fat: 2.96%, crude ash: 3.25% and carbohydrates: 77.63%. The mycelia contained total dietary fiber of 54.5%. The 40 mesh pass of dietary fiber exhibited water-holding capacity 7.39g water/g and oil-holding capacity 2.03g oil/g, while $40{\sim}80$ mesh of dietary fiber had water-holding capacity 7.80g water/g and oil-holding capacity 2.77g oil/g.

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OPTIMAL DESIGN FOR CAPACITY EXPANSION OF EXISTING WATER SUPPLY SYSTEM

  • Ahn, Tae-Jin;Lyu, Heui-Jeong;Park, Jun-Eung;Yoon, Yong-Nam
    • Water Engineering Research
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    • v.1 no.1
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    • pp.63-74
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    • 2000
  • This paper presents a two- phase search scheme for optimal pipe expansion of expansion of existing water distribution systems. In pipe network problems, link flows affect the total cost of the system because the link flows are not uniquely determined for various pipe diameters. The two-phase search scheme based on stochastic optimization scheme is suggested to determine the optimal link flows which make the optimal design of existing pipe network. A sample pipe network is employed to test the proposed method. Once the best tree network is obtained, the link flows are perturbed to find a near global optimum over the whole feasible region. It should be noted that in the perturbation stage the loop flows obtained form the sample existing network are employed as the initial loop flows of the proposed method. It has been also found that the relationship of cost-hydraulic gradient for pipe expansion of existing network affects the total cost of the sample network. The results show that the proposed method can yield a lower cost design than the conventional design method and that the proposed method can be efficiently used to design the pipe expansion of existing water distribution systems.

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Electron Tunneling and Electrochemical Currents through Interfacial Water Inside an STM Junction

  • Song, Moon-Bong;Jang, Jai-Man;Lee, Chi-Woo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.71-74
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    • 2002
  • The apparent barrier height for charge transfer through an interfacial water layer between a Pt/Ir tip and a gold surface has been measured using STM technique. The average thickness of the interfacial water layer inside an STM junction was controlled by the amount of moisture. A thin water layer on the surface was formed when relative humidity was in the range of 10 to 80%. In such a case, electron tunneling through the thin water layer became the majority of charge transfers. The value of the barrier height for the electron tunneling was determined to be 0.95 eV from the current vs. distance curve, which was independent of the tip-sample distance. On the other hand, the apparent barrier height for charge transfer showed a dependence on tip-sample distance in the bias range of 0.1-0.5 V at a relative humidity of approximately 96%. The non-exponentiality for current decay under these conditions has been explained in terms of electron tunneling and electrochemical processes. In addition, the plateau current was observed at a large tip-sample distance, which was caused by electrochemical processes and was dependent on the applied voltage.

Automatic Titration for KMnO4 Consumption Test of Tap Water Using Personal Computer Camera (PC 카메라를 이용한 수돗물의 과망간산칼륨소비량 적정 자동화)

  • Lee, Hyeong-Choon
    • Journal of Environmental Health Sciences
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    • v.34 no.1
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    • pp.95-100
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    • 2008
  • An automatic titration system using a PC-camera with a color filter on its lens was used in the $KMnO_4$ consumption test of tap water and distilled water in relation to blank tests. The very faint pink color of titration end point could be effectively detected by using a yellow cellophane paper as a color filter. The average hue value (Havg) of 192 pixels in the image of the sample solution being titrated was computed and followed up at regular time intervals during titration in order to detect the titration end point. The Havg decrease of 2 degrees from the average of first 10 Havgs was regarded as reaching the end point. The volume of 0.01N $KMnO_4$ consumed by a tap water sample was $0.728{\pm}0.022ml$ in manual titration and $0.735{\pm}0.013ml$ in automatic titration (p=0.580). The volume of 0.01N $KMnO_4$ consumed by a distilled water sample was $0.383{\pm}0.015ml$ in manual titration and $0.367{\pm}0.015ml$ in automatic titration (p=0.252). The high p-values for t-test suggested that there were good agreements between manual and automatic titration data and the automatic method proposed in this article was considered to effectively replace the manual titration.