• Title/Summary/Keyword: Water sample

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A Study on the Measurement of Moisture Content in the Organic Soils (유기질토의 함수비 측정에 관한 연구)

  • Park, Sung-Sik;Choi, Sun-Gyu;Ryu, Ju-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.29 no.10
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    • pp.29-37
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    • 2013
  • Organic soils are widely distributed at Youngdong areas in Kangwon prefecture and Jeonbuk area. Such organic soils usually consist of undecomposed fiber materials. It is difficult to exactly measure the water content of such organic soils because some organic materials may decompose at $110^{\circ}C$ in drying oven. In this study, both drying oven and microwave oven methods are used to measure the water content of organic soils. Three different levels of oven temperature, $60^{\circ}C$, $80^{\circ}C$, and the standard temperature of $110^{\circ}C$, were used to measure the water content of organic soils in the 1st, 2nd, and 3rd day. The water content by microwave oven was measured for two different sample masses (30, 60 g) with five different measuring times (3, 6, 9, 12, 15 min.). As the temperature increased, the water content of organic soils increased due to the decomposition of organic materials in soils. The water content of some soils increased up to 2 times as the temperature was increased from $60^{\circ}C$ to $110^{\circ}C$. However, the water content was not changed after the 1st day, regardless of drying oven temperature and soil types. The water content by microwave oven became constant after 12 min. for the 30 g sample and 15 min. for the 60 g sample used. The measured water content by microwave oven was similar to that measured by drying oven at $60^{\circ}C$.

Environmental Evaluation of Fish Aquafarm off Baegyado in Yeosu by Multivariate Analysis (다변량분석에 의한 여수 백야도 어류양식장의 해양 환경분석)

  • LEE, Chang-Hyeok;KANG, Man-Gu;LIM, Su-Yeon;KIM, Jae-Hyun;SHIN, Jong-Ahm
    • Journal of Fisheries and Marine Sciences Education
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    • v.29 no.3
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    • pp.785-798
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    • 2017
  • This study was conducted to evaluated the surface(10 variables) and bottom(10 variables) water quality, and sediment(3 variables) in the cage fish farm off Baegyado in Gamak Bay using a multivariate analysis from January 2013 to November 2014. Generally, the environmental data did not show a certain tendency by months during two years investigated. The pairwise simple correlation matrices among variables were also shown. The first four principal components of the surface water in 2013 explain 93% of the total sample variance; the first principal component($z_1$) showed the freshwater inflow and/or precipitation, $z_2$, $z_3$ and $z_4$ related to freshwater inflow and/or precipitation, organic matters and eutrophy, respectively; the first four principal components of the bottom water in 2013 explain 93% of the total sample variance; the $z_1$, $z_2$ and $z_4$ related to freshwater inflow and/or precipitation, and $z_3$ water temperature. In 2014, at the surface water the first three principal components explain 87%; the $z_1$, $z_2$ and $z_3$ related to water temperature, eutrophy and freshwater inflow and/or precipitation, respectively; at the bottom water the first three principal components explain 93%; $z_1$, $z_2$ and $z_3$ related to water temperature, freshwater inflow and/or precipitation and eutrophy. Half of the principal components related to freshwater inflow and/or precipitation.

Photodegradation of Butachlor and Pyrazosulfuron-ethyl in Rice Paddy Water under Natural Sunlight

  • Ok, Junghun;Watanabe, Hirozumi;Cho, Junglai;An, Nanhee;Lee, Byungmo
    • Korean Journal of Environmental Agriculture
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    • v.33 no.2
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    • pp.134-137
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    • 2014
  • BACKGROUND: Dissipation of herbicides in paddy water varies significantly, being dependent on environmental conditions such as sunlight. The photodegradation under natural sunlight may be one of natural degradation routes of herbicides dissipation. Therefore, the aim of this study was to monitor the degradation of butachlor and pyrazosulfuron-ethyl in paddy water under natural sunlight. METHODS AND RESULTS: The 12 water sample bottles of treatment were covered by quart glass plates, which allow about 90% of UV radiation (280-2000 nm) to pass through, to minimize the UV attenuation. The other 12 water sample bottles of the control were covered by glass lids and wrapped with aluminum foils to prevent the sunlight. The concentration of butachlor and pyrazosulfuron-ethyl in paddy water samples bottles was monitored under ambient conditions with and without natural sunlight. The concentration of butachlor and pyrazosulfuron-ethyl for treatment decreased from $355.3{\mu}g/L$ to $37.8{\mu}g/L$ and from $10.5{\mu}g/L$ to $3.9{\mu}g/L$, respectively, during consecutive 21 days after herbicide application under natural sunlight. CONCLUSION: The concentration of butachlor in paddy water decreased quickly under ambient conditions with natural sunlight. The degradation of butachlor in paddy water was enhanced by the natural sunlight. However, the degradation of pyrazosulfuron-ethyl was insignificant under natural sunlight.

A Study on the Water-Purification Characteristics of Bio-Composite Planting Blocks (바이오 복합 식생블록의 수질정화 특성 연구)

  • Kim, Young-Ik;Yeon, Kyu-Seok;Choi, Joong-Dae;Kim, Ki-Sung;Seo, Ji-Yeon;Kim, Yong-Seong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.53 no.2
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    • pp.75-82
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    • 2011
  • This study was performed to evaluate the water purification properties of bio-composites planting blocks using oyster shell and effective microorganism that have high absorption ability of heavy metals and organics to develop environmentally friendly river embankment technique contained various factors such as oyster shells, effective microorganism, porous concrete and planting embankment block. To maximize greening effect, the seeds were arbitrarily sown. In addition, in order to analyze the effect of water quality purification after the planting, the samples were collected from each designated zone 1, 7 and 30 days after steeping in water. Then, the samples were analyzed in terms of seven test items such as SS, BOD, COD, T-N, T-P, pH, etc. on the basis of the test method for water pollution. The following conclusions were reached from the test result. As a result of analysis for water quality purification for the concrete block containing the effective microorganism, it was found that the values for SS, BOD, T-N and T-P for the sample taken after 30 days were lower than the initial values, which indicated that the water purification effect had been created. The result of the water quality purification analysis for the concrete block containing oyster shell showed that the values for SS, BOD, COD and T-P for the sample taken after 30 days were lower than the initial values which also indicated that it had been effective in water quality purification.

Influence of C/N ratio on biofim growth in tap water (수돗물의 C/N 비율이 생물막 생장에 미치는 영향)

  • Cho, Ji-Min;Kim, Yeong-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.6
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    • pp.527-533
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    • 2018
  • Microorganisms detected in the biofilm not only cause secondary pollution of drinking water such as taste, odor and pathogenic disease but also increase the amount of disinfectant due to microbial regrowth during the transportation of tap water. In this work, the influence of C/N ratio in tap water on the characteristics of biofilm growth was examined. The C/N ratio of the tap water sample was controlled at 100:5, 100:10, 100:20, 100:30, and 100:40 by adding appropriate amounts of dextrose and $(NH_4)_2SO_4$. Of the five C/N ratios, heterotrophic plate counts (HPC) was highest at the ratio of 100:10. Following the initial formation in all the five experimental conditions, natural detachment of the biofilm was observed. Extracellular enzyme activity (EEA) analyses showed that the change of the EEA during the experimental period was similar to that of the HPC, demonstrating a positive correlation between HPC and EEA. For TOC concentration in the tap water sample, approximately 75% of the TOC was consumed in 7 days of the experiment and 96% in 28 days. The TOC appeared to be relatively rapidly consumed at the initial phase of the biofilm growth. Consumption pattern of the ammonia nitrogen was different from the TOC consumption pattern showing the different role of ammonia nitrogen on the growth of biofilm.

Nutritional Components of Korean Auricularia polytricha(Mont.) sacc. Mushroom and Changes in Characteristics during Rehydration (한국산 털목이버섯의 영양성분과 수화조건에 따른 특성 변화)

  • Lee, Jong-Won;Lee, Seong-Kye;Do, Jae-Ho
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.724-728
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    • 1995
  • Chemical compositions of dried Auricularia polytricha mushroom were analyzed when the dried mushroom were soaked in distilled water at different soaking condition. Physicochemical properties of soaked mushroom were investigated. Compositions of chemical components were 12.6% crude protein, 2.1% crude fat, 6.7% crude fiber and 6.2% ash. The contents of Ca, K, Mg were higher than those of other minerals in the sample, but Mn and Ni were of little quantities. The major amino acids of the sample were found to be aspartic and glutamic acid. The increase in the soaking time and temperature increased the ratio of water uptake, amount of water soluble solid, browning and pH value in the soak water. Ribonucleotide contents of the sample after soaking decreased depending on soaking time and temperature.

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Speciation of Chromium in Water Samples with Homogeneous Liquid-Liquid Extraction and Determination by Flame Atomic Absorption Spectrometry

  • Abkenar, Shiva Dehghan;Hosseini, Morteza;Dahaghin, Zohreh;Salavati-Niasari, Masoud;Jamali, Mohammad Reza
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2813-2818
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    • 2010
  • A novel method was developed for the speciation of chromium in natural water samples based on homogeneous liquid-liquid extraction and determination by flame atomic absorption spectrometry (FAAS). In this method, Cr(III) reacts with a new Schiff's base ligand to form the hydrophobic complex, which is subsequently entrapped in the sediment phase, whereas Cr(VI) remained in aqueous phase. The Cr(VI) assay is based on its reduction to Cr(III) by the addition of sodium sulfite to the sample solution. Thus, separation of Cr(III) and Cr(VI) could be realized. Homogeneous liquid-liquid extraction based on the pH-independent phase-separation process was investigated using a ternary solvent system (water-tetrabutylammonium ion ($TBA^+$)-chloroform) for the preconcentration of chromium. The phase separation phenomenon occurred by an ion-pair formation of TBA and perchlorate ion. Then sedimented phase was separated using a $100\;{\mu}L$ micro-syringe and diluted to 1.0 mL with ethanol. The sample was introduced into the flame by conventional aspiration. After the optimization of complexation and extraction conditions such as pH = 9.5, [ligand] = $1.0{\times}10^{-4}\;M$, [$TBA^+$] = $2.0{\times}10^{-2}\;M$, [$CHCl_3$] = $100.0\;{\mu}L$ and [$ClO_4$] = $2.0{\times}10{-2}\;M$, a preconcentration factor (Va/Vs) of 100 was obtained for only 10 mL of the sample. The relative standard deviation was 2.8% (n = 10). The limit of detection was sufficiently low and lie at ppb level. The proposed method was applied for the extraction and determination of chromium in natural water samples with satisfactory results.

Determination of Zinc and Lead in Water Samples by Solvent Sublation Using Ion Pairing of Metal-Naphthoate Complexes and Tetra-n-butylammonium Ion

  • Kim, Yeong Sang;Choe, Yun Seok;Lee, Won;Lee, Yong Il
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.821-826
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    • 2001
  • Solvent sublation has been studied for the separation and determination of trace Zn(Ⅱ) and Pb(Ⅱ) in water samples. A synergy producing method was utilized to improve the efficiency of extraction in the sublation using an ion-pair of metal-naphth oate {M-(Nph)3- } complexes and tetra-n-butylammonium (TBA+ ) ion. After the M-(Nph)3- complexes were formed by adding 1-naphthoic acid to the sample solution, tetra-n-butylammonium bromide was added in the solution to form the ion-pair. And sodium lauryl sulfate (SLS) was added to make the ion-pair hydrophobic. The ion-pairs of the metal complexes were floated and extracted into methylisobutyl ketone (MIBK) from the aqueous solution by bubbling with nitrogen gas in a flotation cell. Metal ions in MIBK solution were measured by graphite furnace-AAS. Experimental conditions were optimized as follow so. After the pH of a 1.0 L water sample was adjusted to 5.0, 6.0 mL of 0.1 M 1-HNph and 10 mL of 0.03 M TBA-bromide were added to the sample to form ion-pairs, and 2.0 mL of 0.2%(w/v) SLS was added to make the ion-pairs hydrophobic. The solution was bubbled with 30 mL/min N2 gas for 5 minutes in a flotation cell. Linear calibration curves were obtained for the determination of Zn(Ⅱ) and Pb(Ⅱ) in several water samples. Reproducible results of showing a relative standard deviation of < 10% and recoveries of 80-100% could be obtained.

Properties of Pinus densiflora Timber Wood by High Temperature Linseed Oil Treatment (고온아마인유처리에 의한 소나무재의 특성)

  • Lee, Dong-heub;Lee, Myung-Jae;Oh, Hyung-Min;Son, Dong-won
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.2
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    • pp.50-57
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    • 2004
  • This study attempted to evaluate the water repellency and drying effectiveness of linseed oil treated-solid wood at high temperature by immersion. The moisture content of green wood (Pinus densiflora) sample (above 90%) was reduced about 10% after 6 hours treatment at 150℃. When the treated samples were cut into cross section along the length, it was observed that the linseed oil penetrated into up to 20% of the sample cross section area in all locations. However, a strength loss of the specimen was not detected. The pre-drilling before linseed oil treatment was effective in reducing the defects such as checks and splits, and improved the linseed oil penetration into all samples from the surfaces. The result of water absorption test of treated-wood showed that the water repellent efficacy of treated-wood was greater than that of the control. The anti-fungal activity of treated samples using five sap stains and thee decay fungi was not detected in broad-spectrum toxic mechanism. However, decay test using white rot fungi (Tyromyces palustris) and brown rot fungi (Trametes versicolor) showed that the treated sample has a decay resistance to these two fungi.