• Title/Summary/Keyword: Water diffusion coefficient

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Kinetic Studies on Hydration and Cooking of Rice (쌀의 수화 및 취반특성에 관한 속도론적 연구)

  • Cho, Eun-Kyung;Pyun, Yu-Ryang;Kim, Sung-Kon;Yu, Ju-Hyun
    • Korean Journal of Food Science and Technology
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    • v.12 no.4
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    • pp.285-291
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    • 1980
  • The hydration and cooking rate of two rice varieties, Akibare (Japonica) and Milyang 23 (Indica), were investigated in terms of mathematical rate equations. The hydration rate at temperatures of $10{\sim}40^{\circ}C$ was examined by weighing method. The absorption of liquid water by rice grain was directly proportional to the square root of the hydration time. The diffusion coefficient was given by the Arrhenius relation : $D=3.151{\times}10^{-3}\exp\;(-4000/RT)$ for Akibare and $D=5.853{\times}10^{-3}\exp\;(-5700/RT)$ for Milyang 23. Milyang 23 was cooked at a faster rate than Akibare. The activation energies for cooking were in the range of 18 000 cal/mole at $90{\sim}100^{\circ}C$ and 9,000cal/mole at $100{\sim}120^{\circ}C$. However, Milyang 23 showed slightly higher activation energy of cooking at $90{\sim}100^{\circ}C$. Adhesiveness and amylograph viscosities at all reference points for Milyang 23 were higher than those for Akibare.

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Seasonal properties of airborne chlorides to the result of 3 year-measurement (3년간의 측정결과에 따른 비래염분의 계절별 특성)

  • Lee, Jong-Suk;Ahn, Ki-Hong;Kim, Do-Gyeum;Lee, Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.573-576
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    • 2008
  • When the concrete structures are in contact with seawater, concentration of chloride for estimating chloride diffusion coefficient can be defined as the chloride concentration of sea water. However, in case the concrete structures, constructed in the seashore, aren't directly in contact with seawater, it is difficult to establish the interface concentration of chloride. In addition, marine concrete structures are greatly affected by salt attack such as rebar corrosion, among the cause of salt attack, airborne chlorides is primary factor. Therefore, in this study, salt attack environment by airborne chlorides was investigated in terms of a seasonal distribution at 72 spots, 27 areas in the East, West, South coast for 3 years from July '03 to June '06. Results indicated that in the East and South coast, the amount of the airborne chlorides is comparatively higher in summer, in the West coast, higher in winter according to the seasonal wind.

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Characteristics of Diffusion Coefficient of High Performance Concrete using GGBFS for Road Structures by Accelerating Test Method (슬래그 미분말 혼입률에 따른 도로구조물용 고성능 콘크리트의 압축강도 및 촉진 염소이온 확산 특성)

  • Han, Seong-Woo;Kim, Hong-Sam;Lee, Chan-Young;Cheong, Hai-Moon;Ahn, Tae-Song
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.885-888
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    • 2008
  • In recent years, the terminology "High-Performance Concrete(HPC)" has been introduced into the construction industry. Most high-performance concretes have a high cementitious content and a low water-cementitious material ratio. The proportions of the individual constituents vary depending on local preferences and local materials. Therefore, many trial batches are usually necessary before a successful mix is developed. The objective of this experiments is to investigate the fundamental properties of high performance concrete based binary cimentitious materials such as ordinary portland cement and ground granulated blast furnace slag. The results from the study will be utilized as the basic data and guideline in making standard mixproportions and the manufacture, construction work and quality control of HPC

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An experimental and analytical study of the sound wave propagation in beam formed from rubberized concrete material

  • Salhi Mohamed;Safer Omar;Dahmane Mouloud;Hassene Daouadji Nouria;Alex Li;Benyahia Amar;Boubekeur Toufik;Badache Abdelhak
    • Earthquakes and Structures
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    • v.27 no.2
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    • pp.127-142
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    • 2024
  • The amount of wave propagation through a rubber concrete construction is the subject of the current investigation. Rubber tire waste was used to make two different types of cement mixtures. One type contains sand substitute in amounts ranging from 15% to 60% of the total volume, while the other has gravel with diameters of 3/8 and 8/15 and 15% sand in the same mixture. A wide variety of concrete forms and compositions were created, and their viscous and solid state characteristics were assessed, along with their short-, medium-, and long-term strengths. Diffusion, density, mechanical strength resistance to compressive force, and ultrasound wave propagation were also assessed. The water-to-cement ratio and plasticizer were used in this investigation. In the second part of the study, an analytical model is presented that simulates the experimental model in predicting the speed of waves and the frequencies accompanying them for this type of mixture. Higher order shear deformation beam theory for wave propagation in the rubberized concrete beam is developed, considering the bidirectional distribution, which is primarily expressed by the density, the Poisson coefficient, and Young's modulus. Hamilton's concept is used to determine the governing equations of the wave propagation in the rubberized concrete beam structure. When the analytical and experimental results for rubber concrete beams were compared, the outcomes were very comparable. The addition of rubber gravel and sandy rubber to the mixture both resulted in a discernible drop in velocities and frequencies, according to the data.

Oxygen Transfer and Hydraulic Characteristics in Bubble Column Bioreactor Applied Fine Bubble Air Diffusing System (미세기포 산기장치를 적용한 타워형 생물반응기의 산소전달 및 수력학적 특성)

  • Lee, Seung-Jin;Ko, Kyeong-Han;Ko, Myeong-Han;Yang, Jae-Kyeong;Kim, Yong-Guk
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.11
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    • pp.772-779
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    • 2012
  • For improving performance of conical air diffuser generating fine bubble, both experimental and numerical simulation method were used. After adapting diffusers inner real scale bubble column, suitable for various diffuser submergence, the effect of diffuser submergence on oxygen transfer performance such as Oxygen Transfer Coefficient ($K_{L}a_{20}$) and Standard Oxygen Transfer Efficiency (SOTE) was investigated empirically. As flow patterns for various diffuser number and submergence were revealed throughout hydrodynamic simulation for 2-phase fluid flow of air-water, the cause of the change for oxygen transfer performance was cleared up. As results of experimental performance, $K_{L}a_{20}$ was increased slightly by 7% and SOTE was increased drastically by 39~72%, 5.6% per meter. As results of numerical analysis, air volume fraction, air and water velocity in bioreactor were increased with analogous flow tendency by increasing diffuser number. As diffuser submergence increased, air volume fraction, air and water velocity were decreased slightly. Because circulative co-flow is determinant factor for bubble diffusion and rising velocity, excessive circulation intensity can result to worsen oxygen transfer by shortening bubble retention time and amount.

Kinetic Studies on Cooking of Rice of Various Polishing Degrees (도정도별 쌀의 취반에 대한 역학적 연구)

  • Cheigh, Hong-Sik;Kim, Sung-Kon;Pyun, Yu-Ryang;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
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    • v.10 no.1
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    • pp.52-56
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    • 1978
  • The mechanism of cooking rice was investigated using a japonica type rice variety, Akibare, of 50%, 70% and 90% polishing degrees. The hardness of rice cooked at various cooking temperatures ($90^{\circ}-120^{\circ}C$) was measured with a Texturometer. The cooking rate followed the equation of a first-order reaction. The reaction rate constants were in the increasing order of 50%, 70% and 90% polished rice. The temperature coefficient of the reaction rate constant at cooking temperatures of ($90^{\circ}-100^{\circ}C$) was about 2 in all rice samples. The activation energies of cooking at temperatures below $100^{\circ}C$ and above $100^{\circ}C$ were about 17,000 and 9,000 cal/mole, respectively. The polishing degrees and water soaking time of rice did not affect the activation energy of cooking; however, the lower polishing degrees and shorter soaking increased the cooking time The experimental results suggested that the cooking process of rice comprises two mechanisms: At temperatures below $100^{\circ}C$ the cooking rate is controlled by the reaction rate of rice constituents with water, and at temperatures above $100^{\circ}C$, it is controlled by the rate of diffusion of water through the cooked portion (or layer) toward the interface of uncooked core in which the reaction is occurring.

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Characteristics of Percutaneous Absorption of Glycol ethers (Glycol ethers에 대한 피부 투과 특성)

  • Lee, Han-Seob;Choi, Sung-Boo;Kim, Nac-Joo;Keun, Jang-Hyoun;Hwang, Hyun-Suk;Baek, Jung-Hun;Choi, Jin-Ho;Lee, Ho-Joon
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.116-126
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    • 2013
  • Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol commonly used in paints. These solvents typically have a higher boiling point, together with the favorable solvent properties of lower-molecular weight ethers and alcohols. The word "Glycol ethers" was registered as a United States trademark by Union Carbide Corp. Typically, glycol ethers are found in pharmaceuticals, sunscreens, cosmetics, inks, dyes and water based paints. On the other hand, glycol ethers are used in degreasers, cleaners, aerosol paints and adhesives. Most glycol ethers are relatively water soluble, biodegradable and only a few are considered toxic. Therefore, they are unlikely to pose an adverse risk to the environment. Recent study suggests that occupational exposure to glycol ethers is related to low motile sperm count in men, but the finding has been disputed by others. In this study, skin permeation of 3 types glycol ethers were studied in vitro using matrix such as solvent and detergent. The absorption of glycol ethers[methyl glycol ethers(MC), ethyl glycol ethers(EC) and butyl glycol ethers(BC)] has been measured in vitro through rat skin. Epidermal membranes were set up in Franz diffusion cells and their permeability to PBS measured to establish the integrity of the skin before the glycol ethers were applied to the epidermal surface. Absorption rates for each glycol ethers were determined and permeability assessment made to quantify any irreversible alterations in barrier function due to contact with the esters. Types of glycol ethers in vitro experimental results on MC> EC> BC quickly appeared in the following order: skin permeation was beneficial to the skin permeation small molecular weight, the difference in chemical structure, such as hydrophilic, because with the partition coefficient and solubility mechanisms and passive diffusion to increase the speed at which transmission is considered.

A Comparative Study on Strength Development, Chloride Diffusivity and Adiabatic Temperature Rise of Marine Concrete Depending on Binder Type (결합재 종류에 따른 해양 콘크리트의 강도 발현, 염화물 확산 및 단열온도 상승 특성에 대한 비교 연구)

  • Bae, Jun-Young;Cho, Sung-Hyun;Shin, Kyung-Joon;Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.411-418
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    • 2013
  • Recently, in order to reduce a damage of chloride attack and hydration heat in marine concrete structures, blended cement in mixing the marine concrete is widely used. Long term strength development is distinct in concrete with blended cement and it also has excellent resistance to chloride attack and reduction of hydration heat. However, blended cement has a characteristic of relatively low compressive strength in early age of 28 days. On the other hand, a high level of compressive strength is required in the Standard Specification for marine concrete mix design. Such concrete mix design satisfying Standard Specification is effective to chloride attack but disadvantageous for hydration heat reduction due to large quantity of binder. In this study, the material properties of marine concrete considering water-binder ratio and binder type are experimentally investigated. Through the research results, compressive strength in blended cement at the age of 56 days is similar although it has smaller compressive strength at the age of 28 days compared with result of OPC (ordinary portland cement). Even though blended cement has a large water-binder ratio and small unit of binder content, chloride ion diffusion coefficient is still small and hydration heat is also found to be reduced. For meeting the required compressive strength in Standard Specification for marine concrete at 28 days, the increased unit content of binder is needed but the increased hydration heat is also expected.

Water Absoption of Stored Brown Rice in Laminated Film Pouch (플라스틱 적층필름 포장재를 이용한 현미의 저장중 수분흡수 특성 변화)

  • Han, Jae-Gyoung;Kang, Kil-Jin;Kim, kwan;Kim, Seong-Kon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.25 no.4
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    • pp.643-648
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    • 1996
  • The changes in hydration of brown rice, Chu-chung byeo(Japonica type) were determined during storage at different storage temperatures($4^{\circ}C$, 2$0^{\circ}C$, 3$0^{\circ}C$ and 4$0^{\circ}C$) in a 4-layered laminated film pouch(PET 12${\mu}{\textrm}{m}$/AI-foil 7${\mu}{\textrm}{m}$/o-Nylon 15${\mu}{\textrm}{m}$/L-Mix100${\mu}{\textrm}{m}$). At the beginning of storage, the hydration rate of brown rice increased with higher soaking temperature, and the activation energy of hydration was 10.3kcal/mole. Water diffusion coefficient of brown rice due to storage temperature during storage at 3$0^{\circ}C$ of soaking temperature was decreased by the elapse of storage periods and increment of storage temperature(below 3$0^{\circ}C$). ).

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Evaluation of Durability Performance in Concrete Incorporating Low Fineness of GGBFS (3000 Grade) (저분말도 고로슬래그 미분말(3000급)을 혼입한 콘크리트의 내구성능평가)

  • Lee, Seung-Heun;Cho, Sung-Jun;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.96-102
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    • 2019
  • When GGBFS(Ground Granulated Blast Furnace Slag) with high blaine is incorporated in concrete, compressive strength in the initial period is improved, but several engineering problems arise such as heat of hydration and quality control. In this paper, compressive strength and durability performance of concrete with 3,000 Grade-low fineness slag are evaluated. Three conditions of concrete mixtures are considered considering workability, and the related durability tests are performed. Although the strength of concrete with 3,000 Grade slag is slightly lower than the OPC(Ordinary Portland Cement) concrete at the age of 28 days, but insignificant difference is observed in long-term compressive strength due to latent hydration activity. The durability performances in concrete with low fineness slag show that the resistances to carbonation and freezing/thawing action are slightly higher than those of concrete with high fineness slag, since reduced unit water content is considered in 3,000 Grade slag mixture. For the long-term age, the chloride diffusion coefficient of the 3000-grade slag mixture is reduced to 20% compared to the OPC mixture, and the excellent chloride resistance are evaluated. Compared with concrete with OPC and high fineness GGBFS, concrete with lower fineness GGBFS can keep reasonable workability and durability performance with reduced water content.