• Title/Summary/Keyword: Water Droplets

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RHEOLOGICAL PROPERTIES OF OIL/WATER EMULSION AND OIL/LIQUID CRYSTAL/WATER SYSTEMS AND THEIR CONSUMER PERCEPTION IN HAIR CARE PRODUCTS

  • Kim, Chong-Youp;Hong, Jong-Eoun;Kim, Su-Hyun;Kang, Hak-Hee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.4 s.34
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    • pp.123-131
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    • 1999
  • Liquid crystal known as a rheological barrier to coalescence of oil droplets, increases emulsion stability, water-holding capacity and promotes active material penetration to skin. Some investigation for its rheological characteristics have been reported but its relations to consumer perception have been rarely published. In this study, oil/water emulsion and oil/liquid crystal/water systems were manufactured using the same composition or Behenyltrimethylammonium chloride/Cetostearyl alcohol/Lanolin oil. and rheological properties or each system were investigated with Cone and Plate rheometer. The formation of liquid crystalline phase was observed with polarized microscope and Differential Scanning Calorimeter. Continuous shear experiment, creep, yield and water holding capacity were measured for oil/water and oil/liquid crystal/water systems. The results were compared with sensory evaluations. Oil/liquid crystal/water system showed higher,viscosity at the same shear rate. higher viscoelasticity and higher yield stress than oil/water system. These properties were expected to show good spreadability and excellent richness without waxiness in hair can: products of creme type. This expectation was consistent with the results of sensory experiments. Water-holding capacity was evaluated by measuring residual water of specimens at specific temperature and relative humidity. Oil/liquid crystal/water system was proved to have higher ability to hold water in comparison with oil/water system. The results indicated that oil/liquid crystal/water system was of benefit to rheological properties creme type hair care products.

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A Physics-Based Modelling of Multipbase Fluid Phenomena (물리적 모델에 기반한 다상 유체 현상 애니메이션)

  • Song, Oh-Young;Shin, Hyun-Cheol;Ko, Hyeong-Seok
    • Journal of the Korea Computer Graphics Society
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    • v.10 no.3
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    • pp.52-60
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    • 2004
  • This paper presents a physically based technique for simulating complex multiphase fluids. This work is motivated by the "stable fluids" method developed by Stam to handle gaseous fluids. We extend this technique to water, which calls for the development of methods for modeling multiphase fluids and suppressing dissipation. We construct a multiphase fluid formulation by combining the Navier-Stokes equations with the level set method. By adopting constrained interpolation profile (CIP)-based advection, we reduce the numerical dissipation and diffusion significantly. We further reduce the dissipation by converting potentially dissipative cells into droplets or bubbles that undergo Lagrangian motion. Due to the multiphase formulation, the proposed method properly simulates the interaction of water with surrounding air, instead of simulating water in a void space. Moreover. the introduction of the non-dissipative technique means that, in contrast 10 previous methods, the simulated water does not unnecessarily lose mass and its motion is not damped to an unphysical extent. Experiments showed that the proposed method is stable and runs fast. It is demonstrated that two-dimensional simulation runs in real-time.

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Improvement of Dissolution Rate of Poorly Water Soluble Drug Using Self-microemulsifying Drug Delivery System (SMEDDS를 이용한 난용성 약물의 용출율 향상)

  • Kim, Kye-Hyun;Rhee, Yun-Seok;Bae, Joon-Ho;Chi, Sang-Cheol;Park, Eun-Seok
    • Journal of Pharmaceutical Investigation
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    • v.29 no.1
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    • pp.37-45
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    • 1999
  • ABSTRACT-A self-microemulsifying drug delivery system (SMEDDS) was developed to enhance the solubility and dissolution rate of poorly water soluble drug, biphenyl dimethyl dicarboxylate, DDB. The system was optimized by evaluating the solubility of DDB and the microemulsion existence range after the preparation of microemulsions with varying compositions of triacetin and surfactant-cosurfactant mixtures (Labrasol as surfactant (S) and the combination of Transcutol, Cremophor RH 40 and Plurol oleique as cosurfactant (CoS)). SMEDDS in this study markedly improved the solubility of DDB in water up to 10 mg/ml and the size of the o/w microemulsion droplets measured by dynamic light scattering showed a narrow monodisperse size distribution with an average diameter less than 50 nm. The microemulsion existing range is increased proportional to the ratio of S/CoS, however, it decreased remarkably as the oil content was more than 20%. In vitro dissolution study of SMEDDS showed a significantly increased dissolution rate of DDB in water (> 12 fold over DDB powder), and SMEDDS also had significantly greater permeability of DDB in Caco-2 cell compared to powders.

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Rheological Behaviour of Water-in-Oil Emulsions using Quaternium-18 Hectorite (쿼터늄-18 헥토라이트를 사용한 Water-in-Oil 에멀젼의 유변학적 거동)

  • Cho, Wan-Goo;Kim, Byung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.407-414
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    • 2009
  • Water-in-Oil (W/O) emulsions are widely used in cosmetics. However, O/W (Oil-in-Water) emulsions are generally superior to W/O emulsions in terms of stability. In this study, we investigated the changes of viscosity, the size of emulsion droplets, and rheological properties of emulsions prepared using distearyldimonium chloride (DDC), magnesium aluminum silicate (MAS) and quaternium-18 hectorite (QH). In addition to the changes of the composition, we tested the condition of homogenization including rotation per minute of the mixer and the mixing time. The viscosity of emulsions with DDC and AMS were not changed with time and the stability of emulsions was stable during the storage time. However, the fluidity of emulsions were low due to the forming gel network in the emulsions. The gelling power of the emulsions with QH was rather weaker than that of the emulsions with DDC and MAS. The viscosity of emulsions with QH was gradually reduced and the phase separation of emulsions with high concentration of oil was observed throughout the storage time, however, the stability of emulsions with DDC, MAS and QH was excellent, the fluidity of emulsions was enhanced, and the viscosity of emulsions was sustained for a long time after setting of emulsions.

A Physics-Based Modelling of Multiphase Fluid Phenomena (물리적 모델에 기반한 다상 유체 현상 애니메이션)

  • Song, Oh-Young;Shin, Hyun-Cheol;Ko, Hyeong-Seok
    • Journal of the Korea Computer Graphics Society
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    • v.10 no.4
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    • pp.13-21
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    • 2004
  • This paper presents a physically based technique for simulating complex multiphase fluids. This work is motivated by the "stable fluids" method developed by Stam to handle gaseous fluids. We extend this technique to water, which calls for the development of methods for modeling multiphase fluids and suppressing dissipation. We construct a multiphase fluid formulation by combining the Navier-Stokes equations with the level set method. By adopting constrained interpolation profile (CIP)-based advection, we reduce the numerical dissipation and diffusion significantly. We further reduce the dissipation by converting potential1y dissipative cel1s into droplets or bubbles that undergo Lagrangian motion. Due to the multiphase formulation, the proposed method properly simulates the interaction of water with surrounding air, instead of simulating water in a void space. Moreover, the introduction of the non-dissipative technique means that, in contrast to previous methods, the simulated water does not unnecessarily lose mass and its motion is not damped to an unphysical extent. Experiments showed that the proposed method is stable and runs fast. It is demonstrated that two-dimensional simulation runs in real-time.

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A Study for the Effect of Liquid Droplet Impingement Erosion on the Loss of Pipe Flow Materials (배관 재질 손상에 미치는 액적충돌침식의 영향에 대한 연구)

  • Kim, Kyung Hoon;Cho, Yun Su;Kim, Hyung Joon
    • Journal of ILASS-Korea
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    • v.18 no.1
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    • pp.9-15
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    • 2013
  • Wall thinning of pipeline in power plants occurs mainly by flow acceleration corrosion (FAC), cavitation erosion (C/E), liquid droplet impingement erosion (LDIE). Wall thinning by FAC and C/E has been well investigated; however, LDIE in plant industries has rarely been studied due to the experimental difficulty of setting up a long injection of highly-pressurized air. In this study, we designed a long-term experimental system for LDIE and investigate the behavior of LDIE for three kinds of materials (A106B, SS400, A6061). The main control parameter was the air-water ratio (${\alpha}$), which was defined as the volumetric ratio of water to air (0.79, 1.00, 1.72). In order to clearly understand LDIE, the spraying velocity (${\nu}$) of liquid droplets was controled larger then 160 m/s and the experiments were performed for 15 days. Therefore, this research focuses relation between erosion rate and air-water ratio on the various pipe-flow materials. NPP(nuclear power plant)'s LDIE prediction theory and management technique were drawn from the obtained data.

THE STABILITY OF ALL-TRANS-RETINOL IN NOVEL LIQUID CRYSTALLINE OW EMULSION

  • Kang, H.H.;Cho, J.C.;Lee, J.H.;Lee, O.S.
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.111-115
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    • 1998
  • We investigated the stability of all-trans-retinol on the liquid crystalline O/W emulsion composed of mainly alkyl polyglycerine, alkyl polyglucose and glycerine, and compared the activity of all-trans-retinol in the various forms of liquid crystal. Under certain conditions, novel liquid crystalline gel was formed around oil droplets, and layers of this liquid crystalline gel were very wide and rigid. (SWLC; Super Wide Liquid Crystal) SWLC was very helpful to stabilize retinol in O/W emulsion. After storage at 45 C for 4 weeks, all-trans-retinol in O/W emulsion composed of SWLC retained above 85% of the activity upon HPLC analysis, whereas those within no liquid crystalline emulsion gave 47% and normal liquid crystalline emulsion composed of fatty alcohols gave 40 60%. Retinol in oil phase is nealy insoluble in pure water, but in cosmetic emulsion systems can be slightly solubilized into water because emulsifiers and polyols in emulsion systems function as solubilizers. In this case, water in outer phase acts as a media for oxygen transporation$.$and thus destabilizes retinol. As a result, retinol in O/W emulsion has a tendency to become unstable. SWLC surrounding oil droplet which contains retinol is wide and rigid, therefore reduces contact between inner phase and outer phase To make SWLC, properties of emulsifiers are very important phase transition temperature should be high, and the structure of surfactants should be bulky, and their ratio should be suitable to make rigid and wide liquid crystalline gel layer in order to reduce contact between retinol in inner phase and water in outer phase.

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De-icing of the hydrophobic treated nanoporous anodic aluminum oxide layer (소수성 처리된 나노다공성 알루미늄 양극산화피막의 제빙)

  • Shin, Yeji;Kim, Jinhui;Shin, Dongmin;Moon, Hyung-Seok;Lee, Junghoon
    • Journal of the Korean institute of surface engineering
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    • v.54 no.5
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    • pp.222-229
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    • 2021
  • Icing causes various serious problems, where water vapor or water droplets adhere at cold conditions. Therefore, understanding of ice adhesion on solid surface and technology to reduce de-icing force are essential for surface finishing of metallic materials used in extreme environments and aircrafts. In this study, we controlled wettability of aluminum alloy using anodic oxidation, hydrophobic coating and lubricant-impregnation. In addition, surface porosity of anodized oxide layer was controlled to realize superhydrophilicity and superhydrophobicity. Then, de-icing force on these surfaces with a wide range of wettability and mobility of water was measured. The results show that the enhanced wettability of hydrophilic surface causes strong adhesion of ice. The hydrophobic coating on the nanoporous anodic oxide layer reduces the adhesion of ice, but the volume expansion of water during the freezing diminishes the effect. The lubricant-impregnated surface shows an extremely low adhesion of ice, since the lubricant inhibits the direct contact between ice and solid surface.

Surface-modified Cellulose Nanofibril Surfactants for Stabilizing Oil-in-Water Emulsions and Producing Polymeric Particles (표면 개질된 나노피브릴화 셀룰로오스를 이용한 에멀젼 안정화 및 고분자 입자 제조)

  • Kim, Bo-Young;Moon, Jiyeon;Yoo, Myong Jae;Kim, Seonmin;Kim, Jeongah;Yang, Hyunseung
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.110-116
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    • 2021
  • In this work, the surface of hydrophilic cellulose nanofibrils (CNFs) was modified precisely by varying amounts of cetyltrimethylammonium bromide (CTAB) to produce CNF-based particle surfactants. We found that a critical CTAB density was required to generate amphiphilic CTAB-grafted CNF (CNF-CTAB). Compared to pristine CNF, CNF-CTAB was highly efficient at stabilizing oil-in-water Pickering emulsions. To evaluate their effectiveness as particle surfactants, the surface coverage of oil-in-water emulsion droplets was determined by changing the CNF-CTAB concentration in the aqueous phase. Furthermore, styrene-in-water stabilized by CNF-CTAB surfactants was thermally polymerized to produce CNF-stabilized polystyrene (PS) particles, offering a great potential for various applications including pharmaceuticals, cosmetics, and petrochemicals.

Development of Glass-Beads Rainbow Experimental Apparatus for Analyzing the Principle of Rainbow Formation (무지개 생성 원리 분석을 위한 유리구슬 무지개 실험장치 개발)

  • Son, Moonkyu;Kwon, Munho;Choi, Ho-Meoyng
    • Journal of Science Education
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    • v.45 no.3
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    • pp.326-335
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    • 2021
  • In this study, we developed an experimental apparatus to study the principle of rainbow formation. The rainbow is formed through the dispersion, reflection, and refraction of light on water droplets. However, the rainbow cannot be made from a single drop of water. Thus, we devised an apparatus to observe the principle behind the rainbow formation caused by light rays on many water drops. This we deemed would help students understand the formation of the rainbow. We used glass beads as water drops to reproduce the rainbow phenomena. We also materialized the rainbow by changing various variables such as the position of the observer and the height of the light source, etc.