• Title/Summary/Keyword: Waste gas treatment

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Characteristics of Bio-oil by Pyrolysis with Pig Feces (돈분을 이용한 열분해공정 바이오오일의 특성)

  • Kun, Zhu;Choi, Hong L.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.4
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    • pp.57-63
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    • 2008
  • The characteristics of the bio-oil produced by the pyrolysis process with pig feces was investigated in this paper. The continuous auger-type reactor produced bio-oil was maintained at the temperature range of 400 to $600^{\circ}C$, which was higher than a typical that in a conventional pyrolysis system. The pig feces was used as the feedstock. The bio-oil and its compositions were characterized by water analysis, heating values, elemental analysis, bio-oil compounds, by Gas Chromatography/Mass Spectrometry (GC/MS), and functional group by $^1H$ NMR spectroscopy. It was found that the maximum bio-oil yields of 21% w.t. was achieved at $550^{\circ}C$. This result suggested that this auger reactor might be a potential technology for livestock waste treatment to produce bio-oil because it is able to be improved to reach higher efficiency of bio-oil production in further study. The pyrolysis system reported herein had low heat transfer into the feedstock in the auger reactor so that it needs improve the heat conduction rate of the system in further study.

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Synthesis of $LiCoO_{2}$ Nanoparticles From Leach Liquor of Lithium Ion Battery Wastes by Flame Spray Pyrolysis

  • Lee Churl Kyoung;Chang Hankwon;Jang Hee Dong;Sohn Jeong-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.37-43
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    • 2005
  • [ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

미소조류의 응용연구(개관) (Applied Researches on Microalgae(Overview))

  • YIH Won-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.25 no.3
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    • pp.205-218
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    • 1992
  • Trends in the applied microalgal researches were described as those in two separate periods. During the first period (earlie. than 1970) . most researches were oriented to using the whole microalgal cells as feed, food, fertilizer, and agent for the treatment of organic waste water. Since early 1970's (the second period) the number of researches on the production of specific cell metabolites has grown so rapidly. Many researchers endeavored after the very expensive 'natural products' form microalge such as vitamins, amino acids, $\beta-carotene$, phycofluor, pharmaceuticals, biologically active compounds, $H_2$ gas, and deutrated chemicals. On the other hand, the applied microalgal researches in Korea are still in the early stage of developments, and urgent activation of the related researchers is quite important to meet the future needs in the microalgal products. Systems for the management of the management of the microalgal clonal cultures from Korean waters should be established soon, which will support many microalgal researchers in Korea.

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Information security auditing Framework in Industrial control system (산업제어시스템 정보보안 감리 프레임워크 연구)

  • Lee, Chul-Soo
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.18 no.1
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    • pp.139-148
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    • 2008
  • Information technology have led to change the automation of large industrial control system as well as business system and environments. Industrial control system(ICS) is vital components of most nation's critical infrastructures such as electricity, natural gas, water, waste treatment, transportation and communication that are based of national security, safety of citizen and development of national economy According to the change of business environment, organizational management pushed integration all of the system include MIS and ICS. This situation led to use standard information technologies for ICS, this transition has been to expose ICS to the same vulnerabilities and threats that plague business system. Recently government obliged owners of the public information system to audit for safety, efficiency and effectiveness, and also obliged the owners of national infrastructure to improve their system security as a result of vulnerability analysis. But there doesn't prepare a security architecture and information security auditing framework of ICS fur auditing. In this paper, I suggested the security architecture and information security auditing framework for ICS in order to prepare the base of industrial system security auditing.

Synthesis of DMDBTDMA and determination of radiolysis products by GC/MS (DMDBTDMA의 합성 및 방사선 분해산물의 GC/MS 분석)

  • Yang, Han-Beom;Lee, Eil-Hee;Park, Gyo-Beom
    • Analytical Science and Technology
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    • v.21 no.5
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    • pp.403-411
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    • 2008
  • Dimethyldibutyltetradecylmalonamide (DMDBTDMA) extractant was used in a solvent extraction process for a radioactive liquid waste treatment. For the study of radiolysis phenomena, DMDBTDMA was synthesized and the degradation compounds (n-methylbutylamine, tetradecane, 1-tetradecanol) in the DMDBTDMA extractant, irradiated with $^{60}Co$ gamma ray, were identified and determined as radiolysis products by a Fourier transform infrared (FT-IR), gas chromatograph/mass spectrometer (GC/MS) analysis and GC/MS with selected ion monitoring (SIM) mode. Retention behavior of n-methylbutylamine, n-dodecane, tetradecane and 1-tetradecanol in the total ion chromatogram with the standard materials and n-dodecane as the internal standard (ISTD) were 2.35 min., 8.83 min., 10.68 min. and 12.75 min., respectively. In the case of tetradecane, there was a linear relationship between the concentration of the tetradecane and the absorbed dose of the ${\gamma}$-ray irradiated DMDBTDMA.

A Study on the Environmental Review through the Life Cycle Assesment Method of End-of-life Vehicle Dismantling Technology Via Indoor Rail Type (레일형 옥내화 자동차해체시스템의 전과정평가 방법을 통한 환경영향평가에 관한 연구)

  • Kim, DaeBong;Park, JeChul;Park, Jungho;Ha, SeongYong;Sung, Jonghwan
    • Resources Recycling
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    • v.25 no.6
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    • pp.13-22
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    • 2016
  • This study is aimed at compare and evaluate the environmental impact of End-of-Life Vehicle(ELV) on the eco-friendly technology dismantling and recycling system, using Life Cycle Assessment (LCA) method. In this study, it was analyzed for the environmental impacts of raw materials, disassemble process, recycle parts separation and waste treatment into the process of ELV treatment by greenhouse gas and resource consumption, etc. Through this study, the indoor rail type dismantling technology were recycling rate applied on the alternate system was increased by approximately 8%. As a result, it was 3 to 88% by improving the environmental impact category. In addition, the added benefit of approximately 8 - 62% in pre-market occurred through the recycling rate, improve parts reuse rate of ELV. Through the results of this study, legal compliance, improved reuse and recycling ratio, used parts market reach, enable exports has identified the need for the effort that the dissemination and diffusion of eco-friendly technology.

Characteristics of Stabilization of Excavated Solid Wastes by Aerobic and Anaerobic Landfilling (호기 및 혐기매립에 의한 굴착폐기물의 안정화 특성 연구)

  • Park, Jin-Kyu;Oh, Dong Ik;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.3
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    • pp.76-85
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    • 2004
  • Anaerobic decomposition of municipal solid waste (MSW) had potential adverse impacts such as the production of methane and long-term post closure on human health and the environment. It was demonstrated that aerobic degradation of MSW resulted in the reduction of a methane yield and the enhancement of stabilization of MSW. Excavated solid wastes were both aerobically and anaerobically treated in order to evaluate the effects of air injection on the stabilization of landfill site. The municipal solid waste (MSW) samples were excavated from a 10-year old landfill (operation period: 1991. 11~1994. 11), Jeonju, Korea. Excavated municipal solid wastes are primarily composed of soils and vinyl/plastics. For the two aerobic simulated lysimeters, the levels of $O_2$ ranged 1.6~23.1% and the levels of $CO_2$ ranged 1.5~15.1%, which confirmed the aerobic decomposition. Aeration did prevent methane formation. For the anaerobic simulated lysimeter, the $CO_2$ rose as $O_2$ was consumed and low levels of CH4 were produced. The pH levels ranged from 7.7 to 8.9 for anaerobic lysimeter and from 7.3 to 8.5 for aerobic lysimeters. As expected, aerobic treatment proved to enhance the removal of biodegradable materials in the excavated solid wastes when monitoring the concentration of BOD, COD, $NH_4-N$, and $NO_3-N$ in the leachate.

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Chemical Composition and Biological Activities of Essential Oil from 'Setoka' Branches (세토카 가지 정유의 성분 분석 및 생리 활성)

  • Hyun, Ju Mi;Kim, Jung Eun;Yeum, Hyun Sook;Song, Jung-Min;Kim, Mi Ryang;Lee, Nam Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.3
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    • pp.227-233
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    • 2016
  • This study was designed to analyze the chemical compositions of 'Setoka' branch essential oils (SEBO) and to test their biological activities. 'Setoka' is a Citrus species widely cultivated in Jeju Island. At the present, 'Setoka' branches produced by thinning process were mostly discarded as a waste. Therefore, utilization of this branch waste has received much attention. 'Setoka' branch essential oils (SBEO) were prepared by treatment of its ethanol extracts with jojoba oil. SBEO were chemically analyzed using gas chromatograph-mass spectrometry (GC-MS), and following components were identified; ethyl linoleate (64.14%), ethyl palmitate (16.50%), neophytadiene (11.06%) and beta-citronellol (5.09%). The anti-inflammatory activity in the SBEO was examined using RAW 264.7 murine macrophage cells stimulated with LPS. As a result, the SBEO inhibited nitric oxide (NO) productions with a dose-dependent manner. In addition, SBEO showed good anti-microbial activities against drug-susceptible and -resistant skin pathogens such as Staphylococcus aureus and Propionibacterium acnes, which are acne-causing bacteria. Based on these results, we suggest that SBEO has the possibility for use as an anti-inflammatory and anti-microbial agent in cosmetic applications.

Trend and Future Strategy of Ammonia Gas Recovery based on Adsorption from Livestock Fields (축산현장에서 발생된 암모니아 기체의 흡착기반 회수 동향 및 향후 전략)

  • Sangyeop Chae;Kwangmin Ryu;Sang-hun Lee
    • Resources Recycling
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    • v.32 no.6
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    • pp.45-53
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    • 2023
  • This study discussed the trend and future strategy of adsorption technology R&D to effectively recover ammonia emitted from the livestock fields. A proper ammonia adsorbent should incorporate acidic or hydrogen bonding functional groups on the surface, as well as a high specific surface area and a good surface structure appropriate for ammonia adsorption. Activated carbon and minerals such as zeolite have widely been used as ammonia adsorbents, but their adsorption effects are generally low, so any improvement through surface modification should be necessary. For example, incorporation of metal chloride included in a porous adsorbent can promote ammonia adsorption effectiveness. Recently, new types of adsorbents such as MOFs (Metal-Organic Frameworks) and POPs (Porous Organic Polymers) have been developed and utilized. They have shown very high ammonia adsorption capacity because of adjustable and high specific surface area and porosity. In addition, Prussian Blue exhibited high ammonia adsorption and desorption performance and selectivity. This looks relatively advantageous in relation to the recovery of ammonia from livestock waste discharge. In the future, further research should be made to evaluate ammonia adsorption/desorption efficiency and purity using various adsorbents under conditions suitable for livestock sites. Also, effective pre- and/or post-treatment processes should be integrated to maximize ammonia recovery.

Study on $CaCO_3$ Preparation from MSWI Fly Ash (생활쓰레기 소각(燒却)비산재로부터 $CaCO_3$ 제조(製造)에 관한 연구(硏究))

  • Choi, Woo-Zin;Park, Eun-Kyu
    • Resources Recycling
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    • v.15 no.5 s.73
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    • pp.47-51
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    • 2006
  • The total amount of ash generated from the municipal solid waste incineration(MSWI) in Korea was approximately 420,000 tons in 2005 including 68,000 tons of fly ash. Fly ash from MSWI generally contains high amount of CaO (upto ${\sim}50%$) due to the treatment of flue gas by spraying CaO-base materials. Currently, most of fly ash generated is finally ended up with specially designed landfill sites and only less then 20% of fly ash is recycled. In the present work, preparation of $CaCO_3$ from the MSWI ny ash was studied to promote the fly ash recycling. Fly ash obtained from the dust collector in stoker-type MSWI is used to selectively dissolve CaO by using the sugar solution. Then, $CO_2$ gas was passed through the dissolved solution to pro- duce $CaCO_3$ powder. The optimum conditions for CaO dissolution were solid content 10%, reaction time 15 minutes, sugar concentration $10{\sim}15%\;and\;pH\;10.5{\sim}11.0$. The high grade $CaCO_3$ powder was obtained and the experimental conditions are also discussed.