• Title/Summary/Keyword: WAsP Engineering

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Influence of fly ash and GGBFS on the pH value of cement mortar in different curing conditions

  • Shafigh, Payam;Yousuf, Sumra;Ibrahim, Zainah;Alsubari, Belal;Asadi, Iman
    • Advances in concrete construction
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    • v.11 no.5
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    • pp.419-428
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    • 2021
  • The pH of cement-based materials (CBMs) is an important factor for their durability, sustainability, and long service life. Currently, the use of supplementary cementitious materials (SCMs) is becoming mandatory due to economic, environmental, and sustainable issues. There is a decreasing trend in pH of CBMs due to incorporation of SCMs. The determination of numerical values of pH is very important for various low and high volume SCMs blended cement mortars for the better understanding of different defects and durability issues during their service life. In addition, the effect of cement hydration and pozzolanic reaction of SCMs on the pH should be determined at initial and later ages. In this study, the effect of low and high-volume fly ash (FA) and ground granulated ballast furnace slag (GGBFS) cement mortars in different curing conditions on their pH values has been determined. Thermal gravimetric analysis (TGA) was carried out to support the findings from pH measurements. In addition, thermal conductivity (k-value) and strength activity indices of these cement mortars were discussed. The results showed that pH values of all blended cement mortars were less than ordinary Portland cement (OPC) mortar in all curing conditions used. There was a decreasing tendency in pH of all mortars with passage of time. In addition, the pH of cement mortars was not only dependent on the quantity of Ca(OH)2. The effect of adding SCMs on the pH value of cement mortar should be monitored and measured for both short and long terms.

Influence of P and Mg Additions on the Mechanical Properties and Electrical Conductivity of Cu-Sn Based Alloys (Cu-Sn계 합금의 기계적 성질과 전기전도도에 미치는 P 및 Mg 첨가의 영향)

  • Kim, Jeong-Min;Park, Joon-Sik;Kim, Ki-Tae
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.6
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    • pp.318-322
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    • 2007
  • The high electrical conductivity Cu-0.15% Sn alloys containing various P contents, and the high conductivity and high strength Cu-0.1% Sn-0.1%Ag alloys with various Mg/P additions were fabricated and their mechanical properties and electrical conductivity were investigated. The electrical conductivity was generally decreased as the P content was increased where as the hardness and strength was shown to increase. When Mg was added to P-containing Cu alloys, the detrimental effect of P on the conductivity was significantly reduced, and TEM observations indicated that the formation of $Mg_3P_2$ phase is responsible for this result.

Evaluation of the Quality of Beef Patties Formulated with Dried Pumpkin Pulp and Seed

  • Serdaroglu, M.;Kavusan, H.S.;Ipek, G.;Ozturk, B.
    • Food Science of Animal Resources
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    • v.38 no.1
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    • pp.1-13
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    • 2018
  • The objective of this study was to investigate quality attributes of beef patties formulated with dried pumpkin pulp and seed mixture (PM). Four different meatball formulations were prepared where lean was replaced with PM as C (0% PM), P2 (2% PM), P3 (3% PM) and P5 (5% PM). Utilization of PM decreased moisture and increased ash content of the patties. Incorporation of 5% PM (P5) increased the pH value of both uncooked and cooked patties compared to C group. Increasing levels of PM increased water-holding capacity. No significant differences were found in cooking yield and diameter change with the addition of PM. Incorporation of PM increased fat and decreased moisture retention of the samples. $a^*$ values were decreased with PM addition, where $L^*$ values did not differ among treatments and $b^*$ values were similar in C, P3 and P5 samples. Textural properties were mostly equivalent to control samples with the incorporation of PM even at higher concentrations. The addition of PM did not significantly affect any of the sensory scores tested. These results indicated that utilization of PM presents the opportunity to decrease the amount of meat besides to improve healthier profile without causing negative changes in physical, chemical and technological quality of beef patties.

Evaluation of Fire Characteristics for Particle-board with Exfoliated Graphite Nanoplatelets Added (탄소재료의 적용 방법에 따른 파티클 보드의 연소 특성)

  • Seo, Hyun Jeong;Jo, Jeong Min;Hwang, Wuk;Lee, Min Chul
    • Journal of the Korean Society of Combustion
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    • v.22 no.4
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    • pp.1-8
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    • 2017
  • This study was conducted to evaluate the fire retardant performance of exfoliated graphite nanoplatelets (xGnP) applied for particleboard. This work measured heat release rate(HRR), total heat release(THR) and smoke production rate(SPR) of xGnP added particleboard, using cone calorimeter to assess its fire characteristics according to the KS F ISO 5660-1 standard code. Heat release rates of all specimens treated by xGnP were less than the $200kW/m^2$ for a total experiment period of five minutes. Heat release rates of the specimens coated with xGnP were lower than those of the specimens made by mixing wood particles with xGnP directly. Meanwhile, the total heat release rates of xGnP coated specimen maintained quite lower level than the uncoated so the xGnP coating were effective in improving the fire retardant performance of particleboard. However, the smoke emission peaking problem at the initial combustion period, which was caused by adding base coating materials, should be resolved for further satisfaction as a fire retardant materials.

Characteristics for removal of As(V) using Phosphorylated Pine needles (인산화 솔잎을 이용한 비소(As)제거 특성)

  • Kwon, Taik Nam;Kim, Hyun Ah;An, Seon Jin;Lee, Chang Hee;Jeon, Choong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.1
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    • pp.79-85
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    • 2011
  • A study on characteristics for removal of arsenic ion using phosphorylated pine needles was performed. The surface condition of phosphorylated pine needles was confirmed by FT-IR, SEM(Scanning Electron Microscopy) and EDX(Energy Dispersive X-ray). The removal rate of arsenic ion was the highest as about 98% at pH 7. Most absorption for arsenic ion was also completed within 30min and decreased with time and pH of arsenic solution from 6.5 to 2.4.

State Evaluation of Nutrient Removal in an Intermittent Aeration Process by Monitoring ORP & pH (ORP와 pH 측정에 의한 간헐폭기 고도처리 공정 제어의 평가)

  • Ko, Kwang Baik;Suh, Jun Suk
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.401-409
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    • 2002
  • In this study, to evaluate the applicability of ORP and pH as process control parameters for an intermittent aeration process, a 200L/d bench-scale plant was installed and operated for 90 days. It was fed with synthetic wastewater which contained $COD_{Cr}$ : 400mg/L, TN : 40mg/L and TP : 7mg/L. ORP & pH were measured on-line and compared with the variation of nutrient concentrations. As the results, both of the ORP and pH were able to monitor successfully nitrification and denitrification. Bending-points on the ORP curve and peak points on the pH curve corresponded to the termination of nitrification and denitrification. For P uptake and release, pH was the best indicator for performance evaluation. The aerobic pH apex was appeared when P uptake was accomplished and there was a relationship between the P release and pH variation. But the pH curve needed filtering because there were many noises on it. In this study, the shape of the ORP & pH curves were varied as the operating conditions such as aeration rates and organic loads were changed. It allowed the operating states of biological systems to be effectively evaluated. If it is properly managed to show the bending points and peak points clearly, the on-line monitoring of ORP & pH will be a reliable and effective technique for process control of intermittent aeration processes.

Effect of pH on Swelling Property of Hyaluronic Acid Hydrogels for Smart Drug Delivery Systems

  • Kim, Jin-Tae;Lee, Deuk-Yong;Kim, Young-Hun;Lee, In-Kyu;Song, Yo-Seung
    • Journal of Sensor Science and Technology
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    • v.21 no.4
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    • pp.256-262
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    • 2012
  • Hyaluronic acid(HA) hydrogels were synthesized by immersing HA microbeads in phosphate buffered saline solutions having different pH levels to assess the effect of pH on the swelling ratio of HA hydrogels for smart drug delivery systems. No beads were formed when the HA solution(below pH 9) was crosslinked with divinyl sulfone(DVS) because DVS is a basic solution. The variation regarding the size of the microbead was not significant, suggesting that the bead size is not a function of pH(10 ~ 14). However, the pore size of the microbeads decreased with increasing pH from 10 to 14, leading to the surface smoothness and dense network as a result of higher crosslinking. The swelling ratio of hydrogels increased when the pH rose from 2(acidic) to 6(neutral). Afterwards, it decreased with further increasing pH(basic). The lower swelling ratio may be due to the lack of ionization of the carboxyl groups. On the other hand, a higher swelling ratio is likely due to the increased electrostatic repulsions between negatively charged carboxyl groups on different chains. Experimental results suggested that pH-responsive HA hydrogels can be applicable to the controlled drug delivery systems.

Change of Microbial Communities in Fermentative Hydrogen Production at Difference Cultivation pHs (혐기성 수소생산 시 운전 pH 변화에 따른 미생물의 군집 변화)

  • Jun, Yoon-Sun;Lee, Kwan-Yong;Cho, Yoon-A;Lee, Tae-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1239-1244
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    • 2008
  • In this study, PCR-DGGE was conducted to investigate the variations of microbial community according to pH conditions from pH 3 to pH 10 during anaerobic fermentation process of hydrogen production. Maximum hydrogen yield was 1.8 mol $H_2$/mol substrate at pH 5. The microbial growth rate was not proportional to the hydrogen production rate at each pH. Variations of microbial community was observed at each condition from PCR-DGGE experiment of 16s rDNA. Klebsiella was main species of the microbial community. Streptococcus and Clostridium were mainly contributed for hydrogen production.

Cloning of a ${\beta}-Xylosidase$ Gene from Alkalophilic Bacillus sp. and its Expression in Escherichia coli

  • Yu, Ju-Hyun;Kang, Yun-Sook;Park, Young-Seo
    • Journal of Microbiology and Biotechnology
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    • v.1 no.1
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    • pp.17-21
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    • 1991
  • A gene coding for ${\beta}-xylosidase$ in alkalophilic Bacillus sp. YC-335 isolated from soil was cloned into Escherichia coli HB101 using plasmid pBR322. The recombinant plasmid pYK40 was isolated, and the cloned HindIII fragment was 15 kilobases (kb). To reduce the size of the inserted DNA fragment of pYK40, the 15 kb HindIII fragment was subjected to a series of subclonings. A 6 kb subfragment was found to code for ${\beta}-xylosidase$ activity, and the recombinant plasmid was named pYK44. Southern hybridization analysis revealed that the cloned gene hybridized with 3.5 kb, 1.5 kb, and 1.0 kb of HindIII cleaved chromosomal DNA from Bacillus sp. YC-335. ${\beta}-xylosidase$ activity produced by recombinant E. coli was found to be 11 times higher than that produced by Bacillus sp. YC-335. Xylan was required to induce the production of ${\beta}-xylosidase$ in Bacillus sp. YC-335.

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Removal of Sulfamethoxazole using Ozonation or UV Radiation; Kinetic Study and Effect of pH (오존 처리 및 UV 조사를 이용한 Sulfamethoxazole 제거; 동역학적 고찰 및 pH 영향)

  • Jung, Yeonjung;Kim, Wangi;Jang, Hayoung;Choi, Yanghwun;Oh, Byungsoo;Kang, Joonwun
    • Journal of Korean Society on Water Environment
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    • v.24 no.1
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    • pp.63-68
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    • 2008
  • This study was performed to assess the potential use of ozone or UV radiation for the treatment of water contaminated with sulfamethoxazole (SMX), which is frequently used antibiotic in human and veterinary medicines, especially focusing on the kinetic study and effect of pH. In a study using ozone alone, kinetic study was performed to determine second-order rate constant ($k_{O3,SMX}$) for the reactions of SMX with ozone, which was found to be $1.9{\times}10^6M^{-1}s^{-1}$ at pH 7. The removal efficiencies of SMX by ozone were decreased with increase of pH due to rapid decomposition of ozone under the condition of various pH (2.5, 5.3, 7, 8, 10). In a UV irradiation study at 254 nm, a kinetic model for direct photolysis of SMX was developed with determination of quantum yield ($0.08mol\;Einstein^{-1}$) and molar extinction coefficient ($15,872M^{-1}cm^{-1}$) values under the condition of quantum shielding due to the presence of reaction by-products formed during photolysis. For effect of pH on photolysis of SMX, SMX in the anionic state ($S^-$, pH > 5.6), most prevalent form at environmentally relevant pH values, degraded more slowly than in the neutral state (SH, 1.85 < pH < 5.6) by UV radiation at 254 nm.