• Journal of the Korean Wood Science and Technology
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• 제34권5호
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• pp.29-41
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• 2006

This study was to investigate the effect of adding additive as tannin, rice husk and charcoal, for reducing the formaldehyde emission level, on the adhesion properties of urea-formaldehyde (UF) resin for particleboard. We controlled the hot-pressing time, temperature and pressure to determine the bonding strength and formaldehyde emission. Blends of various UF resin/additives (tannin, rice husk and charcoal) compositions were prepared. To determine and compare the effect of additives (tannin, rice husk and charcoal) content, 0, 5, 10 and 15%, by weight of UF resin, were used. $NH_4Cl$ as hardener added. To determine the level of formaldehyde emission, we used the desiccator, perforator and 20 L-small chamber method. The formaldehyde emission level decreased with increased additions of additive (except rice husk). Also, increased hot-pressing time decreased formaldehyde emission level. At a charcoal replacement ratio of only 15%, the formaldehyde emission level is under F ✩ ✩ ✩ ✩ grade (emit < $0.3mg/{\ell}$). Curing of the high tannin additive content in this adhesive system indicated that the bonding strength increased. But, in the case of rice husk and charcoal, the bonding strength was much lower due to the inorganic substance. Furthermore, rice husk was poor in bonding strength as well as formaldehyde emission than tannin and charcoal.

• 대한화학회지
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• 제25권3호
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• pp.160-165
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• 1981

2-비닐피리딘계의 세가지 종류의 고분자물질을 합성하여 그들의 구조를 적외선 흡수 스펙트럼으로 확인한 결과, 2-비닐피리딘-디비닐벤젠의 삼중합체임을 알 수 있었다. 또한 2-비닐피리딘-아세트산비닐-디비닐벤젠의 삼중합체는 $98{\circ}C$에서 50분간 반응시킬 때 가장좋은 수율을 나타냈다. 특히 합성된 삼중합체중, 2-비닐피리딘-비닐알코올-디비닐벤젠과, 2-비닐피리딘-인산비닐-디비닐벤젠은 2-비닐피리딘-아세트산비닐-디비닐벤젠보다 큰 이온교환용량을 가지며, 2-비닐피리딘-비닐알코올-디비닐벤젠과 2-비닐피리딘-인산비닐-디비닐벤젠의 이온교환용량은 각각, 3.69 meq/g 및 5.38 meq/g이었다. 마지막으로 Mg(Ⅱ), Co(Ⅱ) 및 Cd(Ⅱ)금속이온에 대한 흡착능을 알아보았다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.65-68
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• 2002

This study dealt with autonomic microcapsules with the healing agent for damage repair of the composite structures. Autonomic microcapsules were made of a urea-formaldehyde resin for shell of microcapsule and a DCPD for the healing agent. Thermal analysis was conducted by using a DSC and a TGA for the healing agent, microcapsules without the healing agent, and microcapsules with the healing agent. According to the results, autonomic microcapsules were verified to be so thermally stable that the healing agent was kept inside the microcapsule until the shell of microcapsules were burned out.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2004년도 춘계학술대회 논문집
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• pp.309-314
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• 2004

This study focused on the introduction of damage repair for polymeric composite carbody. called selfing tech-healinique. using microcapsules loaded with the healing agent The manufacturing process for microcapsules with the healing agent was introduced and tile characteristics of microcapsules manufactured by varying with various manufacturing process variables were evaluated. The DCPD was used for the healing agent and microcapsules were made of urea-formaldehyde resin. The magnitude and the size distribution of microcapsules were measured by a particle size analyzer using laser diffraction technique. Thermal stability was investigated by using a TGA under continuous and isothermal heating conditions for the healing agent. microcapsules without the healing agent. microcapsules with the healing agent.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.793-796
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• 2003

This study dealt with the manufacturing process of self-healing microcapsules for damage repair in polymeric composites. The microcapsule was consisted with a DCPD (dicyclopentadiene) as the healing agent and a urea-formaldehyde resin as the wall section. The size distribution of microcapsules were measured by a particle size analyzer using a laser diffraction technique. Thermal stability of microcapsules was investigated by using a TGA under continuous and isothermal heating conditions. According to the results, these microcapsules were verified to be to thermally stable and have a great potential to be applicable for damage repair in polymeric composites.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 춘계학술발표대회 논문집
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• pp.169-172
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• 2003

Manufacturing process for autonomic microcapsules was introduced and autonomic microcapsules were manufactured by varying with various manufacturing process variables. Urea-formaldehyde resin was used for the wall of microcapsules and DCPD (dicyclopentadiene) was used for the self-healing agent. The characteristics of these microcapsules was evaluated through a particle size analyaer, an optical microscope, and a TGA. The various manufacturing process variables, such as pH and agitation speed of the emulsified solution, were considered to focus in this study. According to the results, the particle size distributions were affected on the agitation speed of the emulsified solution, and the thermal stability was influenced by pH of the emulsified solution.

• Journal of the Korean Wood Science and Technology
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• 제40권6호
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• pp.406-417
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• 2012

이 연구에서는 선행연구에서 발표된 목재섬유에 녹차를 복합한 친환경 복합보드에 탈취성과 흡착성 등의 기능성을 보강한 건축내장재를 개발하기 위하여, 흑탄, 백탄, 활성탄 등 3종류의 숯을 혼합한 녹차-숯-목재섬유 복합보드를 제작하였고, 구성원료의 종류 및 배합비율이 복합보드의 치수안정성, 탈취성 및 포름알데히드 방산량에 미치는 영향을 조사하였다. 녹차-숯-목재섬유 복합보드의 흡수두께 팽창률은 녹차와 숯의 배합비율의 증가에 따라 증가하였으나, 활성탄 함유 복합보드를 제외하고, KS에 규정된 그 값보다 현저히 낮은 값을 나타내었다. 복합보드의 암모니아가스 감소율은 활성탄 10% 함유 복합보드에서 30분 경과시 96%의 높은 값을 나타내었고, 다른 모든 복합보드에서도 1시간 경과 후 거의 95%전후의 높은 암모니아가스 감소율을 나타내었다. 복합보드의 포름알데히드 방산량은 $E_1$급 요소수지를 사용했을 경우, $E_0$급에 가까운 방산량을, $E_0$급 요소수지를 사용했을 경우는 super $E_0$급의 낮은 포름알데히드 방산량을 나타내는 것이 확인되었다.

• Composites Research
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• 제16권2호
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• pp.54-61
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• 2003

본 연구에서는 자가치료제가 저장된 마이크로캡슐의 제조공법을 소개하였으며 제조공정변수를 달리하여 제조된 마이크로캡슐의 특성을 입도분석기, 광학현미경, TGA 등을 통해 평가하였다. 이때 자가치료용 마이크로캡슐은 요소-포름알데히드 수지로 구성된 박막으로 되어 있으며 마이크로캡슐의 내부에는 자가치료제인 DCPD가 충전되어 있는 경우를 고려하였다. 마이크로캡슐의 제조공정변수로는 (1) 24시간. 40시간. 48시간, 60시간의 EMA copolymer 용해시간, (2) pH3.5, pH4.0, pH4.5의 수소이온농도, (3) 400rpm, 500rpm, 600rpm. 1000rpm의 교반속도, (4) $50^{\circ}$, $55^{\circ}$, $60^{\circ}$의 반응온도 등을 고려하였다. 연구결과에 따르면 마이크로캡슐의 입도분포는 교반속도에 따라 달라지며, EMA copolymer의 용해시간, 수용액에서의 수소이온농도 및 반응온도 등은 마이크로캡슐의 열안정성에 큰 영향을 미친다. 따라서 마이크로캡슐의 내부에 저장된 자가치료제의 증발을 억제할 수 있는 우수한 열안정성을 갖는 마이크로캡슐을 제조하기 위해서는 적절한 제조공정변수가 적용되어야 한다.

• Parasites, Hosts and Diseases
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• 제51권3호
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• pp.297-304
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• 2013

Trichinosis is a parasitic zoonosis caused by the nematode Trichinella spiralis. Anthelmintics are used to eliminate intestinal adults as well as tissue-migrating and encysted larvae. This study aimed to investigate the effects of ivermectin and myrrh obtained from the aloe-gum resin of Commiphora molmol on experimental trichinosis. Ninety albino mice were orally infected with 300 T. spiralis larvae. Drugs were tested against adult worms at day 0 and day 5 and against encysted larvae on day 15 and day 35 post-infection (PI). Mature worms and encysted larvae were counted in addition to histopathological examination of muscle specimens. Serum aspartate aminotransferase (AST), alanine aminotransferase (ALT), total protein, albumin, globulin, urea, and creatinine values were estimated. Significant reductions in mean worm numbers were detected in ivermectin treated mice at day 0 and day 5 PI achieving efficacies of 98.5% and 80.0%, while efficacies of myrrh in treated mice were 80.7% and 51.5%, respectively. At days 15 and 35 post-infection, ivermectin induced significant reduction in encysted larval counts achieving efficacies of 76.5% and 54.0%, respectively, while myrrh efficacies were 76.6% and 35.0%, respectively. AST, ALT, urea, and creatinine levels were reduced, while total proteins were increased in response to both treatments compared to their values in the infected non-treated mice. Ivermectin use for controlling T. spiralis could be continued. Myrrh was effective and could be a promising drug against the Egyptian strains of T. spiralis with results nearly comparable to ivermectin.

• Journal of the Korean Wood Science and Technology
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• 제29권2호
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• pp.109-117
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• 2001

한지(韓紙) 제조(製造) 공정(工程) 중에서 발생하는 백색 슬러지와 흑색 슬러지를 각각 일정비율(10, 20, 30, 40%)로 목재(木材) 파티클과 혼합(混合)하고 PMDI, 요소 및 페놀수지를 이용하여 각각 목표비중(目標比重) 0.60, 0.75, 0.90 별로 복합(複合)보드를 제조(製造)하여 물리적(物理的) 성질(性質)을 측정 분석한 결과 흡수길이변화율은 대조보드에 비해 크게 증가하지 않았으며 흡수두께팽창율은 PMDI를 적용한 백색 슬러지 목재(木材) 파티클 복합(複合)보드가 가장 낮은 값을 보였고 흡수율은 흑색 슬러지 목재(木材) 파티클 복합(複合)보드의 경우 혼합(混合) 비율(比率)이 증가할수록 대체로 감소하는 경향을 보였다.