• Journal of Korean Society for Atmospheric Environment
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• v.19 no.1
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• pp.1-11
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• 2003

Temporal and horizontal distributions of surface ozone concentrations covering the Busan metropolitan area were simulated by UAM -V (The Variable grid Urban Airshed Model) that was run with meteorological inputs taken from MM5 for ozone episode day (18 July 1999). UAM-V underestimated the daily maximum ozone con-centration about 14 ppb on average at all monitoring sites within Busan area comparing with observed value. but the correlation between observed and simulated values showed quite significant (R = 0.896, p< 0.01 on average). Higher concentrations of ozone occurred near the city center and industrial areas (western side of city) with high levels of anthropogenic source in the morning, and transport of ozone and its precursors by sea breeze developed in the afternoon contributed to elevated ozone levels in downwind rural areas. Particalarly in slightly downwind area of city center, the highest daily maximum ozone concentration ($\geq$120 ppb) was simulated by UAM-V at 1400 LST. Consequently, local environments including emission distributions and land -sea breeze circulation influenced ozone distributions in the Busan metropolitan area.

• Journal of the Korean Society of Industry Convergence
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• v.5 no.1
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• pp.75-80
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• 2002

In this study, the initial number of bacteria before ozone sterilizing shows 290 per $1m{\ell}$ in RUN 1 and RUN 2 equally, but the removal rate shows more than 50% in RUN 1, and 100% in RUN 2 respectively when ozone injection amount is $0.28mg/{\ell}$. It is regarded as a satisfactory result that E-coli concentration without ozone contact is 890, rapid removal effect of E-coli is observed in $0.28mg/{\ell}$ of ozone, and E-coli is removed perfectly in $0.84mg/{\ell}$ of ozone. It is thought that an excellent efficiency is obtained for vibrio alginolyticus because the initial number of bacteria before ozone contact is positive, but it is altered to negative after ozone contact. CODcr shows the tendency which is somewhat reduced as the ozone injection is increased, but the general effect is appeared not so much, and it is thought that the tendency is caused by the reason that sea water contains much salt which is estimated as a component of CODcr, therefore it is regarded that ozone contact has not an important effect on salinity. It is thought that the frequency of changing salt water in the fish preserve of a sliced raw fish restaurant can be reduced to under the standard because NTU of 7 days after sea water injection is 0.70 in the experiment of turbidity, hut more than 50% of turbidity removal efficiency is appeared at $0.28mg/{\ell}$ of ozone injection, and it shows 70% at $0.84mg/{\ell}$ of ozone injection in RUN 1 and RUN 2 commonly.

• Journal of Environmental Science International
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• v.9 no.4
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• pp.295-302
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• 2000

This study was conducted to investigate the characteristics of surface ozone concentration and occurrence of high ozone concentration using hourly ozone, nitrogen dioxide and meteorological data for 1997~1998 in Pusan coastal area. Monthly mean ozone concentration was the highest at Dongsamdong in Spring(35.4ppb), at Kwangbokdong in Fall(25.1ppb) and the lowest Dongsamdong(22.2ppb) and Kwangbokdong(16.0ppb) in Winter. Relative standard deviation indicating clearness of observation site was 0.42 at Dongsamdong and 0.49 at Kwangbokdong that is similar to urban area. The diurnal variation of ozone concentration of Dongsamdong and Kwangbokdong showed maximum at 1500~1600LST and minimum 0700~0800LST that typical pattern of ozone concentration. In ozone episode period(Sept. 10~15, 1998), diurnal change of ozone concentration was very high, and ozone concentration was related to meteorological parameters such as temperature, relative humidity, wind speed, cloud amount and radiation on a horizontal surface. During the episode days peak ozone concentrations are much higher than the normal values, wind speeds are always lower, and solar radiation is high with the exception of the September episode.

• Journal of the Korean Association of Geographic Information Studies
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• v.25 no.3
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• pp.74-99
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• 2022

Surface ozone is produced by photochemical reactions of nitrogen oxides(NOx) and volatile organic compounds(VOCs) emitted from vehicles and industrial sites, adversely affecting vegetation and the human body. In South Korea, ozone is monitored in real-time at stations(i.e., point measurements), but it is difficult to monitor and analyze its continuous spatial distribution. In this study, surface ozone concentrations were interpolated to have a spatial resolution of 1.5km every hour using the stacking ensemble technique, followed by a 5-fold cross-validation. Base models for the stacking ensemble were cokriging, multi-linear regression(MLR), random forest(RF), and support vector regression(SVR), while MLR was used as the meta model, having all base model results as additional input variables. The results showed that the stacking ensemble model yielded the better performance than the individual base models, resulting in an averaged R of 0.76 and RMSE of 0.0065ppm during the study period of 2020. The surface ozone concentration distribution generated by the stacking ensemble model had a wider range with a spatial pattern similar with terrain and urbanization variables, compared to those by the base models. Not only should the proposed model be capable of producing the hourly spatial distribution of ozone, but it should also be highly applicable for calculating the daily maximum 8-hour ozone concentrations.

• Journal of Environmental Impact Assessment
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• v.8 no.2
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• pp.21-29
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• 1999

This study was conducted to investigate the characteristics of surface ozone concentration and occurrence of high ozone concentration using hourly ozone and meteorological data of 1997~1998 in Pusan coastal area. Monthly mean ozone concentration was highest in Spring(35.4ppb) and lowest in Winter(22.2ppb). Relative standard deviation indicating clearness of observation site was 0.42 that is similar to urban area. The diurnal variation of ozone concentration of Dongsamdong showed maximum at 15~16LST and minimum 07~08LST that typical pattern of ozone concentration. In ozone episode period(May 18~23, 1998), diurnal change of ozone concentration was very high, and ozone concentration was related to meteorological parameters such as temperature, relative humidity, wind speed, cloud amount and radiation on a horizontal surface.

• Asian Journal of Atmospheric Environment
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• v.5 no.1
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• pp.29-40
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• 2011

In this study, the effects of an urban thermal environment on air quality were investigated using hourly surface weather observation data and air quality data over six summers from 2000 to 2005 in two cities on the Korean Peninsula. One, the city of Daegu, is representative of basin topography and the other, the city of Busan, represents a coastal area. It is known that the characteristics of an urban thermal environment are represented as an "urban heat island". Here, we focus on the nighttime urban thermal environment, which is called a "tropical night", during the summer. On tropical nights in Busan, the temperature and cloud cover levels were higher than on non-tropical nights. Wind speed did not appear to make a difference even on a tropical night. However, the frequency of southwestern winds from the sea was higher during tropical nights. The prevailing southwest winds in all areas meant an inflow of air from the sea. So at most of the air quality stations, the ozone concentration during tropical nights was lower than during non-tropical nights. In Daegu, the tropical nights had higher temperatures and cloud covers. Despite these higher temperatures, the ozone concentration during the tropical nights was lower than that on non-tropical nights at most of the air quality stations. This feature was caused by low irradiance, which in turn caused an increased cloud cover. Wind speed was stronger during the tropical nights and dispersed the air pollutants. These meteorological characteristics of the tropical nights reduced ozone concentrations in the Daegu Basin.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.11-14
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• 2003

Development pollution control strategies relies on photo-chemical transport models. These models integrate of mesoscale meteorological models with chemical moduls. In this study, the PSU/NCAR mesoscale meteorological model with CAMx is used to investigate the temporal and spatial dynamics of the photochemical air pollution in urban atmosphere of Istanbul for selected high ozone days. The ozone climatology for the selected days and model simulations are presented.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.1
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• pp.50-62
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• 2011

Temporal trends and spatial distributions of ozone concentrations in Pohang were investigated using data measured at 4 air quality monitoring stations (i.e., Daedo, Jukdo, Jangheung, and Desong) during 2002-2006. The monthly mean ozone concentrations were highest during April and June and decreased during July and August, which follows the typical trend in the Northeast Asia region. The high springtime ozone concentration might have been strongly influenced by the enhanced photochemical ozone production of accumulated precursors during the winter under increased solar radiations. In July and August, ozone levels were decreased by frequent and severe precipitation that caused lower mean monthly solar radiation and efficient wash-out of ozone precursors. This suggests that precipitation is extremely beneficial in the aspect of ozone pollution control. High ozone concentrations exceeding 80ppb dominantly occurred in May and June during the late afternoon between 16:00~17:00. Ozone concentrations were higher in Jangheung and Daesong relative to Daedo and Jukdo, whereas total oxidants $(O_3+NO_2)$ were higher in Jangheung and Daedo. In the suburban area of Daesong, ozone concentrations seem to be considerably higher than those in urban sites of Daedo and Jukdo due to lower ozone loss by NO titration with lower local NO level.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.4
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• pp.253-264
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• 2002

Surface ozone concentrations measured at 40 monitoring sites in three major cities (Seoul, Busan, and Daegu) of Korea during 1993~2000 were analyzed to understand the characteristics of temporal and spatial distributions. Trends were analyzed for annual mean, 95th percentiles of daily 8-hour maximum and days exceeding 8-h ozone standard of 60 ppb. Three indicators exhibited increasing trends (+0.75 ppb yr$^{-1}$ , +2.20 ppb yr$_{-1}$ , and +5.35 days yr$_{-1}$ on average) throughout the study period at all cities. Diurnal and seasonal variations were the largest in Seoul followed by Daegue and Busan, due to the high photochemical production and titration of ozone (Seoul), strong wind and constant supply of background ozone from the ocean (Busan). In the urban centers and industrial areas at all cities, scavenging of ozone by NO reduces the daily 8-hour maximum ozone by 10 ppb on average. High concentrations of ozone have frequently occurred in downwind eastern (Seoul and Daegu) or northern (Busan) sides of the territory. In particular, the coastal area of Busan had relatively high ozone level due to the local sea land breeze circulation. The results indicated that the temporal and spatial variations of ozone concentration were non -uniform and were closely related to the local environments; emission levels, climates, and geographic locations.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.6
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• pp.607-623
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• 2000

Major trends of ozone concentration variations in Korea were investigated by using observation data from around 100 stations for the period of 1991∼1997. In addition, important regulating those variations were inferred. Three measures such as the number of days exceeding 80ppb, the 95th percentile of daily maxima, and the annual average concentration were used for the analysis of multi-scale ozone concentration variations. Three areas in the southwest (Sosan, Mokpo, and Cheju) of which monitoring has been operated since 1995 showed the highest annual average concentrations over; this was noted because of the high annual average in the Yosu area in the early 1990s. Large increases in annual average concentrations were observed along the relatively cleaner areas connecting Kangnung and Kwangju(northeast to southwest), in contrast to polluted areas connecting Seoul and Pusan(northeast to southeast). Both the number of exceedance days and the daily maximum concentration were nearly constant in the Greater Seoul Area in spite of interannual flucturations associated with year-to-year changes in air temperature. Within the Greater Seoul Area, all three measures usually showed the same trend; they decreased in the middle and west and increased in the east and northeast. All three measures including the number of exceedance days increased largely at Sillim where the average concentration was high but no exceedance days were recorded in the early 1999s, Nationwide ozone concentration variations appear to be determined by the competitive influence of long-range transport and local urban emissions, Within the city including the Greater Seoul Area, changes in emission which accompany changes in population and in the number if vehicles ( in the process of urban development) were found to be important components of ozone concentration variations.