• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.2
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• pp.17-23
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• 2004

A cylindrical constant volume combustion bomb is used to investigate the combustion characteristics and to analyze the heat quantity of homogeneous charge methane-air mixture under various initial pressures, excess air ratios and ignition times. As the overall pressure increase, the values of maximum combustion pressure, maximum heat release rate and cumulative heat release have been increased. But it is not very meaningful to compare with some values such as maximum combustion pressure, maximum heat release rate and cumulative heat release for different overall pressure due to the different heat energy of supplied fuel. So the each value is needed to be compared with normalized value, which is divided by the entered fuel energy. To analyze the heat quantity, some definitions including the CHR ratio, the UHC ratio and the HL ratio are needed and are calculated. As the overall pressure increase, the CHR ratios and the UHC ratios have been decreased, while the HL ratios have been increased. The CHR ratio of 300 ms has the higher value than that of 10000ms, and the HL ratios of 300 ms have a lower value.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.2
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• pp.1-8
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• 2004

A cylindrical constant volume combustion chamber was used to investigate the exhaust emission characteristics of homogeneous charge, stratified pattern and inhomogeneous charge under various conditions using gas chromatography. In the case of homogeneous charge condition, the $CO_2$ concentration is proportional to excess air ratio and overall charge pressure, the $CO_2$ concentration is proportional to excess air ratio and the UHC concentration is inversely proportional to ignition time and overall charge pressure. In the case of stratified pattern, the RI(rich injection) condition shows better exhaust emission characteristics, especially $CO_2$, than that of HI (homogeneous injection) or LI (lean injection) conditions. In inhomogeneous charge conditions, when initial charge pressure is increased, $CO_2$ and UHC concentration is reduced but $O_2$ concentration is increased. And when the excess air ratio of initial charge mixture is 3.0, UHC and $CO_2$concentration show lowest values.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.11
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• pp.1563-1571
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• 2003

This paper is the second part of several companion papers which compare the method of Air-fuel ratio(AFR) determination. In the previous paper, Eltinge chart was applied to the arbitrary fuel composition and the charts for gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane and butane were illustrated. In Eltinge chart, however, unburned hydrocarbon (UHC) is not used for determination of AFR. For improving accuracy, Eltinge suggested UHC compensation after the AFR reading in the chart. This compensation reduced the difference between real and reading value. In the compensation, however, the correction of oxygen and carbon dioxide is uncertain and there might be a mistake in conversion of UHC reading value. Therefore, the error is overestimated comparing with Spindt one which is most widely used. In addition, there is no comparison of the value with other useful methods. In this paper, the compensation of unburned HC was performed in Eltinge chart and the compensated value was compared with Spindts formula over wide range of AFR. The objects of investigating fuel are gasoline, methanol, NG and LPG. The result shows that Eltinge and Spindt method is flawlessly compatible and the difference between the two methods is under 0.3% in a λrange from 0.9 to 1.7. The method fur debugging instrumentation error is also presented.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.2
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• pp.24-31
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• 2004

A cylindrical constant volume combustion bomb is used to investigate the combustion characteristics and to analyzer the heat quantity of inhomogeneous charge methane-air mixture. To analyze the heat quantity, some definitions including the CHR ratio, the UHC ratio and the HL ratio are needed and are calculated. It is shown that the effect of stratification is not significant in case of the overall excess air ratio of 1.1, mainly due to the higher heat loss and lower thermal efficiency compared to those of homogeneous condition. In the case of the overall excess air ratio of 1.4, as the initial charge pressure decreases, the CHR ratio has been decreased while the HL ratio has been increased, Generally, as the initial charge pressure increases, the amount of injection mixture has been decreased and has resulted in lower mean velocity and turbulence intensity for injection mixture. Also, the injected mixture is too rich to result in mixing deficiency in combustion chamber. From these results, it could be possible to acquire the improvement of thermal efficiency and the reduction of heat loss simultaneously through the 2-stage injection in CNG direct injection engine.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.05a
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• pp.247-250
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• 2009

The catalytic combustor has the advantage of stable combustion under very lean conditions with low emissions of $NO_x$, CO and unburned hydrocarbon(UHC). Notwithstanding these advantages, the commercial application of the catalytic combustion has been delayed due to the complicated reaction process. For the stable operation of catalytic combustor, study on the combustion characteristics of the catalytic combustor is needed. So, in this study, numerical study on the propane combustion characteristics of the catalytic combustor with Pd-based catalyst is performed.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.40 no.4
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• pp.309-315
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• 2012

Catalytic combustion is generally accepted as one of the environmentally preferred alternatives for heat and power from fossil fuels, as it has the advantage of stable combustion under very lean conditions with such low emissions as UHC, CO, and NOx. In this work, therefore, comparative numerical studies on the catalytic combustion behaviors over Pd-based catalysts have been conducted with the gaseous $CH_4$, $C_2H_6$, and $C_3H_8$. In the following, after introducing the governing equations with 1D channel and Langmuir-Hinshelwood models, numerical investigations on the catalyst performance are conducted by changing such various parameters as inlet temperature, excess air ratio, and space velocity. The numerical results show that outlet temperature and conversion of $C_3H_8$ are highest among others because of its chemical structure and reactivity.

• International Journal of Automotive Technology
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• v.6 no.4
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• pp.323-332
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• 2005

A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at the spark electrode gap and the combustion characteristics of a homogeneous charged methane-air mixture under various overall charge pressures, excess air ratios and ignition times. The flow characteristics, including the mean velocity and turbulence intensity, were analyzed with a hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer, a flame propagation image acquired by ICCD camera and exhaust emissions measured by 2-valve gas chromatography were used to investigate effects of initial pressures, excess air ratios and ignition times on the combustion characteristics. It was found that the mean velocity and turbulence intensity had the maximum value around 200-300 ms and then decreased gradually to a near-zero value after 3000 ms and that the combustion duration was shorten and the flame speed and laminar burning velocity had the highest value under the condition of an excess air ratio of 1.1, an overall charge pressure of 0.15 MPa and an ignition time of 300 ms in the present study. The $CO_2$ concentration was proportional to the ignition time and overall charge pressure, the $CO_2$ concentration was proportional to the excess air ratio, and the UHC concentration was inversely proportional to the ignition time and overall charge pressure.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.4
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• pp.405-412
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• 2012

In the MCFC power generation system, the combustor supplies a high temperature mixture of gases to the cathode and heat to the reformer by using the off-gas from the anode; the off-gas includes high concentrations of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and avoid local heating, a catalytic combustor is usually adopted. Catalytic combustion is also generally accepted as one of the environmentally preferred alternatives for generation of heat and power from fossil fuels because of its complete combustion and low emissions of pollutants such as CO, UHC, and $NO_x$. In this study, experiments were conducted on catalytic combustion behavior in the presence of Pd-based catalysts for the BOP (Balance Of Plant) of 5 kW MCFC (Molten Carbonate Fuel Cell) power generation systems. Extensive investigations were carried out on the catalyst performance with the gaseous $CH_4$ fuel by changing such various parameters as $H_2$ addition, inlet temperature, excess air ratio, space velocity, catalyst type, and start-up schedule of the pilot system adopted in the BOP.