• Title/Summary/Keyword: Toxic metals

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Variation of hazardous substances in sewage ecotoxicological assessment (하수 원수내 유해물질 변화에 따른 생태독성평가)

  • Seo, Byong-Won;Lee, Ju-Hwa;Lee, Yong-Hoon;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.5
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    • pp.603-610
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    • 2013
  • According to industrialization, increased toxic chemicals discharge has been causing water pollution. Especially domestic sewage is a major source of water pollution. Sixty percent of the total wastewater discharged is domestic sewage. Self-purification capacity of rivers and streams is drastically reduced by the emission of domestic sewage, industrial wastewater and livestock wastewater. Although domestic sewage is managed by implementing standards and regulations, toxicity effect of domestic sewage to humans and the environment is not yet clearly understood. In this study, by using daphnia magna, the ecotoxicity of domestic swage was assessed. Cl, Cu, Pb, COD, T-N, DO, pH and residual chlorine were investigated as background concentrations. The experiments were conducted with water samples obtained from three local sewage treatment plants. The experiment results indicated that higher level of toxicity corresponds to the higher pollution concentrations. The higher level of combinations of background concentrations such as heavy metals leads to the worse ecotoxicity. Especially, the Cu concentration affects the TU value.

Changes in the Ecological Toxic Effects of the Contaminated Sediment of Singapore after Treatment (싱가포르 오염준설토 정화 후 생태 독성 변화)

  • Jho, Eun Hea;Yun, Seong Ho;Hwang, Sun Kyung;Lee, Sung Jong;Kim, Hongseok;Chae, Heehun
    • Journal of Soil and Groundwater Environment
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    • v.22 no.5
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    • pp.82-88
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    • 2017
  • Contaminated sediment can be treated in order to reuse the treated sediment. Even though the chemical criteria are satisfied, the treated sediment could still impose toxic effects. Therefore, this study investigated the changes in the ecological toxic effects of the contaminated sediment from the J region in Singapore after treatment. The contaminated sediment was subject to sequential soil washing and thermal treatment, followed by pH neutralization. Toxic effects of the contaminated and treated sediments were determined by using Vibrio fischeri ($Microtox^{(R)}$), Triticum aestivum (wheat), and Eisenia foetida (earthworm). After treatment, the concentrations of total petroleum hydrocarbons and heavy metals were decreased by 98% and 59-93%, respectively, and satisfied the Industrial Maximum Values of the Dutch Standard, which were used as the remedial goal. The bioluminescence reduction of V. fischeri decreased significantly, and the earthworm survival increased from 0% to 90% after treatment. The germination rate increased from $0{\pm}0%$ to $75{\pm}13%$ after treatment, but the treated sediment may need additional treatment such as nutrient addition for better plant growth. Overall, this study showed that the treatment of the contaminated sediment satisfactorily removed mixed contaminants, and this led to reduction in toxic effects, suggesting improved potentials for reuse of the treated sediment.

A Study On Heavy Metal Contamination in the Different Size Fractions of Deposited Road Particles(DRPs) (노면퇴적물의 입자 크기에 따른 중금속 오염에 관한 연구)

  • Kim, Boo-Gil;Lee, Byung-Cheol
    • Journal of Environmental Science International
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    • v.15 no.12
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    • pp.1171-1175
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    • 2006
  • Deposited road particles (DRPs) were analysed for heavy metal concentrations at four different roads in a city, Korea. The samples were collected using a roadway surface vacuum cleaning vehicle which was commonly used in collecting roadway surface particles. Six particle size ranges were analyzed separately for twelve heavy metal elements (Cd, Cr, Pb, Ni, Al, As, Co, Cu, Fe, Mn, Zn and Hg). At all sampling sites, the high concentration of the heavy metals occurred in the <74um particle size range, which conventional roadway cleaning vehicles do not remove efficiently. The Pb concentration significantly increased with decreasing particle size of DRPs, and other toxic heavy metals (Cd, Cr and Ni) also showed similar results. The heavy metal concentrations in the smaller size fraction of DRPs is important because they are contaminants that are preferentially transported by road runoff during rainfall.

Biosorption and Desorption Characteristics of Heavy metal ion in Aqueous Solution by Chlorophyll (엽록체를 이용한 수중에서의 중금속 흡착 및 탈착 특성)

  • 연익준;신택수;이명선;주소영;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.14 no.1
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    • pp.80-87
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    • 1999
  • According to the fact that algae, which is usually used as a biosorbent, contains chlorophyll, we used the chlorophyll as an adsorbent. In this study, chlorophyll is immobilized by agar, which was made of platan, oak, ginkgo and pine. We investigated the removing capacity of biosorbents to toxic heavy metals (Pb, CU, Cd, Zn) in the single ion solution. Then the experimental parameters were pH, reaction time and concentration of heavy metal ions.The optimum conditions for the adsorption of heavy metals were as follows : pH range was 4~5, reaction time was 40mon, and the highest ratio of the removing rate was 50~70 ppm. The order of the amount of Pb, Cu and Cd removed was specified as oak > ginkgo > pine > platan in these conditions and as pine > ginkgo > oak > platan at Zn. Fro the results of the desorption experiments, we found that the heavy metal with the highest ratio of desorption in the single ion adsorbent was Cu.

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Life Cycle Assessment on Food Waste Treatment Systems - biogasification and composting -

  • Yasuhiro Hirai;Sakai, Shin-ichi;Hiroshi Takatsuki
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2001.05b
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    • pp.109-112
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    • 2001
  • A case study of foodwaste treatment was conducted to compare the impacts of four scenarios: incineration, incineration after biogasification, biogasification followed by composting, and composting. Potential contributions to climate change, acidification, consumption of landfill and human toxicity were assessed. Characterization of human toxicity caused by metals and PCDD/DF was performed by three multimedia fate models. Scenarios with a biogasification process showed lower impact on climate change and human toxicity. The ranking of four scenarios on human toxicity varied depending on the characterization models applied. The steady state models placed high priority on emission of heavy metals to farmland, whereas the dynamic model estimated the emission of PCDD/DF from the incineration process as more significant.

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Preparation of Energetic Metal Particles and Their Stabilization (에너제틱 금속입자 제조 및 안정화 기술)

  • Lee, Hye Moon;Kim, Kyung Tae;Yang, Sangsun;Yu, Ji-Hun;Kim, Yong-Jin
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.173-185
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    • 2013
  • Oxidations of metal generate large quantity of thermal and light energies but no toxic pollutants, so that metals with high calorific values, such as beryllium, boron, aluminum, magnesium, and lithium, are possible to be used as clean fuels instead of fossil fuels. However, they are so explosive due to very high oxidation rates that they should be stabilized by their surface passivation with oxides, organics and inorganics. For reasonable use of energetic metal particles as solid fuel, therefore, some detail information, such as thermal properties, preparation and passivation methods, and application area, of the energetic metals is introduced in this manuscript.

Hazardous Substance Analysis of Disposable Diaper for Infant (유아용 일회용 기저귀의 유해성 평가)

  • 신정화;윤혜온;박미애;안윤경
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.1
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    • pp.165-171
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    • 2004
  • The analytical method of toxic heavy metals in disposable diapers was developed. Disposable diapers obtained from Korea, Japan, America and German were determinated and quantified. Sample treatment (Total Digestion) was wet chemical acid digestion for extraction of nine hazardous inorganic elements (Sb, As, Pb, Cd, Cr, Co, Cu, Ni, Hg) in disposable diapers. Inductively Coupled Plasma Mass Spectrometer (ICP-MS) and Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) have been used for analyzing nine hazardous inorganic elements. The results were as follows : The concentration of extractable Sb which was treated for 3 hours with artificial urine and disposable diapers was higher than those of 6 hours and 24 hours. The concentration of extractable Cr was same as Sb. On the other hands, the behavior of Cu and Ni were different from Sb and Cr. Concentrations of extractable Cu and Ni increased as increasing the reaction time between artificial urine and disposable diapers.

Preliminary Study on the Toxicity and Transfer of Heavy Metals and Tributyltin to Seagrass Zostera marina (잘피의 광합성에 대한 중금속 및 TBT의 독성 영향과 중금속 흡수에 대한 연구)

  • Choi, Tae-Seob;Kim, Kwang-Young;Lee, Byeong-Gweon;Lee, Jung-Suk
    • ALGAE
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    • v.20 no.2
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    • pp.157-166
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    • 2005
  • Uptake kinetics of Cd and Zn by leaves and rhizome of the seagrass Zostera marina were examined in controlled laboratory radiotracer experiments. Subsequently, acute toxicity of Cd, Cu and TBT on photosynthetic quantum yield (ΔF/Fm’ of Z. marina were determined, and the differential sensitivities of rapid light curve (RLC) to those harmful substances were also compared. All measurements on photosynthetic activity were determined by chlorophyll a fluorescence method using pulse amplitude modulation (PAM). Metal uptake by Z. marina was saturated with increasing exposure time in leaves and rhizomes. Uptake of Zn by Z. marina was faster than that of Cd. Metal uptake rates in Z. marina decreased with the increase of dissolved metal concentrations and also with the increase of biomass. The adverse effect of TBT on effective quantum yield was stronger than other pollutants. Average acute toxicity on the RLC of the seagrass exposed to TBT and two heavy metals (Cd and Cu) was going to decrease as follows: TBT > Cd > Cu. Our preliminary results in this study suggested that Z. marina potentially can be used as a biomonitor of harmful substances contamination in coastal waters.

형광 X선에 의한 대기 부유분진중의 미량 성분의 측정 (I): -거름종이 표준시료에 의한 부유분진중 금속성분의 형광 X선 분석-

  • 이용근;맹현재;이보경;황규자
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.2
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    • pp.21-29
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    • 1989
  • The metals present in atmospheric particulate come from various sources; natural or anthropogenic. Among various metals Fe, Zn, Pb, Cu, and Mn are of particular concern in as much as they are not only present in large quantity, but toxic to human body. A simple, fast, and non-destructive analytical method for these metals in atmospheric particulate was developed and the analytical details were described herein. The method involves the measurements of X-ray fluorescence of sample contained in filters and comparing it with those for standards. The standard filters were prepared by applicating premeasured standard solution to the filters and then drying. The accuracy of the method was tested by analyzing standard reference materials and by independently analyzing samples using a different, previously accuracy-proven method, inductively coupled plasma atomic emission spectrometry, and comparing the results obtained. Analytical sensitivities and detection limits of the present method were 62.9, 178.2, 82.9, 146.1, 37.2, 120.3 cps/$\mug/cm^2$ and 39.0 35.6, 137.5, 125.9, 182.6, 72.8 $ng/cm^2$ for Fe, Zn, Pb, Cu, Mn, and Ni respectively. The method was applied to Seoul atmospheric particulate and some results were reported.

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Absorption of Heavy Metals of Waste Leachate Using by Fast Growing Trees(II) (속성수를 이용한 쓰레기 매립지 침출수의 오염물질 흡수제거(II))

  • 우수영
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.5 no.1
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    • pp.36-42
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    • 2003
  • To identify the rapacity of waste leachate absorption in Populus euramericana and Betula platyphylla var, japonica, four different treatments were applied to seedlings: leachate solution (100% leachate), 50% dilution (50% leachate: 50% water, v/v) and 25% dilution, (25% leachate: 75% water, v/v) were applied to these two species. After the experiment, concentrations of heavy metals in tree parts were analyzed by an Inductively Coupled Plasma emission spectrometer (ICP). treatment with waste leachate significantly stimulated both Populus euramericana and Betula platyphylla var. japonica biomass production relative to the water control. In addition, these species showed good absorption capacity of As, Co, Hg and Ni elements. The results of this study suggested that these two species can absorb the toxic materials through their roots and transport them to stems or leaves.