• Title/Summary/Keyword: Technology stability

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CRITERIA FOR A NEW CPNTEPT OF STABILITY

  • Lakshmikanthan, V.
    • Journal of the Korean Mathematical Society
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    • v.37 no.5
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    • pp.657-664
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    • 2000
  • A new concept of stability that includes Lyapunov and orbital stabilities and leads to concepts in between them is discussed in terms of a given topology of the function space. The criteria for such new concepts to hold are investigted employing suitably Lyapunov-like functions and the comparison principle.

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Properties of N-butyl-N-methyl-pyrrolidinium Bis(trifluoromethanesulfonyl) Imide Based Electrolytes as a Function of Lithium Bis(trifluoromethanesulfonyl) Imide Doping

  • Kim, Jae-Kwang;Lim, Du-Hyun;Scheers, Johan;Pitawala, Jagath;Wilken, Susanne;Johansson, Patrik;Ahn, Jou-Hyeon;Matic, Aleksandar;Jacobsson, Per
    • Journal of the Korean Electrochemical Society
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    • v.14 no.2
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    • pp.92-97
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    • 2011
  • In this study we have investigated the Li-ion coordination, thermal behavior and electrochemical stability of N-butyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide ($Py_{14}TFSI$) with lithium bis(trifluoromethanesulfony)imide (LiTFSI) doping intended for use as electrolytes for lithium batteries. The ionic conductivity is reduced and glass transition temperature ($T_g$) increases with LiTFSI doping concentration. Also, the electrochemical stability increases with LiTFSI doping. A high LiTFSI doping could enhance the electrochemical stability of electrolytes for lithium batteries, whereas the decrease in the ionic conductivity limits the capacity of the battery.

Order-disorder structural tailoring and its effects on the chemical stability of (Gd, Nd)2(Zr, Ce)2O7 pyrochlore ceramic for nuclear waste forms

  • Wang, Yan;Wang, Jin;Zhang, Xue;Li, Nan;Wang, Junxia;Liang, Xiaofeng
    • Nuclear Engineering and Technology
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    • v.54 no.7
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    • pp.2427-2434
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    • 2022
  • Series of unequal quantity Nd/Ce co-doped ceramic nuclear waste forms, (Gd, Nd)2(Zr, Ce)2O7, were prepared to tailor its ordered pyrochlore or disordered fluorite structure. The phase transition, microtopography, and elemental composition of the ceramic samples were systematically investigated, especially the effect of order-disorder structure on the chemical stability. It was confirmed that unequal quantity of Nd/Ce could synchronously replace the Gd/Zr-sites of Gd2Zr2O7. And the phase transition of order-disorder structure could be successfully tailored by regulating the average cationic radius ratio of (Gd, Nd)2(Zr, Ce)2O7 series. The elements of Gd, Nd, Zr, and Ce are uniformly distributed in the ordered or disordered structures. The MCC-1 leaching results showed that (Gd, Nd)2(Zr, Ce)2O7 pyrochlore ceramic nuclear waste forms had excellent chemical stability, whose elements' normalized leaching rates were as low as 10-4-10-7 g·m-2·d-1 after 7 days. In particular, the chemical stability of disordered structure was superior to that of ordered structure. It was proposed that the force constant and the closest packing were changed with the structure transformation resulting the chemical stability difference.

EFFECT OF FUEL STRATIFICATION ON INITIAL FLAME DEVELOPMENT: PART 1-WITHOUT SWIRL

  • Ohm, I.Y.;Park, C.J.
    • International Journal of Automotive Technology
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    • v.7 no.5
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    • pp.519-526
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    • 2006
  • For investigating the effect of fuel stratification on flame propagation, initial flame development and propagation were visualized under different axially stratified states in a port injection SI engine. Stratification was controlled by the combination of the port swirl ratio and injection timing. Experiments were performed in an optical single cylinder engine modified from a production engine and images were captured through the quartz window mounted in the piston by an intensified CCD camera. Firstly in this paper, the characteristics under no port-generated swirl condition, i.e. normal conventional case was studied. Under various stratified conditions, flame images were captured at the pre-set crank angles. These were averaged and processed to characterize the flames propagation. The flame stability was estimated by the weighted average of flame area and luminosity. The stability was also evaluated through the standard deviation of flame area and propagation distance, and mean absolute deviation of propagating direction. Results show that stratification state according to injection timing do not affect on the direction of flame propagation. The flame development and the initial flame stability are strongly dependent on the stratified conditions and the initial flame stability is closely related to the engine stability and lean misfire limit.

Decreased entropy of unfolding increases the temperature of maximum stability: Thermodynamic stability of a thioredoxin from the hyperthermophilic archaeon Methanococcus jannaschii

  • Lee, Duck-Yeon;Kim, Kyeong-Ae;Kim, Key-Sun
    • Journal of the Korean Magnetic Resonance Society
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    • v.8 no.1
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    • pp.1-18
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    • 2004
  • A thioredoxin from hyperthermophile, Methanococcus jannashii (MjTRX) was characterized by use of the differential scanning calorimetry to understand the mechanisms of thermodynamic stability. MjTRX has an unfolding transition temperature of 116.5$^{\circ}C$, although the maximum free energy of the unfolding (9.9 Kcal/mol) is similar to that of E. coli thioredoxin (ETRX, 9.0 Kcal/mol). However, the temperature of maximum stability is higher than ETRX by 20$^{\circ}C$, indicating that the unfolding transition temperature increased by shifting the temperature of maximum stability. MjTRX has lower enthalpy and entropy of the unfolding compared to ETRX maintaining a similar free energy of the unfolding. From the structure and the thermodynamic parameters of MjTRX, we showed that the unfolding transition temperature of MjTRX is increased due to the decreased entropy of the unfolding. Decreasing the unfolded state entropy and increasing the folded state entropy can decrease the entropy of the unfolding. In the case of MjTRX, the increased number of proline residues decreased the unfolded state entropy and the increased enthalpy in the folded state increased the folded state entropy.

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Dynamic Analysis of an Automatic Ball Balancer with Triple Races (삼중레이스를 갖는 자동평형장치의 동적 해석)

  • Jwa, Seong-Hun;Jo, Eun-Hyeong;Son, Jin-Seung;Park, Jun-Min;Jeong, Jin-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.4
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    • pp.764-774
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    • 2002
  • Dynamic behaviors are analyzed for an automatic ball balancer (ABB) with triple races, which is a device to reduce the unbalanced mass of optical disk drives (ODD) such as CD-ROM or DVD drives. The nonlinear equations of motion are derived by using Lagrange's equations with the polar coordinate system. It is shown that the polar coordinate system provides the complete stability analysis while the rectangular coordinate system used in other previous studies has limitations on the stability analysis. For the stability analysis, the equilibrium positions and the linearized perturbation equations are obtained by the perturbation method. Based on the linearized equations, the stability of the system is analyzed around the equilibrium positions; furthermore, to confirm the stability, the time responses for the nonlinear equations of motion are computed by using a time integration method and experimental analyses are performed. Theoretical and experimental results show a superiority of the ABB with triple races.

Investigation of slope reinforcement with drilled shafts in colluvium soils

  • Lia, An-Jui;Wang, Wei-Chien;Lin, Horn-Da
    • Geomechanics and Engineering
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    • v.31 no.1
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    • pp.71-86
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    • 2022
  • In Taiwan, an efficient approach for enhancing the stability of colluvium slopes is the drilled shaft method. For slopes with drilled shafts, the soil arching effect is one of the primary factors influencing slope stability and intertwines to the failure mechanism of the pile-soil system. In this study, the contribution of soil arching effect to slope stability is evaluated using the FEM software (Plaxis 3D) with the built-in strength reduction technique. The result indicates the depth of the failure surface is influenced by the S/D ratio (the distance to the diameter of piles), which can reflect the contribution of the soil arching effect to soil stability. When α (rock inclination angles)=β (slope angles) is considered and the S/D ratio=4, the failure surface of the slope is not significantly influenced by the piles. Overall, the soil arching effect is more significant on α=β, especially for the steep slopes. Additionally, the soil arching effect has been included in the proposed stability charts. The proposed charts were validated through two case studies, including that of the well-known Woo-Wan-Chai field in Taiwan. The differences in safety factor (FoS) values between the referenced literature and this study was approximately 4.9%.

Flutter stability of a long-span suspension bridge during erection

  • Han, Yan;Liu, Shuqian;Cai, C.S.;Li, Chunguang
    • Wind and Structures
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    • v.21 no.1
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    • pp.41-61
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    • 2015
  • The flutter stability of long-span suspension bridges during erection can be more problematic and more susceptible to be influenced by many factors than in the final state. As described in this paper, numerical flutter stability analyses were performed for the construction process of Zhongdu Bridge over Yangtze River using the commercial FE package ANSYS. The effect of the initial wind attack angle, the sequence of deck erection, the stiffness reduction of stiffening girders, the structural damping, and the cross cables are discussed in detail. It was found that the non-symmetrical sequence of deck erection was confirmed to be aerodynamically favourable for the deck erection of long-span suspension bridges and the best erection sequence should be investigated in the design phase. While the initial wind attack angle of $-3^{\circ}$ is advantageous for the aerodynamic stability, $+3^{\circ}$ is disadvantageous compared with the initial wind attack angle of $0^{\circ}$ during the deck erection. The stiffness reduction of the stiffening girders has a slight effect on the flutter wind speed of the suspension bridge during erection, but structural damping has a great impact on it, especially for the early erection stages.

Thermal Stability of Silicon-containing Diamond-like Carbon Film (실리콘 함유 DLC 박막의 내열특성)

  • Kim, Sang-Gweon;Kim, Sung-Wan
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.2
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    • pp.83-89
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    • 2010
  • Diamond-like carbon (DLC) coating was studied to be a good tribological problem-solver due to its low friction characteristics and high hardness. However, generally hydrogenated DLC film has shown a weak thermal stability above $300^{\circ}C$. However, the silicon doping DLC process by DC pulse plasma enhanced chemical vapor deposition (PECVD) for the new DLC coating which has a good characterization with thermal stability at high temperature itself has been observed. And we were discussed a process for optimizing silicon content to promote a good thermal stability using various tetramethylsilane (TMS) and methane gas at high-temperature. The chemical compositions of silicon-containing DLC film was analyzed using X-ray photoelectron spectroscopy (XPS) before and after heat treatment. Raman spectrum analysis showed the changed structure on the surface after the high-temperature exposure testing. In particular, the hardness of silicon-containing DLC film showed different values before and after the annealing treatment.

Quality Enhancement of Falcataria-Wood through Impregnation

  • SUMARDI, Ihak;DARWIS, Atmawi;SAAD, Sahriyanti;ROFII, Muhammad Navis
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.5
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    • pp.722-731
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    • 2020
  • The purpose of this research is to determine the efficiency of impregnation using phenol formaldehyde resin to enhance Falcataria wood's stability and better mechanical properties. Impregnation process was carried out after moisture content stabilized at 12% on samples with a dimension of 20 mm × 20 mm × 300 mm at various concentrations and pressure time. Dimensional stability was evaluated by thickness swelling (TS) and anti-swelling efficiency (ASE) and the young's modulus was conducted according to BS 573. The mechanical properties and dimensional stability of impregnated wood were evaluated. Dimensional stability and mechanical properties of Falcataria wood were successfully increased after impregnation. PF impregnation can improve the mechanical properties and the density from 0.26 g/㎤ to 0.30 g/㎤ even with only 10% of weight percent grain. Dimensional stability increases with increasing resin concentration and time pressure. The highest increase in mechanical properties was found at a higher concentration of PF. The penetration of PF into the wood's cell darkens the color of impregnated wood.