• Title/Summary/Keyword: Technology Transfer Agreement

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Corrosion Inhibition Studies on Low Carbon Steel in Hydrochloric Acid Medium Using o-Vanillin-Glutamine Schiff Base

  • Thusnavis, G. Rexin;Archana, T.V.;Palanisamy, P.
    • Corrosion Science and Technology
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    • v.21 no.1
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    • pp.32-40
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    • 2022
  • The o-Vanillin - Glutamine Schiff base [2-Hydroxy-3-Methoxy BenzylidineCarbomyl) -2-Butanoic Acid] was examined for low carbon steel corrosion inhibition in acid media. Weight loss studies were carried out at three different temperatures to determine the inhibition efficiency (IE). Electrochemical impedance spectroscopy revealed that the charge transfer resistance controlled the corrosion reaction and Tafel polarization indicated that the Schiff base acts as mixed mode of inhibitor. SEM images were recorded for the surface morphology of the low carbon steel surface. DFT studies revealed corrosion control mechanisms using quantum chemical parameters such as EHOMO, ELUMO, energy gap (∆E), chemical Hardness (η), chemical Softness (σ), Electronegativity (χ), and the fraction of electron transferred (∆N), which is calculated using Gaussian software 09. The gas-phase geometry was fully optimized in the Density Functional Theory (DFT/B3LYP-6-31G (d)).The DFT results are in good agreement with the experimental results. All the results proved that the Schiff Base (2-Hydroxy-3-Metoxy BenzylidineCarbomyl) -2-Butanoic is a suitable alternative for corrosion inhibition of low carbon steel in acid media.

Experimental study on vertically upward steam-water two-phase flow patterns in narrow rectangular channel

  • Zhou, Jiancheng;Ye, Tianzhou;Zhang, Dalin;Song, Gongle;Sun, Rulei;Deng, Jian;Tian, Wenxi;Su, G.H.;Qiu, Suizheng
    • Nuclear Engineering and Technology
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    • v.53 no.1
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    • pp.61-68
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    • 2021
  • Experiments of vertically upward steam-water two-phase flow have been carried out in single-side heated narrow rectangular channel with a gap of 3 mm. Flow patterns were identified and classified through visualization directly. Slug flow was only observed at 0.2 MPa but replaced by block-bubble flow at 1.0 MPa. Flow pattern maps at the pressure of 0.2 MPa and 1.0 MPa were plotted and the difference was analyzed. The experimental data has been compared with other flow pattern maps and transition criteria. The results show reasonable agreement with Hosler's, while a wide discrepancy is observed when compared with air-water two-phase experimental data. Current criteria developed based on air-water experiments poorly predict bubble-slug flow transition due to the different formation and growth of bubbles. This work is significant for researches on heat transfer, bubble dynamics and flow instability.

Channel characteristics of multi-path power line using a contactless inductive coupling unit (비접촉식 유도성 결합기를 이용한 다중경로 전력선 채널 특성)

  • Kim, Hyun-Sik;Sohn, Kyung-Rak
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.9
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    • pp.799-804
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    • 2016
  • Broadband powerline communication (BPLC) uses distribution lines as a medium for achieving effective bidirectional data communication along with electric current flow. As the material characteristics of power lines are not good at the communication channel, the development of power line communication (PLC) systems for internet, voice, and data services requires measurement-based models of the transfer characteristics of the network suitable for performance analysis by simulation. In this paper, an analytic model describing a complex transfer function is presented to obtain the attenuation and path parameters for a multipath power line model. The calculated results demonstrated frequency-selective fading in multipath channels and signal attenuation with frequency, and were in good agreement with the experimental results. Inductive coupling units are used as couplers for coupling the signal to the power line to avoid physical connections to the distribution line. The inductance of the ferrite core, which depends on the frequency, determines the cut-off frequency of the inductive coupler. Coupling loss can be minimized by increasing the number of windings around the coupler. Coupling efficiency was improved by more than 6 dB with three windings compared to the results obtained with one winding.

The Development of the ±80kV 60MW HVDC System in Korea

  • Park, Kyoung-Ho;Baek, Seung-Taek;Chung, Yong-Ho;Jang, Gil-Soo
    • Journal of Electrical Engineering and Technology
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    • v.12 no.2
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    • pp.594-600
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    • 2017
  • HVDC transmission systems can be configured in many ways to take into account cost, flexibility and operational requirements. [1] For long-distance transmission, HVDC systems may be less expensive and suffer lower electrical losses. For underwater power cables, HVDC avoids the heavy currents required to charge and discharge the cable capacitance of each cycle. For shorter distances, the higher cost of DC conversion equipment compared to an AC system may still be warranted, due to other benefits of direct current links. HVDC allows power transmission between unsynchronized AC transmission systems. Since the power flow through an HVDC link can be controlled independently of the phase angle between the source and the load, it can stabilize a network against disturbances due to rapid changes in power. HVDC also allows the transfer of power between grid systems running at different frequencies, such as 50 Hz and 60 Hz. This improves the stability and economy of each grid, by allowing the exchange of power between incompatible networks. This paper proposed to establish Korean HVDC technology through a cooperative agreement between KEPCO and LSIS in 2010. During the first stage (2012), a design of the ${\pm}80kV$ 60MW HVDC bipole system was created by both KEPCO and LSIS. The HVDC system was constructed and an operation test was completed in December 2012. During the second stage, the pole#2 system was fully replaced with components that LSIS had recently developed. LSIS also successfully completed the operation test. (2014.3)

Analytical, Numerical, and Experimental Comparison of the Performance of Semicircular Cooling Plates (반원형 구조의 냉각판 성능에 관한 해석적/수치해석적/실험적 비교)

  • Cho, Kee-Hyeon;Kim, Moo-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.12
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    • pp.1325-1333
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    • 2011
  • An analytical, numerical, and experimental comparison of the hydraulic and thermal performance of new vascular channels with semicircular cross sections was conducted. The following conditions were employed in the study: Reynolds number, 30-2000; cooling channels with a volume fraction of the cooling channels, 0.04; and pressure drop, $30-10^5$ Pa. Three flow configurations were considered: first, second, and third constructal structures with diameters optimized for hydraulic operations. To validate the proposed vascular designs by an analytical approach, 3-D numerical analysis was performed. The numerical model was also validated by the experimental data, and the comparison results were in excellent agreement in all cases. The validation study against the experimental data showed that compared to traditional channels, the optimized structure of the cooling plates could significantly enhance heat transfer and decrease pumping power.

Effects of Char Produced from Burning Wood Combustibles on Thermal Pyrolysis (목재 가연물의 연소 시 생성되는 탄화가 열분해에 미치는 영향)

  • Hong, Ter-Ki;Ryu, Myung-Ho;Lee, Jong Won;Park, Seul-Hyun
    • Fire Science and Engineering
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    • v.33 no.5
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    • pp.7-12
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    • 2019
  • To investigate the influence of the char layer formed during the combustion process on the pyrolysis of wood combustibles, ISO 5660-1 cone calorimetry experiments and Fire dynamics simulator (FDS) simulations were performed, and the results from these two methods were compared. The wood combustible selected as the fuel for this study, Douglas fir, has been widely used for the production of building materials, furniture, etc. The heat release rate (HRR) measured from the cone calorimetry experiment was in good agreement with the result predicted by the FDS simulation. However, the FDS simulation failed to predict the heat released by the smoldering combustion process, due to the absence of the char surface reaction in the model. The FDS simulation results clearly indicate that the char layer formed on the surface of combustibles produces a thermal barrier which prevents heat transfer to the interior, thickening the thermal depth and thus reducing the pyrolysis rate of combustibles.

A Comparison Analytical Study on the B2B Electronic Trade Settlement System (B2B 전자무역대금결제시스템 비교.분석에 관한 연구)

  • Song Yong-Jong
    • Management & Information Systems Review
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    • v.14
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    • pp.151-180
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    • 2004
  • Owing to the digital revolution, Internet Commerce and Electronic commerce, revolutionize the way of doing business and making payment. The entrance of the Internet has a prominent for spread of Electronic Commerce and those phenomenons will result in paperless trading and cashless trade. By virtue of Internet, an increasing share of business transactions occurs online. Electronic payment is essential for the smooth progress of the electronic commerce as electronic payment plays the important role in the electronic commerce, that is, the value transfer restyling from the electronic commerce. Traditionally international settlement systems such as letters of credits, remittance and documentary collections operated as important and poplar method of payment, Now, information technology has made it possible to pay for the sale of goods and services over the internet. In international trade, there are service providers (bolero, TradeCard, BeXcom) to settle payment electronically through the Internet. The purpose of this study is to Conduct comparative analysis with approach manner functional respect systematic respect, role. It is shown which the Electronic payment system is better. In this study, the author attempts to find the problems is (bolero, TradeCard, BeXcom) and solutions in switching from the documentary payment system to the electronic one. This conclusion of this study can be summarized as followings. In resoect of the law, bolero should seek to prevert the users from being treated unfairly due to multilateral agreement on Rulebook. TradeCard, BeXcom do not have the proper law that users are governed. so far as the practice problems concerned, stability of computer's operation and security of message interchange should be warranted and improved continuously. Through the standardization of the electronic document and the development of software, the examination of the shipping occuments must be done automatically. Bolero should induce more banks to take part in Bolero, and make the carrier the cost and time in managing the traditional document which will be used for the time being. In respect of information technology and security, to deduce the risk in the electronic settlement system and positively uses the global authentication guideline(Identrus).

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Far-ultraviolet Observations of the Taurus-Perseus-Auriga Complex

  • Lim, Tae-Ho;Min, Kyoung-Wook;Seon, Kwang-Il
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.98.2-98.2
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    • 2012
  • We firstly present the unified Far-UV continuum map of the Taurus-Auriga-Perseus (TPA) complex, one of the largest local associations of dark cloud located in (l, b)=([154,180], [-28, -2]), by merging both FIMS and GALEX. The FUV continuum map shows that dust extinction correlate well with the FUV around the complex. It shows strong absorption in FUV toward the dense Taurus cloud while it does not in California cloud. It turned out that it is related to the relative location of each cloud and Perseus OB2 association. We also present some results of dust scattering simulation based on Monte Carlo Radiative Transfer technique (MCRT). Through this dust scattering simulation, we have derived the scattering parameter for this region, albedo(a)=$0.42^{+0.05}{_{-0.05}}$, asymmetry factor(g)=$0.47^{+0.11}{_{-0.27}}$. The optical parameters we obtained seem reasonable compared to the theoretical model values ~0.40 and ~0.65 for the albedo and the phase function though the phase function is rather small. Using the result of simulation, we figured out the geometries of each cloud in the complex region, especially their distances and thicknesses. Our predictions from the results are in good agreement with the previous studies related to the TPA complex. For example, the Taurus cloud is within ~200pc from the Sun and the Perseus seems to be multi-layered, at least two. The California cloud is more distant than the other cloud on average at ~350 pc and Auriga cloud seems to be between the Taurus cloud and the eastern end of the California cloud. We figured out that across the TPA complex region, there might be some correlation between the LSR velocity and the distance to each cloud in the complex.

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Development of a Simultaneous CAE System for the Application to Large Steel Castings (대형주강품에 대한 CAE 시스템 개발 연구)

  • Lee, Young-Chul;Lee, Doo-Ho;Kim, Jong-Ki;So, Chan-Young;Choi, Jeong-Kil;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.17 no.5
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    • pp.465-471
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    • 1997
  • An integrated computer program consisting of a pre-processor, main solver, and post-processor was developed for the design of large steel castings. The pre-processor, based on the AutoCAD, enables the user to produce approval drawings, casting design drawings and mesh diagrams in sequence using a personal computer. In the main solver, two numerical models were employed; one models the fluid flow during mold filling, and the other models the heat transfer and solidification. The post-processor can be used to present simulation results such as flow pattern, mold filling sequences, solidification times, temperature gradients and location of shrinkage defects by color graphics. In order to validate the applicability of the present integrated program, a series of experiments on simple-shaped steel castings were carried out. After the validation of the present model, it was applied to the casting design of the large steel anchor of an SC42 alloy. Various solidification parameters such as a temperature distribution and a solidification time in the casting and the mold were compared with those obtained experimentally. Simulated results predicting shrinkage defects were in good agreement with those obtained experimentally. It was found that the present method can be successfully applied to the quantitative casting design for complex-shaped large steel castings.

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Experimental and numerical studies on the shear connectors in steel-concrete composite beams at fire and post fire exposures

  • Mirza, Olivia;Shil, Sukanta Kumer;Rashed, M.G.;Wilkins, Kathryn
    • Steel and Composite Structures
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    • v.39 no.5
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    • pp.529-542
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    • 2021
  • Shear connectors are required to build composite (concrete and steel) beams. They are placed at the interface of concrete and steel to transfer shear and normal forces between two structural components. Such composite beams are sensitive to provide structural integrity when exposed to fire as they loss strength, stiffness, and ductility at elevated temperature. The present study is designed to investigate the shear resistance and the failure modes of the headed stud shear connectors at fire exposure and post-fire exposure. The study includes ordinary concrete and concrete with carbon nanotubes (CNTs) to build composite (concrete-steel) beams with structural steel. Experimental push tests were conducted on composite beams at ambient and elevated temperatures, such as 200, 400 & 600℃. Moreover, push tests were performed on the composite beams after being exposed to 200, 400 & 600℃. Push test results illustrated the reduction of ultimate shear capacity and stiffness of headed stud shear connectors as the temperature increased. Although similar values of ultimate shear were obtained for the headed stud connectors in both ordinary and CNT concrete, the CNT modified concrete reduced the concrete spalling and cracking compared to ordinary concrete and was observed to be effective at temperatures greater than 400℃. All specimens showed a lower shear resistance at fire exposures compared to the corresponding post-fire exposures. Moreover, numerical simulation by Finite Element (FE) analyses were carried out at ambient temperature and at fire conditions. The FE analysis results show a good agreement with the experimental results. In the experimental studies, failure of all specimens occurred due to shear failure of headed stud, which was later validated by FE analyses using ABAQUS.