• Title/Summary/Keyword: Synthesis optimization

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Mathematical Planning for Revealing Optimal Synthetic Conditions of Naphthalene Chloromethylation

  • Pak, V.V.;Karimov, R.K.;Shakhidoyatov, Kh.M.;Yun, L.M.;Soh, D.W.
    • Journal of the Speleological Society of Korea
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    • no.71
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    • pp.1-4
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    • 2006
  • Chloromethylnaphthalene is a valuable compound for obtaining of the plant growing stimulator - -napthylacetic acid. Chloromethylation of naphthalene by paraformaldehyde in the presence of glacial acetic acid, phosphoric and hydrochloric acids at temperature 80 - 85C and duration - 6 hours the -chloromethylnaphthalene yield was 55-57%. Using Box-Wilson method for mathematical planning of experiment carried out optimization of its synthesis for purpose increasing -chloromethylnaphthalene yield. Preliminary, one - factor experiments were carried out for selecting independence main parameters influencing on the synthesis. A full factor experiment of 23 with extended matrix of planning was used for optimization. Aiming to increase the -chloromethylnaphthalene yield, the obtained mathematical model was used for program of sharp raising on the reply surface. The received optimal conditions for the -chloromethylnaphthalene synthesis were selected as following: molar ratio of naphthalene parapfsormaldehyde of 1 : 2 temperature - 105C duration of the reaction - 3 hours. The yield of -chloromethylnaphthalene under these optimal conditions was 75%.

Optimization of Reaction Conditions for High Yield Synthesis of Carbon Nanotube Bundles by Low-Temperature Solvothermal Process and Study of their H2 Storage Capacity

  • Krishnamurthy, G.;Agarwal, Sarika
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3046-3054
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    • 2013
  • Synthesis of Carbon Nanotube bundles has been achieved by simple and economical solvothermal procedure at very low temperature of $180^{\circ}C$. The product yield obtained was about 70-75%. The optimization of reaction conditions for an efficient synthesis of CNTs has been presented. The CNTs are obtained by reduction of hexachlorobenzene in the presence of Na/Ni in cyclohexane. The X-ray diffraction, Fourier transform infrared and Raman spectral studies have inferred us the graphene structure of the products. The CNTs formed as the bundles were viewed on scanning electron microscope, transmission electron microscope and high-resolution transmission electron microscope. These are the multiwalled CNTs with outer diameter of 5-10 nm, the inner diameter 2-4 nm and cross sectional diameter up to 5 nm. Brunauer-Emmett-Teller (BET) based $N_2$ gas adsorption studies have been made to obtain BET surface area and $H_2$ storage capacity. Effect of the experimental variables such as reaction temperature, amount of catalyst and the amount of carbon source were investigated. It is found that they affect significantly on the product nature and yield.

Optimum Design of a Viscous-driven Micropump with Tandem Rotating Cylinders (한 쌍의 실린더를 가진 점성구동 마이크로 펌프의 최적설계)

  • Choi, Hyung-Il;Kim, Ki-Dong;Cho, Il-Dae;Choi, Dong-Hoon;Maeng, Joo-Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.4
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    • pp.378-385
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    • 2004
  • Viscous-driven pumping is a very promising type in microscale applications. However, there exist a few disadvantages such as low efficiency and small volume flow rate. In the present study, a pump with tandem rotating cylinders and its optimum synthesis are proposed fur enhancing pumping performance. First, using an unstructured grid CFD method, we investigate the effects of geometrical parameters and then the performance of the pump with tandem cylinders is evaluated. Next, an optimum design synthesis tool is constructed by combining the aforementioned CFD analysis model with the mathematical optimization model, namely, Modified Method of Feasible Directions (MMFD). This technique is used to optimize the geometrical parameters of the pump, fur maximizing pumping efficiency. From the optimization results, it is believed that the present optimum synthesis is robust and has a potential fur other microfluidic device design.

Chloromethylation of Naphthalene and Mathematical Planning of Experiment for Revealing Optimal Synthetic Conditions

  • V.V. Pak;R.K. Karimov;Kh.M. Shakhidoyatov;L.M. Yun;Soh, Dea-Wha
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2004.05a
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    • pp.36-37
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    • 2004
  • $\alpha$-Chloromethylnaphthalene is a valuable compound for obtaining of the plant growing stimulator - $\alpha$-napthylacetic acid. Chloromethylation of naphthalene by paraformaldehyde in the presence of glacial acetic acid, phosphoric and hydrochloric acids at temperature 80-85$^{\circ}C$ and duration - 6 hours the $\alpha$-chloromethyl-naphthalene yield was 55-57%. Using Box-Wilson method for mathematical planning of experiment carried out optimization of its synthesis for purpose increasing $\alpha$-chloromethylnaphthalene yield. Preliminary, one - factor experiments were carried out for selecting independence main parameters influencing on the synthesis. A full factor experiment of 2$^3$with extended matrix of planning was used for optimization. Aiming to increase the $\alpha$-chloromethylnaphthalene yield, the obtained mathematical model was used for program of sharp raising on the reply surface. The received optimal conditions for the $\alpha$-chloromethylnaphthalene synthesis were selected as following: molar ratio of naphthalene - parapfsormaldehyde of 1 : 2; temperature -105$^{\circ}C$; duration of the reaction -3 hours. The yield of $\alpha$-chloromethylnaphthalene under these optimal conditions was 75 %.

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H_{\infty} Control Synthesis for Power System Design using LMI Optimization Method (LMI 최적화기법을 적용한 $H_{\infty}$제어 시스템의 전력계통 안정화장치(PSS) 설계)

  • Jeong, Dae-Won;Ju, Un-Pyo;Kim, Geon-Jung
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.49 no.4
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    • pp.165-174
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    • 2000
  • This paper presents the application of H$\infty$ control synthesis using LMI optimization method to power system stabilizer(PSS) design. Since power system is usually operated under circumstance of unmeasurable uncertainties and external disturbances, the improvement of small signal stability becomes one of the most important issue for securing system stability and preventing low frequency oscillation phenomena. The LMI optimized H$\infty$ PSS provides robust performance and guarantees the internal stability under these operating conditions. The global optimal H$\infty$ norm is found using LMI convex optimization method which is more systematic than standard two Riccati solution method. The design results are simulated for a case study. We verified that the LMI method shows the best performance characteristic smong standard Riccati method and conventional lead/lag method.

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Beam pattern analysis for beam homogenization of conformal array sonar (곡면 배열 소나의 빔 균일화를 위한 빔 패턴 분석)

  • Jeong-Ung, Choi;Wooyoung, Hong;Jun-Seok, Lim;Keunhwa, Lee
    • The Journal of the Acoustical Society of Korea
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    • v.41 no.6
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    • pp.637-646
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    • 2022
  • Sub-arrays of arbitrary conformal array have different geometric shape through steering direction, thus the beam patterns of sub-arrays are always non-uniform. In this paper, we apply the beam pattern synthesis method using convex optimization into the conformal array, and shows the improvement of uniformity of beam performance. The simulation is performed with the conformal array of cut-sphere shape. As a result, the standard deviation of 3 dB beamwidth in elevation is greatly reduced but the directivity index is also reduced. To alleviate this trade-off, we propose a convex optimization using a shading function.

Dimensional synthesis of an Inspection Robot for SG tube-sheet

  • Kuan Zhang;Jizhuang Fan;Tian Xu;Yubin Liu;Zhenming Xing;Biying Xu;Jie Zhao
    • Nuclear Engineering and Technology
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    • v.56 no.7
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    • pp.2718-2731
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    • 2024
  • To ensure the operational safety of nuclear power plants, we present a Quadruped Inspection Robot that can be used for many types of steam generators. Since the Inspection Robot relies on the Holding Modules to grip the tube-sheet, it can be regarded as a hybrid robot with variable configurations, switching between 4-RRR-RR, 3-RRR-RR, and two types of 2-RRR-RR, and the variable configurations bring a great challenge to dimensional synthesis. In this paper, the kinematic model of the Inspection Robot in multiple configurations is established, and the analytical solution is given. The workspace mapping is analyzed by the solution-space, and the workspace of multiple configurations is decomposed into the workspace of 2-RRR to reduce the analysis complexity, and the workspace calculation is simplified by using the envelope rings. The optimization problem of the manipulator is transformed into the calculation of the shortest contraction length of the swing leg. The switching performance of the Inspection Robot is evaluated by stride-length, turning-angle, and workspace overlap-ratio. The performance indexes are classified and transformed based on the proportions and variation trends of dimensional parameters to reduce the number of optimization objective functions, and Pareto optimal solutions are obtained using an intelligent optimization algorithm.

A simulation study on synthesis gas process optimization for FT(Fischer-Tropsh) synthesis (FT(Fischer-Tropsh) 합성유 제조를 위한 합성가스 공정 최적화 연구)

  • Kim, Yong-Heon;Lee, Won-Su;Lee, Heoung-Yeoun;Koo, Kee-Young;Song, In-Kyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.888-888
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    • 2009
  • A simulation study on SCR (Steam Carbon dioxide Reforming) process in gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for GTL (gas-to-liquid) process reaction. Optimum SCR operating conditions for synthesis gas to FT (Fischer-Tropsch) process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. SCR process was considered as reaction models for synthesis gas in GTL proess. The effect of temperature and pressure on SCR process $H_2$/CO ratio and the effect of reaction pressure on SCR reaction were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

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Performance-driven Automatic Logic Synthesis System (성능 구동 논리 회로 자동 설계 시스템)

  • 이재형;황선영
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.28A no.1
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    • pp.74-84
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    • 1991
  • This paper presents an algorithm for technology-dependent logic optimization and technology mapping, and describes a performance-driven logic synthesis system, SILOS, implemented based on the proposed algorithm. The system analyzes circuits and resynthesizes the critical sections such that generated circuit operates opertes within time constraints, using only gate types supported by library for direct implementation. Experimental results show that the system can be a viable tool in synthesizing high-performance logic circuits.

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