• Title/Summary/Keyword: Surface hydration

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Field Application of Surface Insulation Curing Method to Cold Weather Concreting (한중콘크리트의 현장 표면단열 양생공법 시공사례 연구)

  • Kim Jong-Back;Lim Choon-Goun;Han Min-Cheol;Kim Seoung-Soo;Han Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.11a
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    • pp.25-28
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    • 2005
  • This study investigates the field application of surface insulation curing method, which combined double layer bubble sheet(DBS) and thick-curing-material(TCM) for cold weather concreting. According to the test, deck slab, curing only upper section with DBS and TCM, does not make big different temperature history with that, curing both upper and bottom section during daily average temperature 6.5t. It is concluded that combination of DBS and TCM in only upper section can be safely cured in early period of time during cold water concreting. The field test was carried out with this favourable data. The upper deck slab was insulated by combination of DBS and TCM, and the construction was surrounded by tent. in order to protect from outside wind. The test result shows that the lowest temperature of deck slab indicated 6$ ^{circ}C $. It demonstrated that this curing method can resist early frost and save construction cost in the side of management and saving labor cost, compared with previous method. In addition, the column specimen, combined both form and bubble board, exhibited favorable temperature history, due to internal hydration heat insulation effect.

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Conformational Analysis of Catecholamines-Raman, High Resolution NMR, and Conformational Energy Calculation Study

  • Park Mi-Kyung;Yoo Hee-Soo;Kang Young Kee;Lee Nam-Soo;Ichiro Hanazaki
    • Bulletin of the Korean Chemical Society
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    • v.13 no.3
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    • pp.230-235
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    • 1992
  • The conformational analysis has been done for catecholamines (dopamine, norepinephrine, and epinephrine) in the cationic and di-anionic states. The species responsible for adsorption on silver metal surface is anionic deprotonated at hydroxyl groups of catechol moiety, i.e., di-anionic states of catecholamines. This was deduced from Fourier-transform Raman spectra of sodium salts of catecholamines. High resolution proton NMR (400 MHz) spectra of catecholamines in basic and neutral $D_2O$ solution show that the conformations of norepinephrine and epinephrine in the di-anionic states are preferred in gauche, but not for dopamine in the di-anionic state. However the energy difference between trans and gauche of catecholamines in the protonated cationic states is small enough to rotate freely through C-C bond in ethylamine moiety. The conformational calculations using an empirical potential function and the hydration shell model (a program CONBIO) show consistent with above experimental results. The calculations suggest that the species of catecholamines adsorbed on silver metal surface would be in favor of the gauche conformations.

Epidermal Condition of Women By Health Promotion Behavior (성인여성의 건강증진 행위에 따른 안면 피부 상태)

  • Lee, Jeong-Ran;Hong, Hae-Sook
    • Journal of Korean Biological Nursing Science
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    • v.2 no.2
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    • pp.20-37
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    • 2000
  • The purpose of this study was to investigate the relationships between the differentials in life styles and their effect on the epidermal facial tissue in order to provide a basis for health professionals so that they might better be able to maintain and promote healthy skin care and further delay the premature ageing of the epidermal facial tissue. The subjects consisted of 145 females of various ages who visited skin care room in cerming health promoting behaviors(Park In sook's Profile) and questions on their behavioral practices pertaining to personal skin care were used. The investigation also ess of the four parts of the epidermal facial tissue studied. All data collected wee entered into the SAS program and analyzed for frequency, percentages, the utilized Pusan. The study dates ranged from May 1, 1998 to May 30, 1998. The methods used for this investigation were a questionnaire survey consisting of general objective questions. The questions con a "skin analyzer" to measured levels of moisturizing hydrated, facial oils, and roughnmean, t-test, ANOVA, and Pearson Correlation Coefficients. The results of this study were as follows ; 1. Epidermal facial oil was at its highest levels in the chin area with additional decreasing levels in the forehead and nose regions. The least regions were those of the cheeks. The highest levels of hydration on the other hand started with the forehead followed by the area of the chin, the cheeks and the lowest level of epidermal facial hydration was in the region of the nose. 2. The average score of the performance in the health promoting behaviors variable was 139.51. The variables with the highest degree of the performance were rest and sleeping(35.71). The lowest degree was hiegenic life(23.44). 3. The relationship health promoting behaviors and epidermal condition was not correlated with oil, hydration and roughness of the skin surface. 4. Skin care behavioral characteristics related to epidermal condition were washing style and temperature of washing water. 5. General characteristics related to epidermal condition were occupation, education level, acne and melasma. In conclusion, this study showed that several factors were significant in the behavior of skin care. Clear knowledge of both internal and external factors which affect the epidermal condition will help women to pursue active and appropriate practices in their health behaviors and skin care.

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Method of Decreasing Cracking Index by Different Mix Conditions for Separated Placement and its Field Application (콘크리트 배합요인별 상·하부 분리타설에 의한 수화열 균열지수 저감방안 및 현장적용)

  • Kim, Min-Ho;Han, Cheon-Goo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.292-298
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    • 2016
  • In this research, considering the practical situation of separated placing method for mass concrete structure, an efficient method of controlling the heat of hydration is suggested by comparing between the simulated values and actual measurements conducted with the optimum mix design obtained from the various mix conditions with different types and amount of supplementary cementitious materials(SCMs). As the result of the research, firstly, the optimum mix designs for top and bottom layers were determined by Midas gen as OPC to FA of 85 to 15, and OPC to FA to BS of 50 to 20 to 30, respectively. The concrete mixtures prepared with the mix designs determined from the simulation satisfied the target performance range in slump, air content and compressive strength. Additionally, from temperature measurement for the actual mass concrete placed during spring, the maximum temperature difference between surface and core was about $10^{\circ}C$ with 59 and $49^{\circ}C$ for top and bottom layers, respectively, and 1.4 of cracking index was obtained. Therefore, considering the practical conditions of mass concrete construction, it is considered that the different heat of hydration method using different mix designs with SCMs can be an efficient method for controlling thermal cracking and settling cracking of mass concrete.

A Study on the Strength Property of Recycled Fine Aggregate (Wet Type) Mortar with Blast Furnace Slag (고로슬래그를 사용한 습식 순환 잔골재 모르타르의 강도 특성에 관한 연구)

  • Shim, Jong-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.5
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    • pp.153-160
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    • 2010
  • This study aims to obtain technical data for improvement of utilization of Blast Furnace Slag(BFS), recycled aggregate in the future by complementing fundamental problems of BFS such as manifestation of initial strength and excessive alkali quantity as well as weakness of recycled fine aggregate through manufacturing of recycled fine aggregate mortar using BFS. The recycled aggregate includes the cement paste hardened as the surface and the type of the aggregate, which contains plenty of calcium hydroxide($Ca(OH)_2$) as well as the unhydrated cement. Accordingly, the objectives of this study are to inspect the manufacturing the recycled fine aggregate mortar used with blast furnace slag, to consider the effects of the recycled aggregate on the strength development of ground granulated blast furnace slag, and then to acquire the technical data to take into consideration the further usages of the recycled aggregate and blast furnace slag. In eluted ions from recycled aggregate, it showed that there were natrium($Na^+$) and kalium($K^+$), expected to be flown out of unhydrated cement, as well as calcium hydroxide($Ca(OH)_2$). Application of this water to mix cement mortar with ground granulated blast furnace slag was observed to expedite hydration as calcium hydroxide($Ca(OH)_2$) and unhydrated cement component were expressed to give stimuli effects on ground granulated blast furnace slag. The results of the experiment show that the recycled aggregate mixed with blast furnace slag has comparatively higher hydration activity in 7 day than the mortar not mixed with one in 3 day mortar does, causing the calcium hydroxide in the recycled fine aggregate to work on as a stimulus to the hydration of ground granulated blast furnace slag.

Evaluation of Hydration Characteristics and NOx-removal Performances of Cement Paste Containing Refined TiO2 Obtained from Waste Sludge (폐수 슬러지에서 정제된 TiO2를 혼입한 시멘트 페이스트의 수화특성 및 질소산화물 제거 성능 평가)

  • Yoon, Hyunno;Seo, Joonho;Kim, Seonhyeok;Bae, Jinho;Kil, Taegeon;Lee, Haeng-Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.4
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    • pp.357-364
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    • 2021
  • The present study investigated the hydration properties and NOx-removal performances of the cement pastes containing three different types of TiO2. Two commercially available TiO2 (P-25 and NP-400) and refined TiO2 (GST) obtained from waste sludge were incorporated to cement paste at levels of 0, 5, 10, and 20 wt%. Isothermal calorimetry test results indicated that the TiO2 incorporation induced a notable influence on the reaction kinetics of cement paste, showing the highest cumulative heat release in the samples containing P-25, followed by NP-400 and GST. Quantitative X-ray diffractometry as calculated by the Rietveld method identified that the incorporated TiO2 promoted the formation of C-S-H, ultimately leading to the enhancement in the 28 day-compressive strength of cement pastes. As revealed by SEM/EDS analysis, the content of distributed Ti elements on the surface of the samples was in the order of P-25, GST, and NP-400. Regardless, the NOx-removal performance was the highest in the sample containing P-25, followed by NP-400 and GST.

Carbonation Resistance Property of Mortar using Electrolysis Aqueous (전기분해수를 배합수로 활용한 모르타르의 탄산화 저항 특성)

  • Jeong, Su-Mi;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.204-210
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    • 2022
  • Cement is pointed out as the main cause of carbon dioxide emission in the construction industry. Many researchs are underway to use blast furnace slag, an industrial by-product, as a substitute for cement to reduce carbon dioxide emitted during the manufacturing the cement. When blast furnace slag is used as a substitute for cement, it has advantages such as long-term strength and chemical resistance improvement. However, blast furnace slag has a problem that makes initial strength low. This is due to the impermeable film on the surface created during the production of blast furnace slag. The created film is known to be destroyed in an alkaline environment, and based on this, previous studies have suggested a solution using various alkali activators. But, alkali activator is dangerous product since it is a strong alkaline material. And it has the disadvantage in price competitiveness. In this study, an experiment was conducted to improve the initial hydration reactivity of the blast furnace slag to secure the initial strength of the mortar substituted with the blast furnace slag and to check whether the carbonation resistance was increased. As a result of the experiment, it was confirmed that the mortar using alkaline water showed higher strength than the mortar using tap water, and there were more hydration products generated inside. In addition, it was confirmed that the mortar using alkaline water as a compounding water had high carbonation resistance.

A Study on the Glass Strengthened in Salt Solution by Chemical Ion Exchange (염 용액에서의 화학적 이온교환 강화유리에 관한 연구)

  • 이종근;김인섭
    • Journal of the Korean Ceramic Society
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    • v.24 no.4
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    • pp.335-342
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    • 1987
  • There were several numbers of studies on chemically strengthening glass. Most of them were strengthened in molten salt bath below transformation range of glass. Apart from them, this study used solution hydration technique by Autoclave. After determining proper concentration of AgNO3 salt solution, experimental condition varied from 4hrs to 16hrs at relatively low temperature (180, 200, 220$^{\circ}C$). The results showed that the Soda-Lime-Silica glass could be strengthened by diffusion mechanism without influence of water above 15% salt solution. Because of Ag+ ion penetration in glass surface, yellow color appeared and decreased transmittance at visible range. Modulus of rupture was increased with the amount of exchange and brittleness was decreased.

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Characteristics of Desiccation on the Stabilized Layer in Waste Landfill (쓰레기 매립지에서 표층고화처리층의 건조수축특성)

  • 천병식;임종윤;최창현;차용혁
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.10a
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    • pp.301-308
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    • 1999
  • With the shortage of the land and NIMBY syndrome, it is issued recently that the capacity of waste-landfill site is needed though the decreasing tendency of waste landfill. From this point, the stability is the most essential problem in the landfill that will be constructed. Advanced design and construction are most important for that. In this paper, for the study of desiccation, dry-shrinkage crack from drying and chemical reaction in cement hydration, which is occurred when the surface layer stabilization method is applied in wast landfill, laboratory test of the ground and specimen according to the mixture ratio of stabilizer is performed. From the result, it is notified that the uni-axial strength increases with the stabilizer, but dry-shrinkage increases too, therefore, it is important and the goal of this study to find the optimal mixture ratio of each stabilizer. Analysis of variance for regression with acting variables is performed to find optimal mixture ratio of each stabilizer.

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Study on the Coefficient of Air Convection for Concrete Mix of Nuclear Power Plant (원전 배합 콘크리트의 외기대류계수에 관한 연구)

  • Lee, Yun;Kim, Jin-Keun;Choi, Myoung-Sung;Song, Young-Chul;Woo, Sang-Kyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.148-151
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    • 2004
  • The hardening of concrete after setting is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the tensile cracking. As a result, in order to predict the exact temperature distribution in concrete structures it is required to examine thermal properties of concrete. In this study, the coefficient of air convection for concrete mix of nuclear power plant, which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind and types of form. The coefficient of air convection obtained from experiment increases with velocity of wind, and its dependance on wind velocity is varied with types of form. This tendency is due to a combined heat transfer system of conduction through form and convection to air. The coefficient of air convection for concrete mix of nuclear power plant obtained from this study was well agreed with the existing models.

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