• Journal of the Mineralogical Society of Korea
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• v.31 no.4
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• pp.295-306
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• 2018

Despite the utility of solid-state NMR, NMR studies of iron-bearing silicate glasses remain a challenge because the variations in the peak position and width with increasing iron content reflect both paramagnetic effect and iron-induced structural changes. Therefore, it is essential to elucidate the effect of temperature on the NMR signal for iron-bearing silicate glasses. Here, we report the $^{29}Si$ and $^{27}Al$ MAS NMR spectra for $(Mg_{0.95}Fe_{0.05})SiO_3$ and $Fe_2O_3$-bearing $CaAl_2Si_2O_8$ (anorthite) glasses with varying spinning speed to interpret the NMR spectra for iron-bearing silicate glasses. The increase in the spinning speed results in an increase in the sample temperature. The current NMR results allow us to understand the origins of the changes in NMR signal with increasing iron content and to provide information on the dipolar interaction between nuclear spins. The $^{29}Si$ NMR spectra for $(Mg_{0.95}Fe_{0.05})SiO_3$ glass and $^{27}Al$ NMR spectra for $Fe_2O_3$-bearing $CaAl_2Si_2O_8$ glasses show that the peak shape and position of iron-bearing glasses do not change with increasing spinning speed up to 30 kHz. These results suggest that the NMR signal in the Fe-bearing glasses may stem from the 'survived nuclear spins' beyond the cutoff radius from the Fe, not from the paramagnetic shift. Based on the current results, the observed apparent shifts toward lower frequency of Al peak for $Fe_2O_3$-bearing $CaAl_2Si_2O_8$ glasses with increasing $Fe_2O_3$ at all spinning speed (15 kHz to 30 kHz) indicate the increase in the fraction of ${Q^4}_{Al}$(nSi) with lower n (i.e., 1 or 2) with increasing $Fe_2O_3$ and the spatial proximity between Fe and ${Q^4}_{Al}$(nSi) with higher n (i.e., 3 or 4). The present results show that changes in the NMR signal for iron-bearing silicate glasses reflect the actual iron-induced structural changes. Thus, it is clear that the applications of solid-state NMR for iron-bearing silicate glasses hold strong promise for unraveling the atomic structure of natural silicate glasses.

• Fibers and Polymers
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• v.7 no.4
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• pp.432-435
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• 2006

High Modulus and high tenacity polypropylene fibers have been prepared by drawing on a gradient heater. Results show that fiber properties are significantly affected by temperature profiles of final stage drawing on a gradient heater. The gradient drawn filaments showed superior mechanical properties when compared to filaments drawn over a constant temperature heater. Fibers with initial modulus of 16.4 GPa and tenacity of 670 MPa have been manufactured in the process. The nature of the gradient drawing had a significant effect on end properties. The superior mechanical properties are attributed to the high crystal perfection and crystallinity and low void fractions obtained at high draw ratios when drawn over a gradient heater.

• Journal of computational fluids engineering
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• v.2 no.1
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• pp.37-45
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• 1997

벽면 근처에 가까이 위치하는 회전와류쌍을 음원으로 갖는 비정상 유동장에서 벽면이 음장에 미치는 효과를 알아보기 위해 이차원 음장 수치해석을 시도하였다. 비압축성 유동장에 대한 비정상 수력정보를 기반으로 오일러식에서 교란 압축성 소음항을 도출하였다. 원거리 자유 경계면은 비반사 경계조건을 이용하였으며, 벽면에서는 벽면 효과를 음향장에 고려하였다. 자유흐름장에 놓인 와류쌍이 대칭인 나선팔을 갖는 반면에, 벽면이 있는 경우엔 음파가 전달되는 경로를 따라 방향성이 존재함을 알 수 있었다. 본 연구를 통하여 벽면이 존재하는 경우에 비정상 수력정보를 이용하여 근거리와 원거리 음장을 동시에 수행할 수 있음을 알아내었다.

• Macromolecular Research
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• v.9 no.6
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• pp.313-318
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• 2001

The present study relates to a method of manufacturing 100$\mu\textrm{m}$ thick cover layer for the high density digital versatile disc system (HD-DVD), which uses a high numerical aperture of 0.85 at 405 nm wavelength. Spin coating technique was investigated as means for manufacturing the cover layer within sufficient margins of thickness variation and with good mechanical properties including small radial and tangential tilts. The influence of processing variables such as spinning speed, spinning time, and dispensing position was investigated. The effect of viscosity of UV-curable resin was also investigated.

• Proceedings of the Korean Fiber Society Conference
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• 1999.04a
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• pp.347-348
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• 1999

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2004.04a
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• pp.97-100
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• 2004

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2007.06a
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• pp.147-148
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• 2007

• Proceedings of the Korean Magnestics Society Conference
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• 1998.10a
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• pp.58-59
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• 1998

• International Journal of Industrial Entomology and Biomaterials
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• v.40 no.1
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• pp.28-32
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• 2020

Recently, many studies have been undertaken on the wet spinning and electrospinning of silk because wet-spun fibers and electrospun webs of silk can be applied in the biomedical and cosmetic fields owing to the good biocompatibility of silk. The rheological properties of silk solution are important because they strongly affect the spinning performance of the silk solution and the structures of resultant fibrous materials. Therefore, as a preliminary study on the effect of solvent composition on the rheological properties of silk fibroin (SF) solution and structure of the resultant film, in the reported work, methanol was added to the SF formic acid solution. A small amount of methanol (i.e. 2%) added to the SF formic acid solution significantly altered the rheological properties of the solution: its shear viscosity increased by 10 folds at low shear and decreased on increasing the shear rate, demonstrating shear thinning behavior of the SF solution. Dynamic tests for the SF solution indicated that the addition of 2% methanol altered the viscous state of the SF formic acid solution to elastic. However, the molecular conformation (i.e. β-sheet conformation) of the regenerated SF film cast from formic acid remained unchanged on the addition of 2% methanol.

• The Transactions of the Korean Institute of Electrical Engineers D
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• v.49 no.8
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• pp.459-466
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• 2000

In this paper, we propose an attitude controller for an unstructured object using CMG(Control Moment of Gyro) subsystem, which has a stabilizer function. The CMG subsystem consists of one motor for spinning the wheel and the other motor for turning the outer gimbal. While the wheel of CMG subsystem is spinning at high speed, applying force to the spin axis of the wheel leads the torque about the vertical axis. We utilize the torque to control the attitude of object in this study. For the stabilizer function, in additiion, holding the load at the current position, the power applied to the gimbal motor of CMG will be cut, which result in the braking force to stop the load by gyro effect. However, due to the gear reduction connected to outer gimbal, slow load motion cannot generate the braking force. Thus, in this study, we are willing to make a holding force by applying control power to the gimbal motor from the signal of piezoelectric gyroscopic sensor that detected the angular velocity of the load. These two features are demonstrated in experiment, carrying a beam with crane. As a result, load was started to rotate by controlling gimbal positiion and was stopped by turning off the gimbal power. Moreover, slow movement of the load was also rejected by additional control with gyroscopic sensor.