• Bulletin of the Korean Chemical Society
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• 제19권9호
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• pp.942-947
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• 1998

The >$^13C$ NMR spectrum of >$^13CO$ adsorbed on Pd particles varies dramatically depending on dispersion. The spectrum of highly dispersed Pd particles supported on silica is a powder pattern ∼800 ppm wide with a first moment of 410 ppm. A low dispersion sample has a motionally narrowed line centered at 750±30 ppm and only ∼85 ppm full width at half height (FWHH). Over several years, high dispersion samples show an increase in the intensity near 750 ppm. These observations are interpreted as an increase of mobile bridging CO on high dispersion Pd surfaces of particles which resulted from smoothing of the metal particle surfaces in the presence of CO.

• Journal of Ship and Ocean Technology
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• 제11권3호
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• pp.1-13
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• 2007

A semi-submersible drilling rig is regarded as one of the typical offshore structures operated in the field with moderate environments such as the Gulf of Mexico, Brazil, and West Africa. Its typical roll and pitch natural periods are around 30 seconds, which avoids prevailing regions of the wave energy spectrum, and their responses in waves are quite acceptable for common operation conditions. But large roll and pitch motions can be induced by wave difference frequency energy spectrum if the metacentric heights of a semi-submersible decrease to small values in some loading conditions, and it is because the roll and pitch natural periods increase and approach to the region where the spectral density of the low frequency wave drift moment has significant value. This paper describes the low frequency roll motion of a semi-submersible that are excited by the wave 2nd order difference frequency energy by a series of model experiments. From the model tests with several different initial metacentric heights (GM), it was observed that a semi-submersible can experience large roll motion due to the wave group spectrum.

• 전기학회논문지
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• 제59권12호
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• pp.2245-2249
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• 2010

The physical properties of the LB films with merocyanine dyes have been published and attract attention due to the possibility of molecular structure control. The evaluation of the thin films was focused for the purpose of molecular structure control. The molecular structure in the case of the thin films with dyes can be examine by optical absorption spectra measurements. In the result measured by optical absorption spectra, the $[DX]_{1-x}[DO]_x$ LB films shows a large in-plane anisotropy and the transition dipole moment of red-shifted band is preferentially oriented perpendicular to the dipping direction of the film, while that of the blue-shifted band prefers the dipping direction. The spectrum for $0_{\circ}$, $90_{\circ}$-polarized light coincides with the spectrum for non-polarized light and also with the spectrum was observed in the LB film deposited using a fresh solution. These results show that the aging process does not cause a structural change in chromophore but a change in the degree of molecular orientation. In the results, study of the merocyanine dyes LB films using optical absorption spectra would an interesting problem of absorbance peak shifts and mixed components.

• Journal of Communications and Networks
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• 제16권2호
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• pp.162-171
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• 2014

Spectrum sensing is a key technical challenge for cognitive radio (CR). It is well known that multicycle cyclostationarity (MC) detection is a powerful method for spectrum sensing. However, a conventional MC detector is difficult to implement because of its high computational complexity. This paper considers reducing computational complexity by simplifying the test statistic of a conventional MC detector. On the basis of this simplification process, an improved MC detector is proposed. Compared with the conventional detector, the proposed detector has low-computational complexity and high-accuracy sensing performance. Subsequently, the sensing performance is further investigated for the cases of Rayleigh, Nakagami-m, Rician, and Rayleigh fading and lognormal shadowing channels. Furthermore, square-law combining (SLC) is introduced to improve the detection capability in fading and shadowing environments. The corresponding closed-form expressions of average detection probability are derived for each case by the moment generation function (MGF) and contour integral approaches. Finally, illustrative and analytical results show the efficiency and reliability of the proposed detector and the improvement in sensing performance by SLC in multipath fading and lognormal shadowing environments.

• Current Applied Physics
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• 제18권11호
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• pp.1190-1195
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• 2018

By employing soft X-ray magnetic circular dichroism (XMCD), soft X-ray absorption spectroscopy (XAS), and photoemission spectroscopy (PES), we have investigated the electronic structure of the candidate zero-moment half-metallic $Mn_3Ga$. We have studied the ball-milled and annealed $Mn_3Ga$ powder samples that exhibit nearly zero magnetization. Mn 2p XAS revealed that Mn ions in $Mn_3Ga$ are nearly divalent for both of the Mn ions having the locally octahedral symmetry and those having the locally tetrahedral symmetry. The measured Mn 2p XMCD spectrum of $Mn_3Ga$ is very similar to that of ferrimagnetic $MnFe_2O_4$ having divalent Mn ions. The sum-rule analysis of the Mn 2p XMCD spectrum shows that both the spin and orbital magnetic moments of Mn ions in $Mn_3Ga$ are negligibly small, in agreement with the nearly compensated-ferrimagnetic ground state of $Mn_3Ga$. The valence-band PES spectrum of $Mn_3Ga$ agrees well with the calculated density of states, supporting the half-metallic electronic structure of $Mn_3Ga$.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 1991년도 가을 학술발표회 논문집
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• pp.81-89
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• 1991

Recently increasing number of highrise buildings are aseismically designed by dynamic analysis method. To perform comparative study on the results of seismic design by dynamic analysis method, five-to thirty-story building models of ductile moment resisting frames and braced frames are considered. Base shears of these models using the spectrum of equivalent static method in the current Korean code and the ones of dynamic analysis method in the UBC-88 code are compared. Based on this study design spectra to be used in the dynamic analysis in Korea are proposed and the results are compared.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 1998년도 춘계학술대회 논문집
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• pp.245-250
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• 1998

This thesis is concerned with the development of useful engineering techniques to detect and analyze nonlinearities in mechanical systems. The methods developed are based on the concepts of higher order spectra, in particular the bispectrum and trispectrum, and the Volterra series. The study of higher order statistics has been dominated by work on the bispectrum. The bispectrum can be viewed as a decomposition of the third moment(skewness) of a signal over frequency and as such is blind to symmetric nonlinearities.

• 한국지진공학회논문집
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• 제12권2호
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• pp.69-80
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• 2008

본 연구에서는 중고층 건물과 같이 고차모드의 영향이 커지는 구조물의 지진에 대한 성능점을 간략하고 정확하게 구할 수 있는 개선된 능력스펙트럼법을 제안한다. 능력스펙트럼법은 주어진 지진의 응답스펙트럼과 다자유도 구조물을 변환한 등가 단자유도 시스템을 이용하여 지진으로 인하여 발생하는 지붕층의 최대 비탄성변위를 간략하게 구하는 방법이다. 제안된 방법에서는 구조물의 탄성 및 비탄성 동적해석을 수행하지 않고, 기존의 능력스펙트럼법에서 요구되는 정적푸쉬오버해석과 탄성변위를 이용하여 비탄성변위를 예측하는데, 기존 연구에서 개발한 $C_R$을 이용한다. 본 연구는 제안한 방법의 정확도를 평가하기 위해 LA 지역의 3, 9, 20층 철골모멘트저항골조를 선택한다. 이 건물들의 지진에 대한 각 층별 최대 층간변위비를 개발한 CSM으로 구하고, 이를 비선형 응답이력해석(NL-RHA)으로 구한 결과와 비교하였다. 사용한 지진은 재현주기 475년과 2475년의 위험수준에 대한 각각 20개의 지진집단들이다. 또한 본 연구에서는 ATC-40에 제시된 CSM 방법과 N2 방법으로 구한 각 건물의 최대 층간변위비도 비교한다. 개발된 CSM은 기존에 개발된 방법에 비하여 보다 정확한 최대 층간변위비를 예측하는 것으로 나타났다.

• 한국전자통신학회논문지
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• 제15권6호
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• pp.1037-1044
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• 2020

윈드프로파일러(RWP, radar wind profiler)는 기상 상태와 관계없이 시공간 분해능이 높은 바람장 자료를 제공하며 생산된 바람의 정확도나 품질에 대한 검증이 필수적이다. 기존 정확도 검증 방식은 레윈존데와의 동시 관측을 통해 윈드프로파일러에서 생성된 바람 벡터를 기준 자료로 활용하는 것이다. 본 연구에서는 평균 모멘트 자료로부터 스펙트럼과 원시 시계열 자료를 시뮬레이션하는 알고리즘을 통해 윈드프로파일러의 신호처리 알고리즘을 단계별로 검증하는 방안을 제시하고, LAP-3000의 원시 자료와의 비교를 통해 해당 알고리즘의 가능성을 확인하였다. 기상 신호의 밀도 함수를 모멘트값을 인자로 하는 왜곡된 정규 분포의 밀도 함수로 가정하여 생성하였고, 난수를 통해 시뮬레이션 스펙트럼을 생성하였다. 또한, 난수 위상과 역 이산푸리에 변환으로 간섭 평균된 시뮬레이션 원시 시계열 자료를 생성하고 최종적으로 디리클레 분포(Dirichlet distribution)를 통해 간섭 평균 전 단계의 원시 시계열 자료를 생성하였다.

• 한국지진공학회논문집
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• 제13권5호
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• pp.23-29
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• 2009

1996년 12월 13일 강원도 영월군 지역에서 국지규모(M$_L$) 4.5의 지진이 발생하였다. 진앙은 37.2545$^{\circ}$N, 128.7277$^{\circ}$E이며, 지체구조구상 옥천습곡대에 해당한다. 지진자료의 필터링 대역에 따라 파형역산을 수행하였는데, 0.02$\sim$0.2 Hz 필터링 대역을 적용할 경우 진원 깊이는 6 km, 지진모멘트는 1.3$\times$10$^{16}$ N$\cdot$m로 추정되었다. 이 지진모멘트는 모멘트규모(M$_W$) 4.7에 해당한다. 파형역산과 P파의 초동 극성 분석을 통한 영월 지진의 발진기구는 역단층 성분을 포함한 주향이동단층 특성을 보이며, 주응력 방향은 동북동-서남서 방향이다. 스펙트럼 분석을 통해 추정된 모멘트규모는 4.8이며, 이는 파형역산에 의해 추정된 모멘트규모와 비슷하다. 평균 응력강하는 14.3 MPa로 추정되었다.