• Title/Summary/Keyword: Solution behaviors

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Elution Behaviors of Stannous Ion by PSA on Chelating Resin (킬레이트 수지에서의 PSA에 의한 주석(Ⅱ)이온의 용리현상)

  • Cha, Ki-Won;Choi, Hyun-Cheol
    • Journal of the Korean Chemical Society
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    • v.39 no.5
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    • pp.379-383
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    • 1995
  • The elution behaviors of stannous ion by PSA(phenol sulfonic acid) as an eluent on chelating resin, Amberlite IRC-718 have been investigated. When 0.10 M stannous solution was adsorbed on the resin and eluted with various concentrations of PSA, the two peaks of stannous ion were appeared in the elution curve. These two peak areas were changed according to the PSA concentration. Using these results, the stability constant of the complex formation between Sn2+ and PSA was calculated. This value is 2.0 ${\times}$ 10-1.

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A Review of Corrosion and Hydrogen Diffusion Behaviors of High Strength Pipe Steel in Sour Environment

  • Kim, Sung Jin;Kim, Kyoo Young
    • Journal of Welding and Joining
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    • v.32 no.5
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    • pp.13-20
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    • 2014
  • A brief overview is given of the corrosion and hydrogen diffusion behaviors of high strength pipe steel in sour environment. Firstly, hydrogen adsorption and diffusion mechanism of the pipe steel is introduced. Secondly, the effect of iron sulfide film precipitated as a result of the corrosion reaction on the steel surface on hydrogen reduction reaction and subsequent hydrogen permeation through the steel is discussed. Moreover, the hydrogen diffusion behavior of the pipe steel under tensile stress in both elastic and plastic ranges is reviewed based on a number of experimental permeation data and theoretical models describing the hydrogen diffusion and trapping phenomena in the steel. It is hoped that this paper will result in significant academic contributions in the field of corrosion and hydrogen related problems of the pipe steel used in sour environment.

Rheological properties and thermal degradation behaviors of sonochemically treated polycarbonate/polysiloxanes blends

  • Choi, Mi-Kyung;Kim, Yu-Bin;Kim, Ji-Hye;Kim, Hyung-Su
    • Korea-Australia Rheology Journal
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    • v.20 no.4
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    • pp.245-251
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    • 2008
  • Two polysiloxanes having different chemical structures were blended with polycarbonate (PC) under ultrasonic irradiation in solution. The polysiloxanes used were poly(methylphenyl siloxane) and vinyl-terminated poly(dimethyl siloxane). It was of primary interest to investigate the effect of polysiloxane structure on the rheological properties of PC/polysiloxane blends. It was found that a small amount (1.5 phr) of polysiloxanes greatly altered the melt viscosities and elasticity of PC. In particular, incorporation of poly(methylphenylsiloxane) led to a notable increase in elasticity with greater shear sensitivity of PC. The observed rheological behaviors of PC/polysiloxane blends were partly explained in conjunction with the tendencies found in ultrasonic degradation of polysiloxanes. Thermal stability and morphology in sonicated blends of PC/polysiloxane blends were also discussed.

Stability of Slotted Aloha with Selfish Users under Delay Constraint

  • Chin, Chang-Ho;Kim, Jeong-Geun;Lee, Deok-Joo
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.5 no.3
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    • pp.542-559
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    • 2011
  • Most game-theoretic works of Aloha have emphasized investigating Nash equilibria according to the system state represented by the number of network users and their decisions. In contrast, we focus on the possible change of nodes' utility state represented by delay constraint and decreasing utility over time. These foregone changes of nodes' state are more likely to instigate selfish behaviors in networking environments. For such environment, in this paper, we propose a repeated Bayesian slotted Aloha game model to analyze the selfish behavior of impatient users. We prove the existence of Nash equilibrium mathematically and empirically. The proposed model enables any type of transmission probability sequence to achieve Nash equilibrium without degrading its optimal throughput. Those Nash equilibria can be used as a solution concept to thwart the selfish behaviors of nodes and ensure the system stability.

Electrochemical Behaviors of PAN/Ag-based Carbon Nanofibers by Electrospinning

  • Park, Soo-Jin;Im, Se-Hyuk
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.777-781
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    • 2008
  • In this work, silver nanoparticles-containing polyacrylonitrile (PAN) solutions in N,N-dimethylformamide (DMF) were electrospun to be webs consisting of nanofibers. The inputted voltage and PAN content in the solution were fixed at 15 kV and 10 wt.% in DMF with 10 cm of tip-to-collector distance (TCD). The PAN/Ag nanofiber webs were stabilized by oxidation at 250 ${^{\circ}C}$ for 2 h in air and carbonized at 1000 ${^{\circ}C}$ for 2 h in $N_2$. The resultant diameter distribution and morphologies of the nanofibers were evaluated by scanning electron microscope analysis. The electrochemical behaviors of the nanofiber webs were also observed by cyclic voltammetry tests. It was found that the presence of silver nanoparticles in carbon nanofiber webs led to the increase of specific capacitance and the decrease of fiber diameters.

Pervaporation Separation of Trace VOCs from Water Through PDMS Membranes

  • Rhim, Ji-Won;Kwon, Young-Mann
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.73-80
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    • 1999
  • The removal of trace chlorinated and aromatic hydrocarbons from water by a pervaporation technique has been carried out through poly (dimethylsiloxane) membrane which had been fabricated by the addition crosslinking reaction. This study dealt with the swelling and permeation behaviors of the PDMS membranes with dichloroethane trichloroethane and toluene aqueous solutions. The swelling ratio in the toluene aqueous solution was much higher than those in the chloroethane solutions at all of the operating temperatures and concentrations. The solubility parameter theory was introduced to interpret the affinity between permeates and a membrane material and in all cases this approach seemed to be proper. It was suggested that the existence of water clusters in the membrane due to the hydrophobic characteristics of the membrane made the size of the permeating water larger resulting in suppressing water permeation and increasing enrichment of the organic components. The permeation behaviors at different membrane thicknesses were indirectly interpreted in terms of the effect of concentration polarization.

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Study on the Polarographic Behaviors of Tl(I) in EDTA and NTA as Supporting Electrolytes (EDTA 및 NTA 支指電解質중 Thallium (I) 의 Polarography 에 關한 硏究)

  • Kim, Hwang-Am;Kim, Yong-Tai
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.61-63
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    • 1962
  • The polarographic behaviors of Tl(I) was investigated in EDTA and NTA as supporting electrolytes for determination of Tl(I). A base solution containing 0.005 % gelatine, 0.1 M EDTA, and 0.05 M NTA was used. The halfwave potential of Tl(I) determined is -0.495 V v.s. S.C.E. in 0.1 M EDTA at pH 4.1 and -0.520V v.s. S.C.E. in 0.05 M NTA at pH 6.3. In this paper, the effects of gelatine concentration and pH values was investigated. The half-wave potentials of common elements was determined and compared with the half-wave potential of Tl(I).

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Complex Dynamic Behaviors of an Impulsively Controlled Predator-prey System with Watt-type Functional Response

  • Baek, Hunki
    • Kyungpook Mathematical Journal
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    • v.56 no.3
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    • pp.831-844
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    • 2016
  • In this paper, we consider a discrete predator-prey system with Watt-type functional response and impulsive controls. First, we find sufficient conditions for stability of a prey-free positive periodic solution of the system by using the Floquet theory and then prove the boundedness of the system. In addition, a condition for the permanence of the system is also obtained. Finally, we illustrate some numerical examples to substantiate our theoretical results, and display bifurcation diagrams and trajectories of some solutions of the system via numerical simulations, which show that impulsive controls can give rise to various kinds of dynamic behaviors.

Nonlinear stability of smart nonlocal magneto-electro-thermo-elastic beams with geometric imperfection and piezoelectric phase effects

  • Faleh, Nadhim M.;Abboud, Izz Kadhum;Nori, Amer Fadhel
    • Smart Structures and Systems
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    • v.25 no.6
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    • pp.707-717
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    • 2020
  • In this paper, analysis of thermal post-buckling behaviors of sandwich nanobeams with two layers of multi-phase magneto-electro-thermo-elastic (METE) composites have been presented considering geometric imperfection effects. Multi-phase METE material is composed form piezoelectric and piezo-magnetic constituents for which the material properties can be controlled based on the percentages of the constituents. Nonlinear governing equations of sandwich nanobeam are derived based on nonlocal elasticity theory together with classic thin beam model and an analytical solution is provided. It will be shown that post-buckling behaviors of sandwich nanobeam in thermo-electro-magnetic field depend on the constituent's percentages. Buckling temperature of sandwich nanobeam is also affected by nonlocal scale factor, magnetic field intensity and electrical voltage.

Phase behaviors, lamellar structures, and physical properties of synthetic vitamin E ceramide (Tocomide) mixed with cholesterol and linoleic acid

  • Lee, Young-Jin;Kim, Do-Hoon;Park, Ho-Sik;Kang, Hyung-Seok;Kim, Joong-Soo;Kim, Han-Kon
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.357-368
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    • 2003
  • II-A isotherms and phase behaviors of 'tocomide', a newly synthesized 1,3-bis(N-(2-hydroxyethyl)-tocopherol succinylamino)-2-hydroxypropane, mixed with cholesterol and linoleic acid, was studied for its monolayer miscibility and a stable delivery formulation for antioxidant applications. The monolayer of tocomide and cholesterol was formed in a homogeneously mixed state at air-water interface. The ternary mixtures with linoleic acid showed various bulk structures, including a stable and transparent solution of thermodynamically stable lamellar phase. The lamellar structure was confirmed by the X-ray diffraction (XRD) patterns and polarized microscopy such that pure tocomide formed a liquid crystal at room temperature with a lamellar periodicity of 36.7 $\AA$(2$\theta$=2.41$^{\circ}$).

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