Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

Study on the Polarographic Behaviors of Tl(I) in EDTA and NTA as Supporting Electrolytes

EDTA 및 NTA 支指電解質중 Thallium (I) 의 Polarography 에 關한 硏究

  • Kim, Hwang-Am (Department of Chemistry, College of Liberal Arts and Science, Sung Kyun University) ;
  • Kim, Yong-Tai (Department of Chemistry, College of Liberal Arts and Science, Sung Kyun University)
  • 김황암 (成均館大學校 文理科大學 化學科) ;
  • 김영태 (成均館大學校 文理科大學 化學科)
  • Published : 19620200
Download PDF
⟨ Previous Next ⟩

Abstract

The polarographic behaviors of Tl(I) was investigated in EDTA and NTA as supporting electrolytes for determination of Tl(I). A base solution containing 0.005 % gelatine, 0.1 M EDTA, and 0.05 M NTA was used. The halfwave potential of Tl(I) determined is -0.495 V v.s. S.C.E. in 0.1 M EDTA at pH 4.1 and -0.520V v.s. S.C.E. in 0.05 M NTA at pH 6.3. In this paper, the effects of gelatine concentration and pH values was investigated. The half-wave potentials of common elements was determined and compared with the half-wave potential of Tl(I).

Keywords

References

  1. ボ一ラログラフ分析法 石橋雅義;藤永太一郞
  2. J.A.C.S. v.76 Gilbert W. Smith;Frederch Nelson
  3. Chem. Listy v.48 Antonin A. Vlcek
  4. J.A.C.S. v.72 H.A. Laitinen
  5. Chem. Listy v.51 J. Cihalik;J. simek;J. Ruzicka
  6. C.A. v.52
  7. Anal. Chim. Acta v.14 John W. Grenier;Louis Meites
  8. C.A. v.51
  9. Polarography I.M. Kolthoff James;J. Lingane
  10. Bull. Nagoya Inst. Technol. v.7 D. Tsurumatsu;K. Morinaga;N. Tsuyoshi
  11. C.A. v.50
  12. Izvest Akad Nauk kazakh, S.S.R., ser khim no.1 D.P. Shcherlov;I.I. Sagalovich
  13. C.A. v.51