• Title/Summary/Keyword: Solution Structure

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Preparation of highly hydrophobic PVDF hollow fiber composite membrane with lotus leaf-like surface and its desalination properties

  • Li, Hongbin;Zi, Xingchen;Shi, Wenying;Qin, Longwei;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.10 no.4
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    • pp.287-298
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    • 2019
  • Lotus leaf has a special dual micro and nano surface structure which gives its highly hydrophobic surface characteristics and so-called self cleaning effect. In order to endow PVDF hollow fiber membrane with this special structure and improve the hydrophobicity of membrane surface, PVDF hollow fiber composite membranes was obtained through the immersion coating of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) dilute solution on the outside surface of PVDF support membrane. The prepared PVDF composite membranes were used in the vacuum membrane distillation (VMD) for the desalination. The effects of PVDF-HFP dilute solution concentration in the dope solution and coating time on VMD separation performance was studied. Membranes were characterized by SEM, WCA measurement, porosity, and liquid entry pressure of water. VMD test was carried out using $35g{\cdot}L^{-1}$ NaCl aqueous solution as the feed solution at feed temperature of $30^{\circ}C$ and the permeate pressure of 31.3 kPa. The vapour flux reached a maximum when PVDF-HFP concentration in the dilute solution was 5 wt% and the coating time was kept in the range of 10-60 s. This was attributed to the well configuration of micro-nano rods which was similar with the dual micro-nano structure on the lotus leaf. Compared with the original PVDF membrane, the salt rejection can be well maintained which was greater than 99.99 % meanwhile permeation water conductivity was kept at a low value of $7-9{\mu}S{\cdot}cm^{-1}$ during the continuous testing for 360 h.

The Solution Structure of FADD Death Domain: Structural Basis of Death Domain Interactions of Fas and FADD

  • Jeong, Euj-Jun;SookHee, Bang;Kim, Key-Sun
    • Proceedings of the Korean Biophysical Society Conference
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    • 1999.06a
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    • pp.21-21
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    • 1999
  • A signal of Fas-mediated apoptosis is transferred through an adaptor protein FADD by interactions between death domains of Fas and FADD. To understand the signal transduction mechanism of Fas-mediated apoptosis, we solved the solution structure of a murine FADD death domain.(omitted)

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Structure and Hydrolysis Study of Inclusion Complex of Cyclodextrin and Aspirin (시클로덱스트린과 아스피린의 포접화합물의 구조와 가수분해에 관한 연구)

  • 최희숙;김경순
    • Journal of Life Science
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    • v.10 no.1
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    • pp.86-93
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    • 2000
  • Specific molecular recognition of cyclodextrin and aspirin was determined. A stable 1:1 inclusion complex was established in solution. The distinct structure of inclusion complex was elucidated by FT-IR, FAB-MS, UV, 1H NMR, and 13C NMR spectroscopy. Based on the 1H NMR data, a time-averaged conformation of $\alpha$-cyclodextrin exhibited significant catalytic activity toward the hydrolysis of aspirin in alkaline solution.

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Dissolution of Antheraea pernyi Silk Fiber and Structure of Regenerated Fibroin from Zinc Nitrate Solution (질산아연에 의한 작잠견피브로인의 용해와 특성)

  • 권해용;이광길;여주홍;박영환
    • Journal of Sericultural and Entomological Science
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    • v.45 no.2
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    • pp.121-125
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    • 2003
  • Dissolution of Antheraea pernyi silk fiber was carried out in a zinc nitrate 6 hydrate (Zn(NO$_3$)$_2$ㆍ6$H_2O$) solution with various dissolving conditions. The solubility was significantly dependent on the concentration of zinc nitrate, dissolving temperature and time. Regenerated A. pernyi silk fibroin powder was obtained through dialysis process to remove chaotropic salt. FTIR and X-ray diffractometer showed that the conformation of regenerated A. pernyi silk powder was sheet structure.

Manufacture of Ultra Fine CuO Powder from Waste Copper Chloride Solution by Spray Pyrolysis Process

  • Yu, Jae-Keun;Ahn, Zou-Sam;Sohn, Jin-Gun
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.165-170
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    • 2001
  • The main purpose of this study is to generate a fine copper oxide powder of high purity, with a compact structure and a uniform particle size by a spray pyrolysis process. The raw material is a waste copper chloride solution formed in the manufacturing process of Print Circuit Board (PCB). This study also examines the influences of various factors on the properties of the generated powder. These factors include the reaction temperature, the inflow speed of the raw material solution, the inflow speed of the air, the size of the nozzle tip, and the concentration of the raw material solution. It is discovered that, as the reaction temperature increases from 80$0^{\circ}C$ to 100$0^{\circ}C$ , the particle size of the generated powder increases accordingly, and that the structure of the powder becomes much more compact. When the reaction temperature is 100$0^{\circ}C$, the particle size of the generated powder increases as the concentration of copper in the raw material solution increases to 40g/l, decreases as the concentration increases up to 120g/l, and increases again as the concentration reaches 200g/1. In the case of a lower concentration of the raw material solution, the generated powder appears largely in the form of CuO. As the concentration increases, however, the powder appears largely in the form of CuCl. When the concentration of copper in the raw material solution is 120g/1, the particle size of the generated powder increases as the inflow speed of the raw material solution increases. When the concentration of copper in the raw material solution is 120g/1, there is no evident change in the particle size of the generated powder as the size of the nozzle tip and the air pressure increases. When the concentration is 40g/1, however, the particle size keeps increasing until the air pressure increases to 0.5kg/$\textrm{cm}^2$, but decreases remarkably as the air pressure exceeds 0.5kg/$\textrm{cm}^2$.

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New Hypothesis "Exhaustion of Diffusion-Contributable Vacancies in Core/Rim Structure"

  • Hayshi, Koji;Yanaba, Yutaka
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2002.11a
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    • pp.8-8
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    • 2002
  • TiC core/(Ti,Mo)C rim structure in TiC-$Mo_2C$-Ni base cermet which is generally prepared by sintering below 145$0^{\circ}C$ had been believed to be generated by the solid diffusion of Mo atoms 1 into TiC grains (D. Moskowitz and M.Humenik, 1r.:1966). Afterward, it was clarified that the c core/rim structure is generated by solution/re-precipitation mechanism : (1) $Mo_2C$ grains and s small TiC grains dissolve into the Ni liquid, (2) the dissolved Mo, Ti and C atoms migrate to the s surface of TiC coarse grains, (3) the Mo, Ti and C precipitate on the surface of TiC coarse g grains and form (Ti,Mo)C solid solution rim, and (4) the Ostwald ripening (grain growth by s solution/re-precipitation mechanism) of TiC-core/(Ti,Mo)-rim grains continues, and thus the w width of (Ti,Mo)C rim (at the same time, the grain size) increases with sintering time, etc. ( (H.Suzuki, K.Hayashi and O.Terada: 1973). The TiC-core was found not to disappear even by s sintering at 190$0^{\circ}C$ (ibid.: 1974) Recently, FeSi core/$Fe_2Si_5$-rim structure in Fe-66.7at%Si thermoelectric aIloy was found to also h hardly shrink and disappear by long heating at an appropriate temperature (1999: M.Tajima and K K.hayashD. Then, the authors considered its cause, and clarified experimentaIly that the disappearance of FeSi-core/$Fe_2Ski_5$-rim structure could be attributed to the exhaustion of diffusion-contributable vacancies in core/rim structure (N.Taniguchi and K.Hayashi:2001). At p present, the authors and my coworker are investigating whether the non-disappearance of TiC c core can be explained also from the new hypothesis "Exhaustion of diffusion-contributable v vacancies in corelrim structure".ure".uot;.

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Tertiary Structure of PreSl(21-47) of Hepatitis B Virus Studied by NMR Spectroscopy

  • Kyeunghee Yu;Cho, Eun-Wie;Shin, Song-Yub;Kim, Kol-Lyong;Kim, Yangmee
    • Journal of the Korean Magnetic Resonance Society
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    • v.4 no.1
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    • pp.41-49
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    • 2000
  • To design more efficient peptide antagonist against the HBV, preSl(21-47) which carries the HBV receptor binding site for hepatocytes was synthesized and the solution structure of preSl(21-47) was investigated using CD spectroscopy and NMR spectroscopy in membrane-mimicking environments. According to CD spectra, preSl(21-47) has a random structure in aqueous solution, while conformational change was induced by addition of TFE and SDS micelle. Tertiary structures as determined by NMR spectroscopy shows that preSl(21-47) has a very flexible structure even in SDS micelle.

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Vibration Analysis of Water-loaded Cylindrical Array Structures (원통형 배열 구조물의 접수진동 해석)

  • Shin, Chang-Joo;Hong, Chin-Suk;Jeong, Weui-Bong;Seo, Hee-Seon
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.1
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    • pp.175-182
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    • 2009
  • This paper summarizes a solution procedure for a large cylindrical structure mounted underneath a ship as a sonar. Vibration analysis of the water loaded structure is required to enhance the structural reliability as well as acoustic performance of the sonar. It is, however, often very difficult to solve such structures since they have many DOFs, considering the frequency of interest and the water-loading. The mode mapping method is proposed and verified to take into account the water-loading with the minimum DOF for the analysis. The cyclic symmetric method is then reviewed to show how the eigen properties of the full model can be obtained from the representative segment model. The solution procedure is finally proposed and applied successfully for a simplified water-loaded cylindrical array structure.

Construction Mechanism of Reticular Structure of Plant Fiber

  • Xie, Yongqun;Tong, Queju;Chen, Yan
    • Journal of the Korea Furniture Society
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    • v.19 no.2
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    • pp.106-110
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    • 2008
  • This paper investigated and validated the mechanisms and principles for constructing reticular structure of plant fiber through frothing solution approach. After process, plant fibers became low-density reticular-structured block with all properties meeting Chinese standards for cushion packing materials. The bonds between fibers acted as knots in a truss and were strong enough to keep space occupied by bubbles in the frothing solution from shrinking in the subsequent draining process. The formation of the reticular structure depends mainly on the pressure difference between inside and outside bubble, the effect of surface adsorbent force on bubble film, and hydrogen bond among fiber hydroxide.

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Vibration Analysis of Waterloaded Cylindrical Aarray Structures (주기대칭법을 이용한 원통형 배열 구조물의 접수진동 해석)

  • Shin, Chang-Joo;Hong, Chin-Suk;Jeong, Weui-Bong;Seo, Hee-Seon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.1054-1059
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    • 2007
  • This paper summarized a solution procedure for a large cylindrical structure mounted underneath a ship as a sonar. Vibration analysis of the water loaded structure is required to enhance the structural reliability as well as acoustic performance of the sonar. It is, however, often very difficult to solve such structures since they have many DOFs, considering the frequency of interest and the waterloading. The cyclic symmetric method is firstly reviewed to show how the eigen properties of the full model can be obtained from the representative segment model. The mode mapping method is then proposed and verified to take into account the waterloading with the minimum DOF for the analysis. The solution procedure is finally proposed and applied for a waterloaded cylindrical array structure.

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