• 멤브레인
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• 제28권3호
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• pp.157-168
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• 2018

우리는 정삼투 공정의 유도용질로서 잠재적인 활용 가능성을 확인하기 위해 식물화학물질인 tannic acid (TA)에 알칼리 염 처리한 alkali tannate 염 중 하나인 potassium tannate (TA-K)를 평가하였다. TA-K의 정삼투 특성과 회수 특성은 체계적으로 조사되었다. 정삼투 공정을 active layer facing feed solution (AL-FS) 방식으로 적용했을 때, TA-K 유도용액의 투수량은 TA 유도용액의 투수량 보다 훨씬 많은 반면, TA 유도용액의 투수량이 거의 확인되지 않았다. 100 mM 저농도에서의 TA-K 유도용액의 삼투압(1,135 mOsmol/kg)은 NaCl 수용액의 삼투압(173 mOsmol/kg)의 약 6.5배로 확인되었다. 100 mM 농도의 TA-K의 투수량과 specific salt flux (6.14 LMH, 1.26 g/L)는 동일한 농도의 NaCl 유도용액의 투수량과 specific salt flux (2.46 LMH, 2.63 g/L)의 약 2.5배 및 0.5배로 각각 확인되었다. TA-K를 재사용하기 위해, 금속 이온 침전법을 이용하여 TA-K유도용질을 침전시킨 후, membrane filtration을 이용하여 유도용질을 회수하였다. 이 연구는 식물화학물질을 정삼투 공정의 유도용질로서의 적용 가능성을 보여준다.

• Korean Chemical Engineering Research
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• 제56권5호
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• pp.679-686
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• 2018

폴리아미드 역삼투막을 이용하여 염화나트륨, 아세트산나트륨, 구연산나트륨 용액의 역삼투 농축실험을 행하고, 농도분극 현상을 압력, 용질의 종류, 농축액의 초기 농도를 변수로 연구하였다. 투과 플럭스에 대한 압력과 농도의 영향을 살펴보면, 공정 압력이 증가할수록 그리고 원액의 초기 농도가 작을수록 투과플럭스가 증가하였다. 농도분극이 일어나면 막 표면의 농도가 증가하여 투과플럭스가 감소한다. 농도분극은 농축이 진행됨에 따라 투과 플럭스의 감소로 이어지고 농도분극 층에서 용질 역확산을 통하여 점차 감소하였다. 이온의 크기, 분자량, 전하량이 증가함에 따라 막표면에서 정전기적 반발력이 커서 농도분극의 이론적 해석과 실험값의 차이가 컸다.

• Membrane and Water Treatment
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• 제8권6호
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• pp.613-623
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• 2017

We report the novel thin film composite RO membrane modified by graphene oxide. The thin film composite RO membrane was exposed to 2000 mg/l sodium hypochloride; thereafter it was subjected to different graphene oxide concentration ranging from 50 mg/l to 1000 mg/l in water. The resultant membrane was crosslinked with 5000 mg/l N-hydroxysuccinimide. The performance of different membranes were analysed by solute rejection and water-flux measurement. It was found that 100 mg/l graphene oxide exposure followed by 5000 mg/l N-hydroxysuccinimide treatment resulted in the membrane with the highest solute rejection of 97.78% and water-flux of 4.64 Liter per sqm per hour per bar g. The membranes were characterized by contact angle for hydrophilicity, scanning electron micrographs for surface morphology, energy dispersive X-Ray for chemical composition of the surface, Atomic force microscope for surface roughness, ATR-FTIR for chemical structure identification. It was found that the graphene oxide modified membrane increases the salt rejection performance after exposure to high-fouling water containing albumin. Highly hydrophilic, antifouling surface formation with the nanomaterial led to the improved membrane performance. Moreover, the protocol of incorporating nanomaterial by this post-treatment is simple and can be applied to any RO membrane after it is manufactured.

• 공업화학
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• 제10권4호
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• pp.563-567
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• 1999

용질배제율이 우수한 나권형 FT-30 폴리아미드 복합막을 상용하여 cephalosporin C를 농축하기 역삼투 농축실험을 하였다. $4{\sim}20kg/cm^2$의 압력과 100~1000 mg/L의 농도, 그리고 2.8과 5.6 L/min의 유속을 갖는 실험 조건하에서 cephalosporin C 수용액의 수투과율과 용질의 배제율 및 물질전달 계수를 구하였다. Cephalosporin C를 분리하는데 있어서 압력이 증가함에 따라 투과 플럭스가 증가하는 것으로 나타났다. 이 결과는 Kedem-Katchalsky 모델에서 예측한 것과 일치하였다. 그리고 배제율은 1에 가까웠다. 또한 공급액의 농도가 증가할수록 cephalosporin C의 배제율은 낮아지는 것으로 나타났다. 배제율은 고농도보다는 저온도에서 높게 나타났으나 그 감소 정도는 작았다.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2001년도 추계 학술대회논문집
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• pp.112-117
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• 2001

A numerical investigation is made of unsteady double-diffusive convection of a Boussinesq fluid in a rectangular cavity subject to time-periodic thermal excitations. The fluid is initially stratified between the top endwall of low solute concentration and the bottom endwall of high solute concentration. A time-dependent heat flux varying in a square wave fashion, is applied on one sidewall to induce buoyant convection. The influences of the imposed periodicity on double-diffusive convection are scrutinized. A special concern is on the occurrence of resonance that the fluctuations of flow and attendant heat and mass transfers are mostly amplified at certain eigenmodes of the fluid system. Numerical solutions are analyzed to illustrate the characteristic features of resonant convection.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제13권2호
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• pp.123-140
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• 2009

The effect of a solute concentration difference on the osmotic transport of water through the semi-permeable membrane of a simple cell model is investigated. So far, most studies on osmotic phenomena are described by simple diffusion-type equations ignoring all fluid motion or described by Stokes flow. In our work, as the governing equations, we consider the coupled full Navier-Stokes equations which describe the fluid motion and the full transport equation that takes into account of convection and diffusion effects. A two dimensional finite difference model has been developed to simulate the velocity field, concentration field, and semi-permeable membrane movement. It is shown that the cell swells to regions of lower solute concentration due to the uneven water flux through the semi-permeable membrane. The simulation is applied on a red blood cell geometry and the relevant results are presented.

• Macromolecular Research
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• 제10권4호
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• pp.209-214
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• 2002

Miscibility of polysulfone (PSf) with various hydrophilic copolymers was explored. Among these blends, PSf gives homogeneous mixtures with poly(1-vinylpyrrolidone-co-styrene) copolymers [P(VP-S)] when these copolymers contained VP from 68 to 88 wt%. Microporous membranes for the ultrafiltration process were prepared from PSf blends with P(VP-S) copolymers. The membranes prepared from the PSf/(VP-S) blends exhibited higher water flux than the membranes prepared from PSf irrespective of the VP content. The solute rejection examined with the membranes fabricated from the miscible blends was similar to that of PSf membrane. However, the solute rejection examined with the membranes fabricated from the immiscible blends was lower than that of PSf membranes.

• 한국전산유체공학회지
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• 제7권1호
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• pp.36-43
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• 2002

A numerical investigation is made of unsteady double-diffusive convection of a Boussinesq fluid in a rectangular cavity subject to time-periodic thermal excitations. The fluid is initially stratified between the top endwall of low solute concentration and the bottom endwall of high solute concentration. A time-dependent heat flux varying in a square wave fashion, is applied on one sidewall to induce buoyant convection. The influences of the imposed periodicity on double-diffusive convection are examined. A special concern is on the occurrence of resonance that the fluctuations of flow and attendant heat and mass transfers are mostly amplified at certain eigenmodes of the fluid system. Numerical solutions illustrate that resonant convection results in a conspicuous enhancement of time-mean mass transfer rate.

• Membrane and Water Treatment
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• 제9권6호
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• pp.385-392
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• 2018

Poly vinyl chloride (PVC) was chemically modified, and used for ultrafiltration to analyze the performance. Non-solvent induced phase separation (NIPS) method was used to prepare membranes. The neat PVC membrane was casted and used as a control membrane. Modified membrane was prepared by reacting PVC with ethanolamine (EA) in the casting solution (labeled as CM-PVC). Pure water permeability (PWP) was evaluated by measuring pure water flux. Humic acid was used as model foulant solute to analyze flux and rejection ability of membranes. Flux and rejection data of neat and modified membranes were compared to prove the improvement in the filtration performance. The experimental results showed that for PVC and CM-PVC, PWP was calculated to be ~64 and ${\sim}143L/m^2{\cdot}h$, respectively, and the rejection of humic acid was found to be 98% and 100%, respectively. TGA was carried out to analyze the effect of chemical modification on the thermal stability of polymer. FT-IR analysis was another characterization technique used for the comparative study.

• 전력전자학회논문지
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• 제5권5호
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• pp.427-434
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• 2000

본 논문은 유도전동기의 직접벡터 제어 시스템에서 전동기가 기동 시 토크 충격없이 부드럽게 기동할 수 있는 기동기법을 제시한다. 정지모드에서는 고정자 전류만으로 고정자자속을 계산하는 방식을 사용하며, 기동 후 직접 벡터제어 모드에서는 프로그램어블 3-단계 저역필터로 고정자자속을 계산한다. 정지모드에서 직접벡터제어 모드로 변환 시 3-단계 저역필터의 시간지연으로 고정자 자속이 급격히 감소되어 토크 역시 갑자기 감소된다. 본 논문에서는 전동기가 기동 시 토크 충격을 방지하기 위한 고정자 자속의 피이드포워드 제어 기법을 제시하고, 시뮬레이션 및 실험을 통하여 이 기법의 타당성을 확인한다.