• Korean Journal of Materials Research
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• v.31 no.7
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• pp.409-419
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• 2021

The effect of solidification rate on micro-segregation in investment casting of IN738LC superalloy was studied. In Ni-based superalloys, the micro-segregation of solute atoms is formed due to limited diffusion during cast and solidification. The microstructure of cast Ni-based superalloys is largely divided into dendrite core of initial solidification and interdendrite of final solidification. In particular, mosaic shaped eutectic γ/γ' and carbides are formed in the interdendrite of the final solidification region in some cases. The micro-segregation phenomena formed in regions of dendrite core and interdendrite including eutectic γ/γ' and carbides were analyzed using OM, SEM/EDS and micro Vickers hardness. As a result of analysis, the lack of (Cr, W) and the accumulation of Ti were measured in the eutectic γ/γ', and the accumulation of (Cr, Mo) and the lack of Ti were measured in the interdendrite between dendrite and eutectic. Carbides formed in interdendritic region were composed of (Ti, W, Mo, C). The segregation applied to each microstructure is mainly due to the formation of γ' with Ni₃(Al,Ti) composition. The Ni accumulation accompanied by Cr depletion, and the Ti accumulated in the eutectic region as a γ' forming elements. The Mo tends to diffuse out from the dendrite core to the interdendrite, and the W diffuse out from the interdendrite to the dendrite core. Therefore, the accumulation of Mo in the interdendrite and the deficiency of W occur in the eutectic region located in the interdendrite. Heat treatment makes the degree of the micro-segregation decrease due to the diffusion during solid solution. This study could be applied to the heat treatment technology for the micro-segregation control in cast Ni-based superalloys.

• Journal of the Korean Society for Precision Engineering
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• v.33 no.6
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• pp.469-475
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• 2016

In this work, casting processes, such as filling and solidification, were simulated in order to accurately predict volume shrinkage defects in large-sized sand gravity casting. Turbulent flow of melted materials and a difference of solidification speed can cause volume shrinkage defects. In order to solve this problem and to understand the phenomenon, a porous filter application was studied. Two different porosities of 10 and 20 p.p.i filters were introduced into the gating system, and in view of the results so far achieved, the defect was dramatically reduced by 22%, compared to that without the use of the filter.

• Journal of Korea Foundry Society
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• v.22 no.4
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• pp.192-199
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• 2002

Dimensional defects of castings are mainly due to the stresses and strains caused by a nonuniform temperature distribution and phase transformation during solidification and cooling, and by mechanical constraint between the mold and casting. It is, however, nearly impossible to trace movements of the casting and mold during solidification and cooling by experimental measurements for castings with complex shape. Two and three dimensional deformation analyses of the casting and the mold were performed using commercial finite element code, MARC. It was possible to calculate deformation and temperature distribution in the casting and mold simultaneously. Cooling curves of the casting obtained by calculation were close to that measured in the field since it was possible to treat latent heat evolution of the casting which could be divided into two parts, primary and eutectic parts. Mold bent inward just after pouring due to the temperature gradient across the mold thickness, and mold returned to its previous position with time. Plastic deformation occurred at the part of the casting where solidification was slow.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.1
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• pp.189-205
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• 1996

The twin-roll type strip continuous casting process(or direct rolling process) of steel materials is characterized by two rotating water cooled rolls receiving a steady supply of molten metal which solidifies onto the rolls. A solidification analysis of molten metal considering phase transformation and thermofluid is performed using finite diffefence method with curvilinear coordinate to reduce computing time and molten region analysis with arbitrary shape. An enthalpy-specific heat method is used to determine the temperatures inthe roll and the steel. The temperature distribution of cooling roll is calculated using two dimensional finite element method, because of complex roll shape due to cooling hole in rolls and improvemnt accuracy of calculation result. The energy equaiton of cooling roll is solved simultanuously with the conservation equaiton of molten metal in order to consider heat transfer through the cooling roll. The calculated roll temperature is compared to experimental results and the heat transfer coefficient between cooling roll surface and rolling material(steel) is also determined from comparison of measured roll temperature and calculated temperature.

• Journal of Korean Society on Water Environment
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• v.25 no.3
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• pp.404-410
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• 2009

In this study, research for physical and chemical characteristics were conducted through analysis of sediments, grading and heavy metals (e.g., Mn, Cu, Cd, Zn and Pb ) in sewers which are classified by drainage types. After that, cement solidification and yellow soil calcinations made heavy metals stabilized and then, ways of recycling it were examined. The grain size distribution of all sediments was relative graded. When evaluating heavy metal pollution through index of geoaccumulation (Igeo), Cu showed moderately pollution or strong pollution in forest and street site and Zn was assessed by moderately pollution in military, residential, and street site. Analysis of Pearson Correlation coefficient of heavy metal indicated that all items in street site have tight relationship respectively. Especially, Cd-Zn, Cu-Pb, Cu-Mn, and Pb-Mn have relationship at 99% confidence intervals in statistical analysis. Recycling it with cement solidification was satisfied with compressive strength standard under 55% deposit contents and Zn, Pb, Mn were stabilized effectively. If time and temperature plasticity and compressive strength would be standard, it is revealed that yellow soil calcinations is valuable aggregate when it has 50-60 Wt% contents. When considering economic feasibility and stabilization of heavy metals, cement solidification would be more appropriate than yellow soil calcinations as solution to recycling.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.4
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• pp.303-310
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• 2000

This study is conducted in order to find more improved solidifying effects than the former converter slag solidification technology. The converter slag is used as a solidifying agent, and the quick lime and the gypsum are used as solidifying aids. Several tests are performed for the purpose of investigating the solidifying effects and the applicability of the solidified sludge as a daily or intermediate landfill cover. The unconfined uniaxial compressive strength, pH and leaching of heavy metal are investigated. In the case of using both quick lime and gypsum as solidifying aids, the compressive strength of specimen has significantly increased that of specimen which used quick lime only. The compressive strength of each specimen cured for 7 days which is mixed with quick lime and gypsum as mixing ratios 7:1, 5:1 and 3:1 are $0.59kg/cm^2$, $1.18kg/cm^2$, and $1.25kg/cm^2$, respectively. The results of all the leaching tests of specimen cured for 7 days show that the concentrations of leachate heavy metals(Cu, Pb, Cd and $Cr^{6+}$) are lower than the Korea toxic waste criteria. The microstructure analysis by SEM shows that needlelike crystals appear as the solidification proceed. The analysis of these crystals by EDS confirms that these main components are Ca. Si etc. Also, XRD analysis shows that the main solidification products are CSH and Ettringite; in addition, $Ca(OH)_2$ CAH are observed. When the added gypsum is used as a solidifying aid, more improved solidifying effects are obtained and the solidified sludge may be appropriately used as a daily or intermediate landfill cover.

• Journal of computational fluids engineering
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• v.6 no.1
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• pp.1-13
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• 2001

The natural convection heat transfer and solidification in a stratified pool are studied. The flow and heat transfer characteristics in a heat generating pool are compared between single-layered and double-layered pools. And local Nusselt number distributions on outer walls are obtained to consider thermal loads on a vessel wall. The cooling and solidification of Al₂O₃/Fe melt in a hemispherical vessel are simulated to study the mechanism of heat transfer and temperature distribution. A unstructured mesh is chosen for this study because of the non-orthogonality originated from the boundaries of double-layered pool. Interface between the layers is modeled to be fixed. With this assumption mass flux across the interface is neglected, but shear force and heat flux are considered by boundary conditions. The colocated cell-centered finite volume method is used with the Rhie-Chow interpolation to compute cell face velocity. To prevent non-physical solutions near walls in case body force is large the wall pressure is extrapolated by the way to include body force. The numerical solutions calculated by current method show that averaged downward heat flux of the double-layered pool increases compared to single-layered pool and maximum temperature occurs right below the interface of the layers.

• Journal of Mechanical Science and Technology
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• v.19 no.9
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• pp.1773-1780
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• 2005

The process of mould design in the foundry industry has been based on the intuition and experience of foundry engineers and designers. To bring the industry to a more scientific basis the design process should be integrated with scientific analysis such as heat transfer. The production by foundry techniques is influenced by the geometry configuration, which affects the solidification conditions and subsequent cooling. Numerical simulation and/or experiments make possible the selection of adequate materials, reducing cycle times and minimizing production costs. The main propose of this work is to study the heat transfer phenomena in the mould considering the phase change of the cast-part. Due to complex geometry of the mould, a block unstructured grid and a generalized curvilinear formulation engaged with the finite volume method is described and applied. Two types of boundary conditions, diffusive and Newtonian, are used and compared. The developed numerical code is tested in real case and the main results are compared with experimental data. The results showed that the solidification time is about 6 seconds for diffusive boundary conditions and 14.8 seconds for Newtonian boundary conditions. The use of the block unstructured grid in combination with a generalized curvilinear formulation works well with the finite volume method and allows the development of more efficient algorithms with better capacity to describe the part contours through a lesser number of elements.

• Coupled systems mechanics
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• v.5 no.4
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• pp.341-353
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• 2016

Manufactures of multi-crystalline silicon ingots by means of the directional solidification system (DSS) is important to the solar photovoltaic (PV) cell industry. The quality of the ingots, including the grain size and morphology, is highly related to the shape of the crystal-melt interface during the crystal growth process. We performed numerical simulations to analyze the thermo-fluid field and the shape of the crystal-melt interface both for steady conditions and transient processes. The steady simulations are first validated and then applied to improve the hot zone design in the furnace. The numerical results reveal that, an additional guiding plate weakens the strength of vortex and improves the desired profile of the crystal-melt interface. Based on the steady solutions at an early stage, detailed transient processes of crystal growth can be simulated. Accuracy of the results is supported by comparing the evolutions of crystal heights with the experimental measurements. The excellent agreements demonstrate the applicability of the present numerical methods in simulating a practical and complex system of directional solidification system.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.7 s.238
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• pp.814-819
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• 2005

The phase change heat transfer has been applied to the processes of machines as well as of manufacturing. The cycle in a heat exchanger includes the phase change phenomena of coolant for air conditioning, the solidification in casting process makes use of the characteristics of phase change of metal, and the welding also proceeds with melting and solidification. To predict the phase change processes, the experimental and numerical approaches are available. In the case of numerical analysis, the Enthalpy method is most widely applied to the phase change problem, comparing to the other numerical methods, i.e. the Equivalent Specific Heat method and the Temperature Recovery method. It's because that the Enthalpy method is accurate and straightforward. The Enthalpy method does not include any correction step while the correction of final temperature field is inevitable in the Equivalent Specific Heat method and the Temperature Recovery method. When the temperature field is to be used in the calculation, however, there must be converting process from enthalpy to temperature in the calculation scheme of Enthalpy method. In this study, an improved method for the Equivalent Specific Heat method is introduced whose method dose not include the correction steps and takes temperature as an independent variable so that the converting between enthalpy and temperature does not need any more. The improved method is applied to the solidification process of pure metal to see the differences of conventional and improved methods.