• Title/Summary/Keyword: Size selectivity

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Properties Analysis of Wavelength Selective Filter and Implementation of Demultiplexer using Multiple Writing in Photorefractive Crystal (광굴절결정에서 파장 선택 필터의 특성 분석 및 다중 기록을 통한 역다중화기 구현)

  • Lee, Kwon-Yeon;An, Jun-Won;Kim, Nam
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.6
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    • pp.79-86
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    • 1999
  • We propose a new photorefractive demultiplexer(DMUX) for WDM communicaytion system using a wavelength selectivity and demultiplexing properties of a volume holographic grating filters formed in $LinbO_3$ crystal doped with 0.015wt.% Fe. The wavelength selectivity properties of the filter are analyzed and experimentally investigated as a function of the following parameters : the crossing angle of the two writing beams, the reading-beam angle and writing-beam size. In addition, applying these wavelength selectivity properties and the multiplexing technique for recording multiple-exposure filters with equal diffraction efficiency, some preliminary experimental results are presented for use as DMUX.

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Role of gas flow rate during etching of hard-mask layer to extreme ultra-violet resist in dual-frequency capacitively coupled plasmas

  • Gwon, Bong-Su;Lee, Jeong-Hun;Lee, Nae-Eung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.132-132
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    • 2010
  • In the nano-scale Si processing, patterning processes based on multilevel resist structures becoming more critical due to continuously decreasing resist thickness and feature size. In particular, highly selective etching of the first dielectric layer with resist patterns are great importance. In this work, process window for the infinitely high etch selectivity of silicon oxynitride (SiON) layers and silicon nitride (Si3N4) with EUV resist was investigated during etching of SiON/EUV resist and Si3N4/EUV resist in a CH2F2/N2/Ar dual-frequency superimposed capacitive coupled plasma (DFS-CCP) by varying the process parameters, such as the CH2F2 and N2 flow ratio and low-frequency source power (PLF). It was found that the CH2F2/N2 flow ratio was found to play a critical role in determining the process window for ultra high etch selectivity, due to the differences in change of the degree of polymerization on SiON, Si3N4, and EUV resist. Control of N2 flow ratio gave the possibility of obtaining the ultra high etch selectivity by keeping the steady-state hydrofluorocarbon layer thickness thin on the SiON and Si3N4 surface due to effective formation of HCN etch by-products and, in turn, in continuous SiON and Si3N4 etching, while the hydrofluorocarbon layer is deposited on the EUV resist surface.

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The difference of selectivity of gill net between least square method with polynomials in Kitahara's and maximum likelihood analysis (자망 선택성에서 다항식을 사용한 경우의 Kitahara에 의한 최소제곱법과 최우법의 차이)

  • Park, Hae-Hoon;Millar, Russell B.;Bae, Bong-Seong;An, Heui-Chun;Hwang, Seon-Jae
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.46 no.3
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    • pp.223-231
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    • 2010
  • This paper showed the difference between the selectivity of gill net by least square method with polynomials in Kitahara's and that by maximum likelihood analysis for Japanese sandfish and Korean flounder. Catch experiments for Japanese sandfish using commercial vessels off the eastern coast of Korea were conducted with six different mesh sizes between October and December 2007 and those for Korean flounder with five different mesh sizes between 2008 and 2009. The mesh size of 50% probability of catch corresponding to biological maturity length of fish was not different between that by least square method and that by maximum likelihood analysis for Japanese sandfish, however, a little different for Korean flounder, that is, those mesh sizes of 50% probability of catch for biological maturity length of Korean flounder were 10.6cm and 10.1cm by least square method and maximum likelihood analysis, respectively.

Mesh Selectivity of Beam Trawl for Shrimps (새우조망의 망목선택성)

  • Oh, Taek-Yun;Cho, Young-Bok;Park, Gwang-Jei;Jeong, Sun-Beom;Kim, Min-Seok;Kim, Hyeong-Seok;Lee, Ju-Hee
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.40 no.1
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    • pp.86-94
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    • 2004
  • This study was conducted to mesh selectivity of Beam trawl for shrimps fishing experiment in the coastal waters around Geomundo, South sea of Korea, during from Oct. to Nov. 2002. The selectivity parameters of big head shrimp (Solenocera melantho) have been studied on the covered con-end method. with mesh of 8, 38, 51 and 61 mm. Selection curves and selection parameters were calculated by using a logistic function S=1/(1+exp-(aCL+b)). The mesh selection master curves were estimated by S=1/(1+exp$^{({\alpha}(CL/M)+{\beta}}$), and the optimum mesh size were calculated with (L/M)50 of master curve. Optimum mesh size and selectivity master curves for the southern rough shrimp (Yrachysalambria curvirostris) and smoothshell shrimp (Parapenaeopsis tenella) optimum mesh size and selectivity master curves were estimated by big head shrimp master curves. The results obtained are summarized as follows : Selection parameters '${\alpha}$' and '${\beta}$' of the master curve for big head shrimp were 8.84 and -5.89, and The selection factor of the master curve (L/M)$_{50}$ was 0.67. The optimum mesh size of minimum length for sexual maturity for big head shrimp was 30.7 mm. Estimated (L/M)$_{50}$ for southern rough shrimp and smoothshell shrimp by using the master curve of big head shrimp was 0.73 and the optimum mesh sizes were 25.5 mm for southern rough shrimp and 16.9 mm for smoothshell shrimp, respectively.

Nanoporous Membrane with Ultrahigh Selectivity and Flux Suitable for Filtration of Viruses

  • Yang, Seung-Yun;Ryu In-Cheol;Jang, Sung-Key;Kim, Jin-Kon;Russell Thomas P.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.313-313
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    • 2006
  • In this study, we describe a new double layered nanoporous membrane suitable for virus filtration. One layer is an 80 nm thick film having cylindrical pores with diameters of 15 nm and a narrow pore size distribution. This layer is prepared by using a thin film of the mixture of a block copolymer and a homopolymer, and mainly acts to separate viruses. The support layer (${\sim}150\;microns\;thick$) is a conventional micro-filtration membrane with a broad pore size distribution. This asymmetric membrane showed very high selectivity and flux for the separation of human rhinovirus type 14 (HRV 14) which has a diameter of ${\sim}30\;nm$ and is a major pathogen of the common cold in humans.

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Gas Separation of Pyrolyzed Polymeric Membranes: Effect of Polymer Precursor and Pyrolysis Conditions

  • Jung, Chul-Ho;Kim, Gun-Wook;Han, Sang-Hoon;Lee, Young-Moo
    • Macromolecular Research
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    • v.15 no.6
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    • pp.565-574
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    • 2007
  • In this study, five representative, commercially available polymers, Ultem 1000 polyetherimide, Kapton polyimide, phenolic resin, polyacrylonitrile and cellulose acetate, were used to prepare pyrolyzed polymer membranes coated on a porous {\alpha}-alumina$ tube via inert pyrolysis for gas separation. Pyrolysis conditions (i.e., final temperature and thermal dwell time) of each polymer were determined using a thermogravimetric method coupled with real-time mass spectroscopy. The surface area and pore size distribution of the pyrolyzed materials derived from the polymers were estimated from the nitrogen adsorption/desorption isotherms. Pyrolyzed membranes from polymer precursors exhibited type I sorption behavior except cellulose acetate (type IV). The gas permeation of the carbon/{\alpha}-alumina$ tubular membranes was characterized using four gases: helium, carbon dioxide, oxygen and nitrogen. The polyetherimide, polyimide, and phenolic resin pyrolyzed polymer membranes showed typical molecular sieving gas permeation behavior, while membranes from polyacrylonitrile and cellulose acetate exhibited intermediate behavior between Knudsen diffusion and molecular sieving. Pyrolyzed membranes with molecular sieving behavior (e.g., polyetherimide, polyimide, and phenolic resin) had a $CO_2/N_2$ selectivity of greater than 15; however, the membranes from polyacrylonitrile and cellulose acetate with intermediate gas transport behavior had a selectivity slightly greater than unity due to their large pore size.

Performance of Convolution Coding Underwater Acoustic Communication System on Frequency Selectivity Index (주파수 선택 지표에 따른 길쌈 부호 수중 음향 통신 시스템의 성능 평가)

  • Seo, Chulwon;Park, Jihyun;Park, Kyu-Chil;Shin, Jungchae;Jung, Jin Woo;Yoon, Jong Rak
    • The Journal of the Acoustical Society of Korea
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    • v.32 no.6
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    • pp.494-501
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    • 2013
  • The convolution code(CC) of code rate 1/2 as a forward error correction (FEC) in Quadrature Phase Shift Keying (QPSK) is applied to decrease bit error rate (BER) by background noise and multipath in shallow water acoustic channel. Ratio of transmitting signal bandwidth to channel coherence bandwidth is defined as frequency selectivity index. BER and bit energy-to-noise ratio gain of transmitted signal according to frequency selectivity index are evaluated. In the results of indoor water tank experiment, BER is well matched theoretical results at frequency selectivity index less than about 1.0. And bit energy-to-noise ratio gain is also matched theoretical value of 5 dB. BER is effectively decreased at frequency selective multipath channel with frequency selectivity index higher than 1.0. But bit energy-to-noise ratio greater than a certain size in terms of CC weaving is effective in reducing bit errors. In the results, the defined frequency selectivity index in this study could be applied to evaluate a performance of CC in multipath channel. Also it could effectively reduced BER in a low speed underwater acoustic communication system without an equalizer.

Properties and Gas Permeability of PEBAX Composite Membrane Containing GO (GO를 함유한 PEBAX 복합막의 성질과 기체투과도)

  • Lee, Seul Ki;Hong, Se Ryeong;Lee, Hyun Kyung
    • Membrane Journal
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    • v.28 no.4
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    • pp.233-242
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    • 2018
  • To study gas membrane using GO (graphene oxide), the PEBAX [poly(ether-block-amide)]-GO polymer composite membrane was prepared by adding GO to PEBAX. Through this composite membrane, gas permeation characteristics for $H_2$, $N_2$, $CH_4$, and $CO_2$ were studied. As a result of the gas permeation test, the permeability of $N_2$, $CH_4$, and $CO_2$ to PEBAX-GO composite membranes gradually decreased as the GO content increased. On the other hand, the gas permeability of $H_2$ increased with the increase of GO content, and it was 21.43 barrer at the GO content of 30 wt%, which was about 5 times higher than that of PEBAX membrane. This is because the GO was easier to operate with a fast and selective gas transport channel for $H_2$ than other gases. The increased selectivity ($H_2/N_2$) and selectivity ($H_2/CH_4$) were influenced by the diffusion selectivity by the permeate gas size. The increased selectivity ($CO_2/N_2$) and selectivity ($CO_2/CH_4$) were more influenced by the solubility selectivity due to the affinity of $CO_2$ and GO for -COOH.

Development of Ceria-Based Slurry with High Selectivity for STI CMP

  • Lim, G.;Kim, T.E.;Kim, J.;Lee, J.H.;Lee, H.W.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.439-440
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    • 2002
  • Nano-Crystalline $CeO_2$ particles were dispersed in deionized water with controlled slurry chemicals for CMP test. According to the CMP test, the removal rate of $SiO_2$ layer was mainly controlled by the size and crystallinity of $CeO_2$ particles which can be controlled by the heat-treatment condition during $CeO_2$ synthesis. In contrast, the removal rate of $Si_3N_4$ layer was significantly influenced by the passivation reagent which protects the $Si_3N_4$ surface layer from excessive dissolution during CMP.

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Basic Study for Development of Denitrogenation Process by Ion Exchange(V) -Synthesis of Nitrate-Selective Ion Exchange Resines- (이온교환법에 의한 탈질소 공정개발의 기초연구(V) -질산성 질소 선택적인 이온교환수지의 합성-)

  • 이동환;김승일;전진희;박찬영;이민규
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.319-323
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    • 2000
  • Nitrate-selective ion exchange resin which have bulky tertiary amine as functional group have been synthesized by the reaction of chloromethylated polystyrene-divinylbenzene copolymer and the corresponding tertiary amine [$NR_3=NE_{t3} 1, N{(C_2 H_4 H_3)}_32]$in ethanol, while commercial resin has $NMe_3$ as functional group. The fundamental properties such as bulk density, water content, appearance index, exchange capacity, effective size, uniformity coefficient of synthesized anion exchange resin (1) have been measured. The ion exchange resin (1) and (2) exhibited the better selectivity for nitrate than sulfate in both batch and continuous column experiments.

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