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Wavepacket Correlation Function Approach for Nonadiabatic Reactions: Quasi-Jahn-Teller Model

  • Park, Heesoo;Shin, Changkyun;Shin, Seokmin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1061-1066
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    • 2014
  • Time-dependent formulations of the reactive scattering theory based on the wavepacket correlation functions with the M${\phi}$ller wavepackets for the electronically nonadiabatic reactions are presented. The calculations of state-to-state reactive probabilities for the quasi-Jahn-Teller scattering model system were performed. The conical intersection (CI) effects are investigated by comparing the results of the two-surface nonadiabatic calculations and the single surface adiabatic approximation. It was found that the results of the two-surface nonadiabatic calculations show interesting features in the reaction probability due to the conical intersection. Single surface adiabatic calculations with extended Born-Oppenheimer approximation using simple wavepacket phase factor was found to be able to reproduce the CI effect semi-quantitatively, while the single surface calculations with the usual adiabatic approximation cannot describe the scattering process for the Jahn-Teller model correctly.

Model Reference Adaptive Pole-Placement Controller of Nonminimum Phase systems (비최소 위상 시스템에 대한 기준 모델 적응 폴-플레이스먼트 제어기)

  • 김종환;최계근
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.22 no.6
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    • pp.89-96
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    • 1985
  • A pole-placement control of discrete, deterministic, single-input single-output nonmini-mum phase systems is considered using a model reference type approach. The proposed pole-placement controller is designed in the parameter form to make the transfer function of the controller equal to that of the reference model with only single variable polynomial S(q-1). The proposed adaptive pole-placement controllr is designed with the true system para-meters by applying the adaptation method to the proposed pole-placement controller.

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Analysis of Tunnelling Rate Effect on Single Electron Transistor

  • Sheela, L.;Balamurugan, N.B.;Sudha, S.;Jasmine, J.
    • Journal of Electrical Engineering and Technology
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    • v.9 no.5
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    • pp.1670-1676
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    • 2014
  • This paper presents the modeling of Single Electron Transistor (SET) based on Physical model of a device and its equivalent circuit. The physical model is derived from Schrodinger equation. The wave function of the electrode is calculated using Hartree-Fock method and the quantum dot calculation is obtained from WKB approximation. The resulting wave functions are used to compute tunneling rates. From the tunneling rate the current is calculated. The equivalent circuit model discuss about the effect of capacitance on tunneling probability and free energy change. The parameters of equivalent circuit are extracted and optimized using genetic algorithm. The effect of tunneling probability, temperature variation effect on tunneling rate, coulomb blockade effect and current voltage characteristics are discussed.

3D Measurement Method Based on Point Cloud and Solid Model for Urban SingleTrees (Point cloud와 solid model을 기반으로 한 단일수목 입체적 정량화기법 연구)

  • Park, Haekyung
    • Korean Journal of Remote Sensing
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    • v.33 no.6_2
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    • pp.1139-1149
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    • 2017
  • Measuring tree's volume is very important input data of various environmental analysis modeling However, It's difficult to use economical and equipment to measure a fragmented small green space in the city. In addition, Trees are sensitive to seasons, so we need new and easier equipment and quantification methods for measuring trees than lidar for high frequency monitoring. In particular, the tree's size in a city affect management costs, ecosystem services, safety, and so need to be managed and informed on the individual tree-based. In this study, we aim to acquire image data with UAV(Unmanned Aerial Vehicle), which can be operated at low cost and frequently, and quickly and easily quantify a single tree using SfM-MVS(Structure from Motion-Multi View Stereo), and we evaluate the impact of reducing number of images on the point density of point clouds generated from SfM-MVS and the quantification of single trees. Also, We used the Watertight model to estimate the volume of a single tree and to shape it into a 3D structure and compare it with the quantification results of 3 different type of 3D models. The results of the analysis show that UAV, SfM-MVS and solid model can quantify and shape a single tree with low cost and high time resolution easily. This study is only for a single tree, Therefore, in order to apply it to a larger scale, it is necessary to follow up research to develop it, such as convergence with various spatial information data, improvement of quantification technique and flight plan for enlarging green space.

Single-Electron Devices for Hopfield Neural Network (홉필드 신경회로망을 위한 단일전자 소자)

  • Yu, Yun-Seop
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.6
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    • pp.16-21
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    • 2008
  • This paper introduces a new type of Hopfield neural network using newly developed single-electron devices. In the electrical model of the Hopfield neural network, a single-electron synapse, used as a voltage(or current)-variable resistor, and two stages of single-electron inverters, used as a nonlinear activation function, are simulated with a single-electron circuit simulator using Monte-Carlo method to verily their operation.

2-Stage Adaptive Skin Color Model for Effective Skin Color Segmentation in a Single Image (단일 영상에서 효과적인 피부색 검출을 위한 2단계 적응적 피부색 모델)

  • Do, Jun-Hyeong;Kim, Keun-Ho;Kim, Jong-Yeol
    • 한국HCI학회:학술대회논문집
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    • 2009.02a
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    • pp.193-196
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    • 2009
  • Most of studies adopt a fixed skin color model to segment skin color region in a single image. The methods, however, result in low detection rates or high false positive error rates since the distribution of skin color is varies depending on the characteristics of input image. For the effective skin color segmentation, therefore, we need a adaptive skin color model which changes the model depending on the color distribution of input image. In this paper, we propose a novel adaptive skin color segmentation algorithm consisting of 2 stages which results in both high detection rate and low false positive error rate.

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Dependence of Weibull parameters on the diameter and the internal defects of Tyranno ZMI fiber in the strength analysis

  • Morimoto, Tetsuya;Yamamoto, Koji;Ogihara, Shinji
    • Advanced Composite Materials
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    • v.16 no.3
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    • pp.245-258
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    • 2007
  • The single-modal Weibull model has been assessed on Tyranno ZMI Si-Zr-C-O fiber if a set of shape and scale parameters accurately reproduced the effect of the size of the diameter on strength. The tensile data of a single fiber have been divided into two expedient groups as 'small diameter' group and 'large diameter' group in deriving the parameters, which should be consistent if the Weibull model accurately reproduced the size effect. However, the derived Weibull parameters were inconsistent between the two groups. Thereby the authors have concluded that the parameters of the single-modal Weibull model are dependent on the fiber diameter, so that the model is inadequate to reproduce the strength size effect. On the other hand, Weibull parameters were found consistent between the two groups by excluding the data of 'large mirror zone' sample, which was defined as the sample around 10% mirror zone area of the fracture surface. What is more, the exclusion reduced the strength variance more drastically in the 'large diameter' group than in the 'small diameter' group, even though the 'large mirror zone' samples were found identical in the percentage between the two groups. The authors therefore conclude that diameter limitation to the 'small diameter' group level can lead to drastically less distributed strength values than the estimated strength through the Weibull scaling on the present Tyranno ZMI Si-Zr-C-O fiber.

Single Channel Active Noise Control using Adaptive Model (적응모델을 이용한 단일채널 능동 소음제어)

  • Kim, Yeong-Dal;Lee, Min-Myeong;Jeong, Chang-Gyeong
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.49 no.8
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    • pp.442-450
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    • 2000
  • Active noise control is an approach to noise reduction in which a secondary noise source that destructively interferes with the unwanted noise. In general, active noise control systems rely on multiple sensors to measure the unwanted noise field and the effect of the cancellation. This paper develops an approach that utilizes a single sensor. The noise field is modeled as a stochastic process, and a time-adaptive algorithm is used to adaptively estimate the parameters of the process. Based on these parameter estimates, a canceling signal is generated. Opppenheim model assumed that transfer function characteristics from the canceling source to the error sensor is only propagation delay. But this paper proposes a modified Oppenheim model by considering transfer characteristics of acoustic device and noise path. This transfer characteristics is adaptively cancelled by adaptive model. This is proved by computer simulation with artifically generated random noise and sine wave noise. The details of the proposed architecture, and theoretical simulation and experimental results of the noise cancellation system for three dimension enclosure are presented in the paper.

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General Derivation of Two-Fluid Model (2상 유동 모델의 일반적인 유도)

  • Hee Cheon No
    • Nuclear Engineering and Technology
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    • v.16 no.1
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    • pp.1-10
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    • 1984
  • General time-volume averaged conservation equations and jump conditions for two-phase flows are derived here. The time-averaged equations for a single phase region in two-phase flow are obtained from local instant balance equations by a technique often used for single phase turbulent flow equations. The results obtained by integrating the time averaged equations over a flow volume are spatially averaged twice; first, they are averaged over a single phase region of the k-th phase and then averaged over the total volume of the k-th phase, in a flow volume. The mass, momentum, and energy conservation equations are obtained from the general time-volume averaged equations. The advantages of the present model are explained by comparing it with Ishii's model (1) and Banerjee's model (2). Finally, the assumptions and approximate terms of the equations of the THERMIT-6S are clarified.

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Sensitivity of Parameters for Elasto-plastic Constitutive Model (탄.소성 구성 모델의 초질매개변수 예민성)

  • Jeong, Jin-Seop;Kim, Chan-Gi;Lee, Mun-Su
    • Geotechnical Engineering
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    • v.8 no.2
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    • pp.81-96
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    • 1992
  • This paper dealt with the influence of experimental error generated inevitably during performing experiments on the granular soil behaviour analysis selecting Lade's Single Work-Hardening constitutive model. Several isotropic compression-expansion tests and a series of drained conventional triaxial tests with various confining pressures for Baekma river sands were performed and the values of parameters for the above model were determined using computer program developed for this study based on regression analysis. By finding the range of the upper and lower bound for deviator stress and volumetric strain versus axial strain dependant on the increase and decrease of the standard deviation from mean value of parameters, sensitivities of all the parameters were examined. Practical use of program to determine the parameters and capability to predict the behaviour of granular soil by Lade's Single Work -Hardening model verified.

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