• Membrane Journal
• /
• v.15 no.3
• /
• pp.206-212
• /
• 2005

Acid-resistant poly(vinyl alcohol) (PVA) membranes connected with ethylene and ether groups were prepared via a thermal crosslinking reaction by varying the ratio of PVA to ethylene glycol diglycidyl ether (EGDE). The crosslinked membranes were characterized using FT-IR and swelling tests, respectively. Pervaporation behaviors with the PVA membranes were investigated for aqueous TFEA (2,2,2-trifluoroethanol) as a function of EGDE content and operating temperature. The pervaporation properties far MA (methacrylic acid)/water mixture were also carried out with the optimized PVA membrane. The PVA membranes prepared with EGDE showed more excellent acid-resistance than those crosslinked with gluaraldehyde. The membranes showed high permeation fluxes of 0.1 and $0.3\;km^2h$ and high separation factors of 100 and 900 in the $96\;wt\%$ TFEA and MA aqueous fred mixtures at high temperature above $80^{\circ}C$, respectively. These confirmed theses membranes could be used in esterification membrane reactor process for the production of 2,2,2-trifluoroethylmetacrylate (TFEMA).

• Journal of Environmental Science International
• /
• v.2 no.1
• /
• pp.61-72
• /
• 1993

Result of this study indicate that two criteria must be met in order to have effective macrocycle-mediated transport in these emulsionsystem. First, one must effective extraction of the post transition metals, $Cd^{2+}$. $Pb^{2+}$ and $Hg^{2+}$ , into toluene membrane. The effectiveness of this extraction is greatest if log K values for the metal-macrocycle interaction is large. Second, the ratio of the log K values for the metal ion-receiving phase to the metal ion-macrocycle interaction must be large enough to ensure quantitative stripping of the metal ion at the toluene phase interface. Control of the first step can be obtained by appropriate selection of macrocycle donor atom, substituents, and cavity radius. The second step can be controlled by selecting the proper complexing agent for inclusion in the receiving phase. The order of the transport, when using the several $A^-$ species such as $SCN^-$, $1^-$, $Br^-$ and $Cl^-$ is the order of the changing degree of solvation for $A^-$ and the transport of the metals is also affected by the control of concentration for receiving species because of solubility-differences. In this study, we can seperate each single metal ion from the mixture of $Cd^{2+}$, $Pb^{2+}$, and $Hg^{2+}$ ions by using the toluene membranes controlled by optimized conditions. Transport of the single metal is also very good, and alkaline and alkaline earth metals as interferences ions did not affect the seperation of the metals in this macrocycle-liquid membrances but transition metal ions were partially affected as interferences for the post transition metal ions.

• Journal of Biosystems Engineering
• /
• v.27 no.1
• /
• pp.59-66
• /
• 2002

The objectives of the study were to analyze the acoustic characteristics related to the internal quality factors of watermelon(Citrulus Vulgaris Schrad). Among the various internal quality factors, only four factors such as ripeness, inside cavity, yellow belt and blood flesh were considered in this study. Relationships between the internal quality factors, the day after fruit set and the day after harvest were also investigated. Test apparatus was the same as the apparatus described in the previous study(Choi et at., 2000). The selected sample was divided into four groups; 69 samples used for ripeness tests 56 samples for ripeness test along the day after fruit set and for yellow belt detection, 60 samples for ripeness along the day after harvest 44 samples fur blood flesh detection. It was shown that the first peak frequencies shifted to the lower range and the energy ratios of the bandwidths between 0∼550 Hz to the bandwidths between 850∼2500 Hz increased as the day after fruit set elapsed. Since the acoustic responses of the watermelon such as frequency and magnitude began to change from 10 days after harvest, the storage period of watermelon in a normal temperature condition seemed to be approximately 10 days after harvest. The ratios of the first peak amplitude to the maximum peak amplitude fur the sound watermelon showed the higher value than that fur watermelon with cavity inside, and the separation between the sound and cavity inside could be accomplished by the ratio value of 0.25. The energy ratios (0∼550 Hz/850∼2,500 Hz) for the watermelon with cavity inside showed the higher value than 2.3. The frequency characteristics of the yellow belt watermelon appeared mostly in the range of 600∼900 Hz frequencies. The yellow belt watermelon showing the energy spectral density function at this frequency range to be over 70 seemed to be not a marketable commodity, The energy ratios(0∼550 Hz/850∼2,500 Hz) for the blood flesh watermelon showed the higher value than 3.5.

• Journal of Korean Society of Transportation
• /
• v.27 no.5
• /
• pp.97-111
• /
• 2009

Image-based traffic information collection systems have entered widespread adoption and use in many countries since these systems are not only capable of replacing existing loop-based detectors which have limitations in management and administration, but are also capable of providing and managing a wide variety of traffic related information. In addition, these systems are expanding rapidly in terms of purpose and scope of use. Currently, the utilization of image processing technology in the field of traffic accident management is limited to installing surveillance cameras on locations where traffic accidents are expected to occur and digitalizing of recorded data. Accurately recording the sequence of situations around a traffic accident in a signal intersection and then objectively and clearly analyzing how such accident occurred is more urgent and important than anything else in resolving a traffic accident. Therefore, in this research, we intend to present a technology capable of overcoming problems in which advanced existing technologies exhibited limitations in handling real-time due to large data capacity such as object separation of vehicles and tracking, which pose difficulties due to environmental diversities and changes at a signal intersection with complex traffic situations, as pointed out by many past researches while presenting and implementing an active and environmentally adaptive methodology capable of effectively reducing false detection situations which frequently occur even with the Gaussian complex model analytical method which has been considered the best among well-known environmental obstacle reduction methods. To prove that the technology developed by this research has performance advantage over existing automatic traffic accident recording systems, a test was performed by entering image data from an actually operating crossroad online in real-time. The test results were compared with the performance of other existing technologies.

• Proceedings of the Mineralogical Society of Korea Conference
• /
• 2003.05a
• /
• pp.54-54
• /
• 2003

The metasedimentary rocks together with various granitoids are the main constituents in Taebaeksan gneiss complex, northern Yeongnam Massif. Chemical compositions of sedimentary rocks may reflect the nature of the provenance and could be crucial for understanding the evolution of early continental crust. Previous workers have suggested that the provenance and tectonic studies based on the geochemistry of sediments are applicable to the Precambrian samples. In this study we analyzed the major, trace and REE elements of metasedimentary rocks to understand their provenance and tectonic setting during sedimentation. The overall geochemical characteristics of metasedimentary rocks are similar to those of average shale of the post-Archean. Major element chemistry indicates mature and sorted nature of the sediments. The degree of weathering in the source rocks the is not uniform, as inferred from a large scatter in chemical indices of weathering (CIW). The immobile trace elements such as Th, Sc, and REE can be used to discriminate various sedimentary processes. The Th/sc ratios (0.9 - 4.4) are larger than those of the upper crust and average shale, suggesting that the felsic source predominates. The contents of Ni and Cr and the variations in the ratio of compatible to incompatible elements are similar to the average post-Archean shale. Uniform chondrite-normalized REE pattern with the LREE enrichment (LaN/SmN = 4.9 ${\pm}$ 0.4) and slight negative Eu anomalies (Eu/Eu$\^$*/ = 0.7 ${\pm}$ 0.1) also support this observation. The presence of negative Eu anomaly indicates that intracrustal igneous processes involving plagioclase separation have affected the provenance rocks. The LREE enrichment implies the major role of felsic rocks in source rocks. The eNd (1.9 Ga) values of metasediment rocks vary from 9.4 to 6.7, corresponding to TDM of 2.9 - 2.7 Ga. On the other hand, the 147Sm/144Nd ratios are 0.1079 - 0.1101, corresponding to typical tettigenous sediments. The geochemical features of metasedimentary rocks such as high abundances of large ion lithophile elements, high ratios of Th/Sc and La/Sm, commonly high Th/U ratios, negative Eu anomalies, and negative eNd, suggest a provenance consisting virtually entirely of recycled upper continental crust in passive margin environment. Tectonic discrimination diagrams based upon major element compositions also support this suggestion. In conjunction with igneous activity and metamorphism in the convergent margin setting at 1.8 - 1. 9 Ga, the transition from passive margin to active margin characterize the Paleoproterozoic crustal evolution in northern Yeongnam Massif.

• Journal of Korean Society of Water and Wastewater
• /
• v.19 no.3
• /
• pp.288-294
• /
• 2005

This study was conducted to evaluate the grit removal efficiency of tornado block-type vortex grit separator. Vortex grit separator was manufactured for this study, and it was characterized by the impeller and tornado block installed in separator. Impeller was installed to increase water velocity in the separator and tornado block was installed to increase the grit lifting efficiency. Pilot study was also conducted in A sewage treatment plant (STP) in Gyeonggi province from November 2003 to May 2004 (64 days). Major findings are as follows. 1. Impeller was proven to increase water velocity in the grit separator, especially in low flow rate. This influence will increase separation ratio of organics from grits, preventing those organics from sedimentation. 2. Sand (with 0.2~0.3mm size) removal efficiency was over 98 % and 96 %, at the flow rate of $500m^3/day$ and $750m^3/day$ under the condition that impeller rotation velocity kept at 15 rpm. Originally that grit separator was designed to have the capacity of $500m^3/day$. $750m^3/day$ was tried to investigate the performance of this type of grit separator under overload condition. Stable grit removal was still available to the extent of 150% of designed capacity. 3. It took less than 3 minutes for the grit separator to completely lift out 3 kgs of 0.2-0.3 mm sized, settled sand at the bottom to 2,060 mm high above water surface. But it showed the tendency to spend a little more time on lifting the grit as the grit size and the vertical height of the lift increased. 4. During experimental duration in A STP, it was found that the average amount of inlet grit was about 981 g/day (160~1,685 g/day) under $500m^3/day$ of operation condition, but it varied so severely during the experimental duration. After classification of discharged grit according to its size, grit with 0.3-0.42 mm size was found as largest part of output.

• Applied Chemistry for Engineering
• /
• v.31 no.2
• /
• pp.179-186
• /
• 2020

In this study, chitosan/zeolite composites were prepared by using basalt-based zeolite impregnated with aqueous chitosan solution for the adsorptive separation of CO₂. The prepared composites were characterized by scanning electron microscopy (SEM), Fourier-transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption analysis. In addition, the adsorption equilibrium isotherms for CO₂ and N₂ were measured at 298 K using a volumetric adsorption system, and the results were analyzed by applying adsorption isotherm equations (Langmuir, Freundlich, and Sips) and energy distribution function. It was found that CO₂ adsorption capacities were well correlated with the structural characteristics of chitosan and zeolite, and the ratio of elements [N/C, Al/(Si + Al)] formed on the surface of the composite. Moreover, the CO₂/N₂ adsorption selectivity was calculated under the mixture conditions of 15 V : 85 V, 50 V : 50 V, and 85 V : 15 V using the Langmuir equation and the ideal adsorption solution theory (IAST).

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.27 no.4
• /
• pp.278-285
• /
• 1991

The authors propose to use the slot system in order to improve of the efficiency for the cambered otter boards. The experiment is divided into 2 parts, one is the efficiency model test, and the other is the visualization model test. The hydrodynamic characteristics of the model otter boards were tested by efficiency model test to measure the shearing, drag force of the models and visualization test using hydrogen bubble method to observe the streak-line and time-line of flow around the models, and milk spout method to observe the separation zone in the wake behind the models. This study tested for 5 models such ad without slot, slot position 0.2C, 0.4C, 0.6C and 0.8C. The results obtained are as follows: \circled1 The maximum C sub(L) of model otter board with slot position 0.6C in attack angle 27$^{\circ}$ was the highest of all models, it's value was 1.59. \circled2 In general, the L/D ratio of the one slot otter boards were 16~28% higher than otter board without slot. \circled3 The slot position 0.6C was better than any other slot position, and it's conformed by visiualization. \circled4 As to the model otter board with slot position 0.6C, flow speed of the back side was faster 1.3 to 1.7 times than in the front side. \circled5 The size of the separated zone in case of the model otter board with 0.6C was smaller than that of any other models.

• Resources Recycling
• /
• v.25 no.6
• /
• pp.13-22
• /
• 2016

This study is aimed at compare and evaluate the environmental impact of End-of-Life Vehicle(ELV) on the eco-friendly technology dismantling and recycling system, using Life Cycle Assessment (LCA) method. In this study, it was analyzed for the environmental impacts of raw materials, disassemble process, recycle parts separation and waste treatment into the process of ELV treatment by greenhouse gas and resource consumption, etc. Through this study, the indoor rail type dismantling technology were recycling rate applied on the alternate system was increased by approximately 8%. As a result, it was 3 to 88% by improving the environmental impact category. In addition, the added benefit of approximately 8 - 62% in pre-market occurred through the recycling rate, improve parts reuse rate of ELV. Through the results of this study, legal compliance, improved reuse and recycling ratio, used parts market reach, enable exports has identified the need for the effort that the dissemination and diffusion of eco-friendly technology.

• Resources Recycling
• /
• v.27 no.4
• /
• pp.16-22
• /
• 2018

Inconel713C which of a commercial Ni super alloy have the compositions of 70 wt.% Ni, 12 wt.% Cr, 6 wt.% Al and 4 wt.% Mo. In this study, solvent extraction has been performed to separate Mo from the synthetic leaching solution, formation of Inconel713C alloy similarly and is found the optimum conditions of recovery of Mo from the leaching solution. The effects of some variables, such as the nature and concentration of the extractants, $H_2SO_4$ concentrations, and the presence of impurities were investigated. The extraction percentage of Mo by Cyanex272 is 96% in the condition of pH 1 and 4% of concentration of Cyanex272 but Alamine336 is 99% in the condition of the range of pH 1 to 4 and 1 wt.% of concentration of Alamine336. In the case of Alamine336, the extraction percentage of Mo is increased by increasing of the concentration of Alamine336. The optimum condition of this experiment is pH 1 in aqueous phase, 1% concentration of Alamine336 and activation ratio of $H_2SO_4$ 1:0.5.