Resources Recycling (자원리싸이클링)

The Korean Institute of Resources Recycling (한국자원리싸이클링학회)
권호 표지
DOI QR코드

DOI QR Code

Basic Study for Solvent Extraction Separation of Mo from Synthetic Leaching Solution of Inconel713C by Alamine336

Inconel713C 모사 용액으로부터 Alamine336을 통한 Mo의 용매추출분리를 위한 기초 연구

  • 박상렬 (성일하이텍(주)) ;
  • 안종관 (중원대학교 신재생에너지자원학과)
  • Received : 2018.04.17
  • Accepted : 2018.07.02
  • Published : 2018.08.31
Download PDF
⟨ Previous Next ⟩

Abstract

Inconel713C which of a commercial Ni super alloy have the compositions of 70 wt.% Ni, 12 wt.% Cr, 6 wt.% Al and 4 wt.% Mo. In this study, solvent extraction has been performed to separate Mo from the synthetic leaching solution, formation of Inconel713C alloy similarly and is found the optimum conditions of recovery of Mo from the leaching solution. The effects of some variables, such as the nature and concentration of the extractants, $H_2SO_4$ concentrations, and the presence of impurities were investigated. The extraction percentage of Mo by Cyanex272 is 96% in the condition of pH 1 and 4% of concentration of Cyanex272 but Alamine336 is 99% in the condition of the range of pH 1 to 4 and 1 wt.% of concentration of Alamine336. In the case of Alamine336, the extraction percentage of Mo is increased by increasing of the concentration of Alamine336. The optimum condition of this experiment is pH 1 in aqueous phase, 1% concentration of Alamine336 and activation ratio of $H_2SO_4$ 1:0.5.

Inconel713C에는 Ni 70 wt.%, Cr 11 ~ 14 wt.%, Al 5 ~ 6 wt.% 및 Mo 4 wt.% 가량 함유되어 있다. 본 연구에서는 Inconel713C 모사용액으로부터 Mo을 회수하고자 용매추출공정을 이용하여 Mo 분리 추출하는 기초연구를 수행하였다. 실험변수로는 추출제의 종류 및 농도, 침출액의 평형 pH, $H_2SO_4$의 농도 및 불순물의 영향 실험을 수행하여 Mo을 회수하는 최적조건을 조사하였다. 음이온 추출제인 Alalmine336은 평형 pH 1 이상에서 99% 추출되고, 양이온 추출제인 Cyanex272는 96%의 추출률을 나타내어 Alamine336의 Mo 추출률이 우수하다. 또한 수상의 평형 pH가 1~4인 조건에서 Mo의 회수율은 Alamine336이 Cynex272 보다 높게 나타났다. 본 연구의 경우 용매추출공정을 이용한 Mo 회수의 최적조건은 평형 pH 1, Alalmine336 1 wt.%, 황산의 활성화 처리 농도는 1 : 0.5이었다.

Keywords

References

  1. All Metals & Forge Group webpage, 2018 : http://www.steelforge.com/.
  2. KORES webpage, 2017 : https://m.kores.net/mobile/mprice/mbasemetal.
  3. KIMM, 2009 : MaterALL, pp.343-350.
  4. KITA, 2015 : Trade trends of Ni alloy, https://unipass.customs.go.kr:38030/ets/.
  5. Kyoungho, P. and Jeoungsu, S., 2010 : Application and understanding of Ni, Steel & metal news.
  6. Wonguen, L. and Bumrae, C. 2017 : Eco-friendly hydrometallurgy process for the recovery of Mo from spent petroleum catalyst. KR. Patent No. 101727891B1.
  7. Minwoo, K., 2011 : Master thesis, Selective recovery of V, Mo by solvent extraction from sodium leaching solution of spent DSC, Korea Univ., pp.10-15.
  8. Nguyen, Hong Thi, and Lee, Man Seung, 2013 : Recovery of Molybdenum and Vanadium from Acidic Leaching Solution of Spent Catalysts by Solvent Extraction, J. the Korean Inst. of Resources Recycling, 22(4), pp.3-11. https://doi.org/10.7844/kirr.2013.22.4.3
  9. Nguyen, Thi Hong and Lee, Man Seung, 2016 : Separation of Molybdenum and Tungsten from Sulfuric acid Solution by Solvent Extraction with Alamine336, J. the Korean Inst. of Resources Recycling, 25(1), pp.16-23. https://doi.org/10.7844/kirr.2016.25.1.16
  10. Valverde Jr, I. M., Paulino, J. F., and Afonso, J. C., 2008 : Hydrometallurgy route to recover molybdenum, nickel, cobalt and aluminum from spent hydrotreating catalysts in sulphuric acid medium, J. Hazad. Mater., 160, pp.310-317. https://doi.org/10.1016/j.jhazmat.2008.03.003
  11. Parhi, P. K., Park, K. H., Kim, H. I., and Park, J. T., 2011 : Recovery of molybdenum from the sea nodule leach liquor by solvent extraction using Alamine 304-I, Hydrometallurgy, 105, pp.195-200. https://doi.org/10.1016/j.hydromet.2010.09.004
  12. Zeng, L. and Cheng, C. Y., 2009 : A literature review of the recovery of molybdenum and vanadium from spent hydrodesulphurisation catalyst. Part I: Metallurgical processes, Hydrometallurgy, 98, pp.1-9. https://doi.org/10.1016/j.hydromet.2009.03.010
  13. Zeng, L. and Cheng, C. Y., 2009 : A literature review of the recovery of molybdenum and vanadium from spent hydrodesulphurisation catalysts Part II: Separation and purification and references within, Hydrometallurgy, 98, pp.10-20. https://doi.org/10.1016/j.hydromet.2009.03.012
  14. Nekovar, P. and Schrotterova, D., 2000 : Extraction of V(V), Mo(VI) and W(VI) polynuclear species by JMT, Chem. Eng. J., 79, pp.229-233. https://doi.org/10.1016/S1385-8947(00)00207-2
  15. Jonggwan A. and Heekeong J., 2015 : Solvent Extraction Separation of Re (VI) from Hydrochloric Acid Leaching Solution of Spent Super Alloy by Alamine 304-1, J. the Korean Inst. of Resources Recycling, 24(5), pp.56-62. https://doi.org/10.7844/KIRR.2015.24.5.56
  16. Mishra, D., Chaudhury, G. R., Kim, D. J., and Ahn, J. G., 2010 : Recovery of metal values from spent petroleum catalyst using leaching-solvent extraction technique, Hydrometallurgy, 101, pp.35-40. https://doi.org/10.1016/j.hydromet.2009.11.016