• 제목/요약/키워드: Secondary Material

검색결과 1,260건 처리시간 0.024초

Flow Induced Material Degradation In Power Plant Secondary Systems-A Review

  • Kim, I.S.;Van Der Helm, M.;Ballinger, R.G.
    • Nuclear Engineering and Technology
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    • 제30권2호
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    • pp.148-163
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    • 1998
  • Flow Induced Material Degradation (FIMD) is reviewed focusing on Flow Accelerated Corrosion (FAC) models. Several examples of FAC related incidents are described, which include nuclear and fossile power plants. Lastly, mitigation techniques such as inspection, material selection, water chemistry, temperature, and hydrodynamic factor are discussed.

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리튬 이차전지용 금속이 담지된 다공성 실리콘 음극물질의 전기화학적 특성 (Electrochemical Characteristics of Porous Modified Silicon Impregnated with Metal as Anode Materials for Lithium Secondary Batteries)

  • 장은정;전법주
    • 한국수소및신에너지학회논문집
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    • 제23권4호
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    • pp.353-363
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    • 2012
  • The relationship between the diffusivity and electrochemical characteristics of lithium secondary battery with the modified Si anode material prepared in HF/$AgNO_3$ solution was investigated. The crystallographic structure and images of the modified porous Si and modified Si/Cu was examined using the X-ray diffraction, BET and SEM. To examine the effect of metal composite and pore size distribution according to chemical etching on the electrochemical characterization, the electrodes for half cells were prepared with the modified Si, modified Si/Cu, and modified Si/Cu annealed with $600^{\circ}C$. Our results showed that the chemical diffusivity of lithium ions was related to structure and resistance of Si/Cu composite anode material. The lithium diffusivity in modified silicon compound calculated from the CV was at the range of $1{\times}10^{-12}$ to $9{\times}10^{-16}cm^2/s$. The effects of modified silicon structure and resistance on the cycling efficiency were significant.

전자빔 몬테 카를로 시물레이션 프로그램 개발 및 전자현미경 이미징 특성 분석 (Development of Electron Beam Monte Carlo Simulation and Analysis of SEM Imaging Characteristics)

  • 김흥배
    • 한국정밀공학회지
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    • 제29권5호
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    • pp.554-562
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    • 2012
  • Processing of Scanning electron microscope imaging has been analyzed in both secondary electron (SE) imaging and backscattered electron (BSE) image. Because of unique characteristics of both secondary electron and backscattered electron image, mechanism of imaging process and image quality are quite different each other. For the sake of characterize imaging process, Monte Carlo simulation code have been developed. It simulates electron penetration and depth profile in certain material. In addition, secondary electron and backscattered electron generation process as well as their spatial distribution and energy characteristics can be simulated. Geometries that has fundamental feature have been imaged using the developed Monte Carlo code. Two, SE and BSE images generation process will be discussed. BSE imaging process can be readily used to discriminate in both material and geometry by simply changing position and direction of BSE detector. The developed MC code could be useful to design BSE detector and their position. Furthermore, surface reconstruction technique is possibly developed at the further research efforts. Basics of Monte Carlo simulation method will be discussed as well as characteristics of SE and BSE images.

방전전압에 따른 리튬 이온 2차전지용 음극물질의 전기화학적 특성 (The electrochemical Characteristics on the Anode Material of Lithium Ion Secondary Batteries with Discharge Voltage)

  • 박종광;한태희;정동철;임성훈;한병성
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제49권6호
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    • pp.328-334
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    • 2000
  • A lithium ion secondary battery using carbon as a negative electrode has been developed. Further improvements to increase the cell capacity are expected by modifying the structure of the carbonaceous material. There are hopes for the development of large capacity lithium ion secondary batteries with long cycle, high energy density, high power density, and high energy efficiency. In the present paper, needle cokes from petroleum were examined as an anode of lithium ion secondary battery. Petroleum cokes, MCL(Molten Caustic Leaching) treated in Korea Institute Energy Research, were carbonized at various temperatures of 0, 500, 700, $19700^{\circ}C$ at heating rate of $2^{\circ}C$/min for lh. The electrolyte was used lM liPF6 EC/DEC (1:1). The voltage range of charge & discharge was 0.0V(0.05V) ~ 2.0V. The treated petroleum coke at $700^{\circ}C$ had an initial capacity over 560mAh.g which beyond the theoretical maximum capacity, 372mAh/g for LiC6. This phenomena suggests that carbon materials with disordered structure had higher cell capacity than that the graphitic carbon materials.

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플라즈마 삽입전극의 전류에 미치는 밀도 구배의 영향 (Influence of the Density Gradient on the Current of the Electrode Immersed in the Non-uniform Plasma)

  • 황휘동;구치욱;정경재;최재명;김곤호;고광철
    • 한국전기전자재료학회논문지
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    • 제24권6호
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    • pp.504-509
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    • 2011
  • The conducting current of non-uniform plasma immersed electrode consists of ion current and secondary electron emission current caused by the impinging ion current. The ion current is determined by the ion dose passing through the sheath in front of electrode and the ion distribution in front of the electrode plays an important role in the secondary electron emission. The investigation of the distributed plasma and secondary electron effect on electrode ion current was carried out as the stainless steel electrode plugged with quartz tube was immersed in the inductively coupled Ar plasma using the antenna powered by 1 kw and the density profile was measured. After that, the negative voltage was applied by 1 kV~6 kV to measure the conduction current for the analysis of ion current.

DMSO 첨가에 따른 리튬이차전지용 복합필름의 전기적 특성 (The Electrical Characteristic of Composite Film for Lithium Secondary Battery by adding DMSO)

  • 박수길;김종진;이창진;김상욱;김현후;임기조;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.269-272
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    • 1997
  • The Lithium ion secondary battery has been developed for high energy density of portable electrical device and electronics. Among the many conductive polymer materials, the positive active film for Li polymer battery system was synthesized successfully from polyphenylene diamine(PPD) by chemical polymerization in our lab. And PPD-DMcT(2, 5-dimercapto-1, 3, 4-thi-adiazole) composite flim conductive material, at high temperature was also prerared with the addition of dimethylsulfoxide(DMSO). The surface morphology and thermal stability of prepared composite flim was carried out by using SEM and TGA, respectively. Electrochemical and electrical conductivity of composite flim were also discussed by cyclic voltammetry and four-probe method in dry box(<27pm). And the electrode reaction mechanism was detected and analyzed from the half cell unit battery system.

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Preparation of Anode Material for Lithium Secondary Battery using Pitch-coated Graphite Residue Compounds

  • Ko, Young-Shin;Oh, Won-Chun
    • Carbon letters
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    • 제8권3호
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    • pp.207-213
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    • 2007
  • The properties and electrochemical characteristics of anode material using pitch-coated graphite residue compounds by heat-treatment at $600^{\circ}C$ for 1 hour were investigated. The distance of layers of pitch-coated graphite residual compounds was 3.3539 ${\AA}$, which was as same as that of graphite. Its electrochemical and charge discharge characteristics were tested according to different four types of carbon material, natural graphite, pitch-coated graphite, amorphous graphite and pitch-coated graphite residual compounds, respectively. So it was shown the best charge-discharge characteristics in all of the samples. For the electrochemical and charge-discharge characteristics, although pitch-coated graphite residual compounds had different carbon contents 70% and 80%, these two samples were shown good electrochemical and charge-discharge characteristics.

$SF_6$ 가스 방전 특성의 유한요소해석 (A finite Element Analysis on the discharge characteristics of $SF_6$ gas)

  • 최승길;심재학;강형부
    • 한국전기전자재료학회논문지
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    • 제13권3호
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    • pp.265-272
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    • 2000
  • In this paper the corona discharge in SF$_{6}$ gas used as insulating material in lots o high voltage equipment, is simulated by finite element method with Flux-Corrected Transport(FCT) method. By application of proposed method the negative corona discharge characteristics in needle to plane electrode is analyzed with time step. For the accuracy of analysis the secondary electron emission by photon and ion are also considered as well as the accuracy of analysis the secondary electron emission by photon and ion are also considered as well as townsend first ionization and electron attachment. The calculated results show that the electric field intensity between anode and ion group is decreased as times go-by according to field distortion by those space charge. Accordingly the electron density is decreased strongly by the attatchment effect of SF6 gas so that the corona discharge becomes extinguished abruptly.y.

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실리콘 재료의 표면개질에 따른 리튬이차전지 음극 특성 (Electrochemical Properties of Surface-Modified Silicon as Anode for Lithium Secondary Batteries)

  • 박철완;도칠훈;문성인;윤문수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.602-606
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    • 2003
  • Silicon has been developed as an alternate anode material for lithium secondary batteries. A simple approach to improve the electrical contact of silicon powder has described. Carbon-coated and silver-coated silicon have been prepared by chemical vapor deposition and electroless plating respectively. Assembled cells, which consisted of surface modified silicon, lithium foil and $Li^+$ contained organic electrolyte, have been studied using electrochemical methods. Carbon-coated silicon was improved in the electrochemical performance such as reversibility and resistance compared to surface-unmodified silicon.

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