• Title/Summary/Keyword: Salt diffusion

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A Study on the Glass Strengthened in Salt Solution by Chemical Ion Exchange (염 용액에서의 화학적 이온교환 강화유리에 관한 연구)

  • 이종근;김인섭
    • Journal of the Korean Ceramic Society
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    • v.24 no.4
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    • pp.335-342
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    • 1987
  • There were several numbers of studies on chemically strengthening glass. Most of them were strengthened in molten salt bath below transformation range of glass. Apart from them, this study used solution hydration technique by Autoclave. After determining proper concentration of AgNO3 salt solution, experimental condition varied from 4hrs to 16hrs at relatively low temperature (180, 200, 220$^{\circ}C$). The results showed that the Soda-Lime-Silica glass could be strengthened by diffusion mechanism without influence of water above 15% salt solution. Because of Ag+ ion penetration in glass surface, yellow color appeared and decreased transmittance at visible range. Modulus of rupture was increased with the amount of exchange and brittleness was decreased.

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Effect of Ethanolamine Salts and Enhancers on the Percutaneous Absorption of Meloxicam from a Pressure Sensitive Adhesive Matrix

  • Ki, Han-Moe;Cheong, Hyun-Ah;Choi, Hoo-Kyun
    • Journal of Pharmaceutical Investigation
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    • v.37 no.3
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    • pp.173-177
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    • 2007
  • The purpose of this study was to investigate the effect of salt formation on the percutaneous absorption of meloxicam through hairless mouse skin from a pressure sensitive adhesive (PSA) matrix. In addition, the influences of enhancers on the permeation of meloxicam or meloxicam-ethanolamine (MX-EA) salts across the hairless mouse skin were evaluated using a flow-through diffusion cell system. The salt formation of meloxicam resulted in lower permeation rate than the parent drug. $Span^{(R)}$ 80 provided the highest enhancing effect for meloxicam and meloxicam monoethanolamine salt. The maximum amount of the drug that can be loaded without retarding permeation rate was different depending on the compound. No relationship was found between the fluxes of meloxicam or MX-EA salts from saturated solutions and those from PSA matrices containing the same enhancer.

Characteristics of Chloride Penetration due to Sprinkle of the Deicing Salt on the Concrete Pavement (제설제 살포에 따른 콘크리트 포장의 염화물 침투특성)

  • Park, Jin-Ro;Kim, Myung-Yu;Yang, Eun-Ik;Yi, Seong-Tae;Park, Rae-Geun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.475-478
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    • 2005
  • Deicing salt has been generally used for traffic safety in winter, and the amount is increasing every year. However, deicing salt may induce the decrease of bond strength, surface scaling, and environmental pollution, etc. the purpose of this paper is to suggest the fundamental data on safety and durability for concrete structures through the estimation of chloride concentration profile and chloride diffusion coefficient. According to the test results, the critical chloride concentration($0.9\~1.2kg/m^3$)was measured at depth $23\~30mm$, and the limit chloride concentration($0.3kg/m^3$)was reached to depth 40mm. Also the surface chloride amount indicates 3.45kg per concrete unit weight, and the results showed the possibility of corrosion by deicing salt penetration.

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Characteristics on the distribution of salinity of airborne sea salt by height (높이에 따른 비래염분량의 감소 특성)

  • Lee Jong Suk;Choi Won Sung;Kim Do Gyeum;Moon Han Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.261-264
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    • 2005
  • For concrete structures immersed in seawater, the concentration of chloride used to estimate the chloride diffusion coefficient can be defined as the seawater chloride concentration. However, for seashore concrete structures which are not coming into direct contact with seawater, establishing the interface concentration of chloride becomes delicate. In addition, concrete structures are greatly affected by salt attack primarily due to airborne sea salt like it can be seen through the corrosion of rebar. This study intends to investigate characteristics on the salinity of airborne sea salt by height. Salinity measurement devices were installed at height of 2, 10 and 19m on the seashore water tower located in the area of Samchuk in the Eastern coast. Analysis results of the decrease of salinity with respect to the height above the ground at a distance of 30m from the seashore showed that the reduction reached about 40$\%$ at a height of 10m and 60$\%$ at 20m.

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ELECTROREFINING OF INDIUM METAL FROM IMPURE In-Sn ALLOY IN FLUORIDE MOLTEN SALT

  • HYUN-GYU LEE;SANG-HOON CHOI;JAE-JIN SIM;JAE-HONG LIM;SOONG-KEUN HYUN;JONG-HYEON LEE;KYOUNG-TAE PARK
    • Archives of Metallurgy and Materials
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    • v.64 no.3
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    • pp.899-905
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    • 2019
  • In this study, molten salt electrorefining was used to recover indium metal from In-Sn crude metal sourced from indium tin oxide (ITO) scrap. The electrolyte used was a mixture of eutectic LiF-KF salt and InF3 initiator, melted and operated at 700℃. Voltammetric analysis was performed to optimize InF3 content in the electrolyte, and cyclic voltammetry (CV) was used to determine the redox potentials of In metal and the electrolyte. The optimum initiator concentration was 7 wt% of InF3, at which the diffusion coefficients were saturated. The reduction potential was controlled by applying constant current densities of 5, 10, and 15 mA/cm2 using chronopotentiometry (CP) techniques. In metal from the In-Sn crude melt was deposited on the cathode surface and was collected in an alumina crucible.

The Evaluation of Durability by NDT test of Marine-Concrete Structures (항만구조물의 비파괴시험에 의한 안정성 검토)

  • 조병완;이일근;강희풍
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.169-172
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    • 1995
  • Establishment of a diagnosing technology for the deterioration of reinforced concrete structures due to salt contamination is urgent, but few analytical methods based on measured data obtained from concrete structures have been presented so far. Chloride penetration into concrete from sea water is generally understood and analysed as diffusion of chloride ion. This paper presents a new method of predicting chloride penetration into concrete based on diffusion theory. Also, it determines the duralility of Marine structure in service with the prediction of remaiing lifetime by the carvonation test.

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The Formation Rate and Activation Energy of Diffusion Layer and Compound Layer in Ion-Nitriding (이온질화 에 있어 확산층 및 합성층 의 생성속도 및 질소 의 활성화에너지)

  • 성환태;유봉환;조규식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.8 no.5
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    • pp.476-480
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    • 1984
  • This paper deals with nitrogen diffusion velocity and activation energy in diffusion layer and compound layer in ion-nitriding, and presents observations on the effect of deformation according to nitriding methods. During the experiment the activation energy and diffusion velocity of nitrogen have been examined in S45C steel samples. It is found that the results of an investigation correspond with the theoretical data and the ion-nitriding method offers less deformation than conventional salt-bath method of nitriding.

Prediction Model of Absorbed Quantity and Diffusivity of Salf in Radish during Salting (무우의 염절임시 소금의 침투량과 확산도 예측모델)

  • 최용희;권태연
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.6
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    • pp.572-581
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    • 1991
  • For the development of a model to predict absorbed salt quantity in radish during salting, absorbed salt quantity and water content change in radish by the hour were measured at 5%, 10%, 15% brine concentration and $10^{\circ}C,\;20^{\circ}C,\;30^{\circ}C$ respectively. Absorbed salt quantity in radish by the time showed logarithmic function, absorbed salt quantity by brine concentration and temperature showed linear relation. A model to predict absorbed salt quantity in radish at each time, brine concentration and temperature was calculated by the regression program of SPSS. Apparent diffusivity of salt in radish was calculated from appropriated diffusion equation solution of Fick's second law using computer simulation. Salt diffusivity in radish increased as brine concentration increased and the effect of temperature could by expressed by Arrhenius equation. A model equation which could predict salt diffusivity was developed by regression analysis. To specify relation between salt quantity which absorbed into radish and water content which removed out of it, Flux ratio(${\Delta}W/{\Delta}S$) was calcuated. The values showed that the removed water content was greater than the absorbed salt quantity.

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On the Seasonal Transports of Freshwater and Salt in the Tropical Atlantic Ocean (열대 대서양에서의 계절별 담수 및 염분의 수송)

  • Jung-Moon Yoo
    • International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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    • v.22 no.1
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    • pp.1.1-15
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    • 1994
  • The transports of the seasonal freshwater and salt from surface to 500 m depth in the tropical Atlantic Ocean are derived from the equations of the continuity and saltconservation, respectively. The freshwater transport is obtained by southward integration of the divergence of surface freshwater flux, using climatological freshwater(i. e. precipitation, evaporation, and river discharge) data. The annual freshwater transport is northward, ranging from 0 Sv near the equator to 0.3 Sv at $12^{\circ}{\;}N{\;}and{\;}20^{\circ}{\;}S$. The seasonal meridional transport amounts of freshwater range from 1.35 Sv to-0.45 Sv. The strong northward freshwater transports prevail for the intraseasonal period summer to fall. This seasonal cycle is caused by the shifts of the ITCZ as well as the changes in the local freshwater storage. Annual and seasonal salt transports are calculated from objectively analyzed historical (1900-86) salinity observations. The annual salt flux in the ocean zero, showing that the salt flux by horizontal advection balances the flux by horizontal diffusion. The salt flux due to the diffusion is northward, and has a maximum of $5{\;}{\times}{\;}10^6kg/s$ at 15oN. Seasonal transport amounts of salt range from $30{\;}{\times}{\;}10^6kg/s{\;}to{\;}-35{\;}{\times}10^6kg/s$. The direction of the seasonal salt transports is northward except for the intraseasonal period summer to fall.

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Study on the Change of Strength and Water Vapour Diffusion Resistant of Stone by Soluble Salt (수용성 염에 의한 암석의 강도와 수증기확산저항도 변화에 관한 연구)

  • Lim, Kwon-Woong;Do, Jin-Young
    • Journal of Conservation Science
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    • v.25 no.2
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    • pp.147-154
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    • 2009
  • The change of strength and water vapour diffusion resistant by soluble salts was investigated in the tuff and granite used in many stone monuments of Gyeongju area. With $Na_2SO_4$ and $CaSO_4{\cdot}2H_2O$ were treated the rock samples to understand the difference of solubility. The densities of the tested rocks were increased by the impregnation of $CaSO_4{\cdot}2H_2O$ and $Na_2SO_4$. The flexural strength was increased in the tuff samples but decreased in the granite as the salts increased in the pore. In the tuff, the uniaxial compressive strength was increased by $CaSO_4{\cdot}2H_2O$, but decreased by $Na_2SO_4$. In the granite, it was decreased slightly by $CaSO_4{\cdot}2H_2O$, but increased by $Na_2SO_4$. The water vapour diffusion resistant was increased by the salts in both rocks. As results, it was cleared that the mechanical strength colud be increased in early stage of weathering by the accumulation of salt and water vapour diffusion resistant.

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