• Journal of Electrochemical Science and Technology
• /
• v.5 no.3
• /
• pp.82-86
• /
• 2014

This work presents the variation of formic acid oxidation on Pt depending on hydrodynamic condition using a rotating disk electrode. As the rotating speed increases, the oxidation rate of formic acid decreases under voltammetric and chronoamperometric measurements. The coverages of poison formed from formic acid during the chronoamperomertric investigations decrease when the rotating speed increases. As the roughness factor of Pt electrode surface increases, on the other hand, the current density of formic acid oxidation increases. These observations are discussed in terms of the tangential flow along Pt electrode surfaces generated by the rotating disk electrode, which reduces a contact time between formic acid and a Pt site, thus the formic acid adsorption.

• Journal of the Microelectronics and Packaging Society
• /
• v.14 no.3
• /
• pp.65-71
• /
• 2007

For chip-stack package applications, Cu filling characteristics into trench vias of $75{\sim}10\;{\mu}m$ width and 3 mm length were investigated with variations of the electroplating current density and the speed of a rotating disc electrode (RDE). Cu filling characteristics into trench vias were improved with increasing the RDE speed. There was a Nernst relationship between half width of trench vias of Cu filling ratio higher than 95% and the minimum RDE speed, and the half width of trenches with 95% Cu filling ratio was linearly proportional to the reciprocal of root of the minimum RED speed.

• Nuclear Engineering and Technology
• /
• v.32 no.6
• /
• pp.595-604
• /
• 2000

Flow-Accelerated Corrosion Behavior of SA106 Gr.C steel in room temperature alkaline solution simulating the CANDU primary water condition was studied using Rotating Cylinder Electrode. Systems of RCE were set up and electrochemical parameters were applied at various rotating speeds. Corrosion current density decreased up to pH 10.4 then it increased rapidly at higher pH. This is due to the increasing tendency of cathodic and anodic exchange half-cell current. Corrosion potential shifted slightly upward with rotating velocity. Passive film was formed from pH 9.8 by the mechanism of step oxidation and the subsequent precipitation of ferrous species into hydroxyl compound. Above pH 10.4, the film formation process was active and the film became stable. Corrosion current density showed increment in pH 6.98 with the rotating velocity, while it soon saturated from 1000 rpm above pH 9.8. This seems that activation process which represents formation of passive film on the bare metal surface controls the entire corrosion process

• Journal of applied mathematics & informatics
• /
• v.22 no.1_2
• /
• pp.1-20
• /
• 2006

This paper presents the interior penalty discontinuous Galerkin finite element methods (DGFEM) for solving the rotating disk electrode problems in electrochemistry. We present results for the simple E reaction mechanism (convection-diffusion equations), the EC' reaction mechanism (reaction-convection-diffusion equation) and the ECE and $EC_2E$ reaction mechanisms (linear and nonlinear systems of reaction-convection-diffusion equations, respectively). All problems will be in one dimension.

• Bulletin of the Korean Chemical Society
• /
• v.28 no.8
• /
• pp.1322-1328
• /
• 2007

The catalytic activity of poly[(2,2'-bipyridine)copper(II)-μ4-oxalato] coated on a glassy carbon electrode (GCE) for O2 electroreduction is examined using cyclic voltammetry and rotating disk electrode techniques. The cyclic voltammograms show that O2 is electroreduced on pBpCuOx-coated GCE surfaces at a peak potential of ? 0.25 V in pH 4.7 acetate buffer media. The electroreduction of O2 on pBpCuOx-coated GCE occurs at 450 mV more positive potential than that found at a bare GCE. The catalytic activity originates from Cu(II) coordinated by bipyridine in the complexes and the polymer type Cu-complex films exhibit an enhanced stability compared to monomeric Cu-complexes during the O2 electroreduction. The rotating disk electrode measurements reveal that the electroreduction of O2 on pBpCuOx-coated GCE is a four-electron process. Kinetic parameters for O2 reduction on pBpCuOx-coated GCE are obtained from rotating disk experiments and compared with those on bare glassy carbon electrode surfaces.

• Journal of Electrochemical Science and Technology
• /
• v.3 no.4
• /
• pp.165-171
• /
• 2012

An experimental study of mass transfer to an amalgamated copper rotating disc electrode has been employed to determine an empirical correlation for the mass transfer rate in laminar flow. The study was performed in a three-electrodes configuration using 0.1 M boric acid and 0.1M potassium chloride as supporting electrolyte with Zn (II) concentration in the range (25-100 mg $dm^{-3}$). Polarization curves at different zinc ion concentration are reported. Hydrogen and oxygen reduction has also been considered.The diffusion coefficients and mass transfer coefficient were obtained using limiting diffusion current technique based on zinc ion reduction. A least squares analysis indicates that the laminar flow results for 13067 < Re > 57552 and 550 < Sc > 1390 can be correlated by the following equation with correlation coefficient (CR) equal to 0.98: $sh=0.61Re^{0.5}Sc^{1/3}$.

• 한국연소학회:학술대회논문집
• /
• 2006.04a
• /
• pp.144-148
• /
• 2006

Characteristics of a plasma reactor for partial oxidation of methane, especially focused on the role and effectiveness of plasma chemistry, is investigated. Partial oxidation of methane is investigated using a rotating arc which is a three dimensional version of a typical glidingarc. The rotating arc has both the characteristics of equilibrium and non-equilibrium plasma. Non-equilibrium characteristics of the rotating gliding arc can be increased by rotating an elongated arc string attached at both the tip of inner electrode and the edge of outer electrode. In this way, plasma chemistry can be enhanced and hydrogen selectivity can reach almost 100% that is much higher than thermal equilibrium condition. As a result, the present study enables the strategic approach of the plasma reforming process by means of appropriate reactor design to maximize plasma effect and resulting in maximized reaction efficiency.

• Journal of Electrical Engineering and Technology
• /
• v.12 no.5
• /
• pp.2001-2006
• /
• 2017

This paper explains the effects of the weak signal of a rotating-type electric field mill sensor fabricated for measuring the intensity of the electric field generated by high-voltage direct current (HVDC) power transmission lines. The fabricated field mill consists of two isolated electrode vanes, a motor driver, and a ground part. The sensor plate is exposed to and shielded from the electric field by means of a rotary shutter consisting of a motor-driven mechanically complementary rotor/stator pair. When the uncharged sensor plate is exposed to an electric field, it becomes charged. The rotating electrode consists of several conductive vanes and is connected to the ground part, so that it is shielded. Determining the appropriate design variables such as the speed of the vane, its shape, and the distance between the two electrodes, is essential for ensuring optimal performance. By varying the speed, the weak signal characteristics which is used to signal processing and calibration experiment are quite different. Each weak signal pattern was analyzed along with the output voltage characteristics, in order to be able to determine the intensity of the electric field generated by HVDC power transmission lines with accuracy.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2002.05a
• /
• pp.1003-1007
• /
• 2002

Micro-EDM is generally used far machining micro 3-D structure. For micro-EDM, first of all, micro-electrode fabrication is needed and WEDG system is proposed for tool electrode fabrication method. When tool electrode is fabricated using WEDG system, its characteristics are under the control of many EDM parameters. Also relations between the parameters affect electrode fabrication. In this study, experiments are carried out to analyze effects of EDM parameters on micro-electrode fabrication. Experimental method and analysis are used to experimental design method. Factors used in experiments are composed of applied voltage, capacitance, wire feed rate, spindle rotating speed, machining time. As a result of experiments, wire feed rate, machining time and capacitance is proportional to gap distance(material removal), the other parameters(applied voltage, spindle rotating speed) and relations between the parameters have little influence on machining.

• Corrosion Science and Technology
• /
• v.2 no.1
• /
• pp.41-46
• /
• 2003

Flow-Accelerated Corrosion behavior concerning both activation and mass transfer process of SA106 Gr.C steel was studied using rotating cylinder electrode in room temperature alkaline solution by DC and AC electrochemical techniques. Passive film was tanned from pH 9.8 by step oxidation of ferrous product into hydroxyl compound. Corrosion potential shifted slightly upward with rotating velocity through the diffusion of cathodic species. Corrosion current density increased with rotating velocity in pH 6.98, while it soon saturated from 1000 rpm at above pH 9.8. On the other hand the limiting current increased with rotating speed regardless of pH values. It seems that activation process, which represents formation of passive film on the bare metal surface, controls the entire corrosion kinetics