Electrochemical Analysis on Flow-Accelerated Corrosion Behavior of SA106 Gr.C Steel in Alkaline Solution

  • Kim, Jun Hwan (Department of Nuclear Engineering, Korea Advanced institute of Science and Technology) ;
  • Kim, In Sup (Department of Nuclear Engineering, Korea Advanced institute of Science and Technology) ;
  • Chung, Han Sub (Korea Electric Power Research institute)
  • Published : 2003.02.01

Abstract

Flow-Accelerated Corrosion behavior concerning both activation and mass transfer process of SA106 Gr.C steel was studied using rotating cylinder electrode in room temperature alkaline solution by DC and AC electrochemical techniques. Passive film was tanned from pH 9.8 by step oxidation of ferrous product into hydroxyl compound. Corrosion potential shifted slightly upward with rotating velocity through the diffusion of cathodic species. Corrosion current density increased with rotating velocity in pH 6.98, while it soon saturated from 1000 rpm at above pH 9.8. On the other hand the limiting current increased with rotating speed regardless of pH values. It seems that activation process, which represents formation of passive film on the bare metal surface, controls the entire corrosion kinetics

Keywords

Acknowledgement

Supported by : Korea Electric Power Research Institute

References

  1. W. J. Shack, Proc. of the 3rd International Symposium on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors 55 (1988)
  2. V. Shah, and P. E. Macdonald, Aging and Life Extension of Major Light Water Reactor Components 523 (1993)
  3. K. A. Burill, and E. L. Cheluget, ‘Corrosion of CANDU Outlet Feeder Pipes’, JAIF Int'l Conf. On Water Chemistry 699 (1998)
  4. J. H. Kim and I. S. Kim, ‘Environmentally Assisted Crack Growth Behavior of SA508 Cl.3 Pressure Vessel Steel’, Proc. of the KNS Spring Meeting, 154 (1998)
  5. KINS REPORT, No. 756.05
  6. J. Y. Zou, and D. T. Chin, ‘Anodic Behavior of Carbon Steel in Concentrated NaOH Solutions’, Electrochimica Acta, 33(4), 477 (1988)
  7. J. Y. Zou, and D. T. Chin, ‘Mechanism of Steel Corrosion in Concentrated NaOH Solutions’, Electrochimca Acta, 32(12), 1751 (1987)
  8. T. Misawa, ‘The Thermodynamic Consideration for $Fe-H_20$ System at 25 ${\circ}C$, Corr. Sci., 13, 659 (1973)
  9. D. A. JONES, Principles and prevention of Corrosion 357 (1992)
  10. G. Bellanger, ‘Effect of carbonate in slightly alkaline medium on the corrosion of maraging steel’, J of Nucl. Mat., 217, 187 (1994)
  11. Y. J. Kim, C. C. Lin, and R. Phathania, ‘Electrochemical Corrosion Potential Measurement with a Rotating Cylinder Electrode in 288 ${\circ}C$ Water’, Proc. Of the Water Chemistry of Nuclear Reactors System 6, BNES p.139 (1992)
  12. J. G. Kim, ‘A Study on the Flow-Accelerated Corrosion Characteristics of Galvanically Coupled Dissimilar Metals’, 1st Workshop on the Evaluation of Pipe Wall Thinning in Nuclear Power Plants, KINS/PR-012 (2000)
  13. K. Denpo and H. Ogawa, ‘Fluid Flow Effects on $C0_2$ Corrosion Resistance of Oil Well Materials’, Corrosion, 49(6), 442 (1993)
  14. S. W. Dean, ‘Velocity-Accelerated Corrosion Testing and Predictions’, Material Protection, Sept p.61 (1990)
  15. B. Chexal, ‘Flow-Accelerated Corrosion in Power Plant’, EPRI report TR-106611, pp.4-33 (1996)