• Title/Summary/Keyword: alkaline solution

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Eco-friendly Indigo Dyeing using Baker's Yeast: Reducing Power according to Alkaline Solution Type (효모를 사용한 친환경 인디고 염색: 알칼리수용액 종류에 따른 환원력)

  • Son, Kyunghee;Shin, Younsook
    • Textile Coloration and Finishing
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    • v.31 no.4
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    • pp.249-257
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    • 2019
  • Baker's yeast(Saccharomyces cerevisiae) was used as a biocatalyst for eco-friendly indigo dyeing and the reducing power of yeast according to the alkaline solution type was compared. NaOH solution, lye, and buffer solution were used as alkaline solutions. The reducing power(K/S value, oxidation/reduction potential(ORP), pH) was monitored according to the elapsed time including the initiation of reduction, peak reduction, and the end of reduction. In all alkaline solutions, it was confirmed that yeast can be used reducing agent in indigo reduction dyeing. The pH stability and reducing power of buffer solution was better than that of NaOH alone. Although, pH and ORP stability of the reduction bath in lye were better than that of buffer solution, K/S value in buffer solution was higher compared to lye. The reducing power was different depending on the starting pH of the dye bath, and it was better when starting at pH 10.70 than at pH 11.30. Fastnesses to washing, rubbing, and light were relatively good with above rating 4. There was no significant difference in colorfastness depending on the type of alkaline solutions.

Antimicrobial efficacies of alkaline disinfectant solution and commercial disinfectants against Brucella ovis

  • Yoo, Jong-Hyun
    • Korean Journal of Veterinary Service
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    • v.32 no.4
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    • pp.347-351
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    • 2009
  • Bruella spp. involves a considerable danger of public health and farm animal industry. In this study, we assessed the disinfection efficacy of alkaline disinfectant solution and three commercial farm disinfectants (quaternary ammonium compound, sodium dichloroisocyanurate, potassium monopersulphate/sodium dichloroisocyanurate) against Brucella ovis. A bactericidal efficacy test by broth dilution method was used to determine the lowest effective dilution of selected disinfectants following exposure to test bacteria for 30 minutes at $4^{\circ}C$. Disinfectants and test bacteria are diluted with distilled water (DW), hard water (HW) or organic matter suspension (OM) according to treatment condition. Three commercial disinfectant showed excellent antimicrobial activity (up to dilution of $\times200$ in OM treatment). Alkaline disinfectant solution demonstrated favorable bactericidal efficacy against B. abortus (at dilution of $\times20$ in OM treatment). Three commercial farm disinfectants possess excellent efficacy against B. ovis. Alkaline disinfectant solution has lower potency than commercial farm disinfectant but could help to limit the spread of brucellosis.

Weibull Statistical Analysis on the Mechanical Properties of SiC by Immersion in Acidic and Alkaline Solutions (산 및 알칼리 용액에 부식된 SiC의 기계적 특성에 대한 와이블 통계 해석)

  • Ahn, Seok-Hwan;Jeong, Sang-Cheol;Nam, Ki-Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.9
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    • pp.767-773
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    • 2016
  • A Weibull statistical analysis of the mechanical properties of SiC ceramics was carried out by immersion in acidic and alkaline solutions. The heat treatment was carried out at 1373 K. The corrosion of SiC was carried out in acidic and alkaline solutions under KSL1607. The bending strength of corroded crack-healed specimens decreased 47% and 70% compared to those of uncorroded specimens in acidic and alkaline solutions, respectively. The corrosion of SiC ceramics is faster in alkaline solution than in acid solution. The scale and shape parameters were evaluated for the as-received and corroded materials, respectively. The shape parameter of the as-received material corroded in acidic and alkaline solutions was significantly more apparent in the acidic solution. Further, the heat-treated material was large in acidic solution but small in alkaline solution. The shape parameters of the as-received and heat-treated materials were smaller in both acidic and alkaline solutions.

An Analysis on Stainless Steel for Hydrogen Generator' Pipeline Interacting with Alkaline Solution (알칼리 용액이 수소배관으로 사용되는 Stainless steel에 미치는 영향 분석)

  • Byun, Chang-Sub;Choi, Jin-Young;Lim, Soo-Gon;Hwang, Gab-Jin;Choi, Ho-Sang;Shin, Hoon-Kyu
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.3
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    • pp.207-212
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    • 2012
  • This study was performed to observe the change of stainless steel pipe interacting with alkaline solution. We used STS316L and STS304 as samples which were soaked in alkaline solution. We measured the samples by use of FE-SEM, EDX, SIMS to observe the surface and depth profile of both samples. The result showed that the precipitate appeared on the surface of both samples from 5 days. but the precipitate was confirmed to be decreased as time passes. but the quantitative change of precipitates at both samples was different as time passed. The EDX showed that the precipitate is Potassium from solution of Electrolysis. The result also showed that the primary elements of stainless steel pipeline and of Alkaline Solution were changed. The change of primary elements was severe between 5 days to 16 days and was stable around 40 days at both samples. The reaction of STS316L with alkaline solution was lower than STS304. We hoped that this study would be the foundation of developing the electrode of the alkaline hydrogen generator.

Alkaline Hydrolysis of Polyester/Acetate Union Fabric (폴리에스테르/아세테이트 혼용직물의 알칼리 가수분해)

  • Ju, Young Min;Kim, Myung Kyoon;Ahn, Kyoung Ryoul;Lee, Jeong Min
    • Textile Coloration and Finishing
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    • v.8 no.4
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    • pp.42-51
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    • 1996
  • Alkaline hydrolysis to improve the hand of PET/acetate union fabric was studied in relation to skin saponification and retarding effect of salts on the alkaline hydrolysis of cellulose acetate fiber, accelerating effect of salts on the alkaline hydrolysis of PET fiber, and changes of total hand value(T.H.V) of PET/acetate union fabric treated with alkali/salt solution. It was found that the rate of saponification of acetate was delayed by the addition of salts such as LiCl, NaCl and CH$_{3}$COONa into NaOH solution below 10 minutes. The rate of shrinkage of acetate fabric treated with 5g/l NaOH solution at 9$0^{\circ}C$ and 60 minutes showed 20 % but it was decreased 8% by. the addition of 120g/l Concentration of inorganic salts. We could know that the rate of alkaline hydrolysis of filament yarn treated with alkali solution at 9$0^{\circ}C$ and 60 minutes was delayed about 3 % using 2,000T/M of hard twist yarn, especially acetate filament treated with alkali solution at 9$0^{\circ}C$ and 10 minutes was delayed about 10%. T.H.V. of PET/acetate union fabric was increased from 2.77 to 3.04~3.18 by the addition of salts into alkali solution.

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Study on the Durability of GFRP Composites in Alkaline Environment(1) (알칼리 환경에 대한 GFRP 복합재료의 내구성에 관한 연구(1))

  • Moon, Yong-Jae;Park, Chang-Ho;Moon, Chang-Kwon
    • Journal of Ocean Engineering and Technology
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    • v.22 no.1
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    • pp.58-63
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    • 2008
  • The effect of alkaline environmental condition on durability of GFRP composites according to additives was investigated. Additives used were polyvinyl alcohol(PVA), kaolin and alumina powder. Weight gains increased with immersion time in all GFRP composites at $80^{\circ}C$. But weight gain of specimen added PVA did not differ through the wlwle immersion time in both tap water and alkaline solution at 20 and $80^{\circ}C$. Tensile strength decreased with immersion time in all environment conditions. Tensile strength of GFRP composites regardless of additives decreased rapidly up to 5 days of immersion and then decreased slowly up to 30 days in alkaline solution environment at $80^{\circ}C$. Weight gains had not. much difference in both tap water and alkaline solution at $20^{\circ}C$. And weight gain of GFRP composites added polyvinyl alcohol had smaller than the others through the whole immersion time in both tap water and alkaline solution at $20^{\circ}C$ and $80^{\circ}C$. Tensile strength of GFRP composites added polyvinyl alcohol had higher than the others through the whole immersion time in both tap water and alkaline solution at $20^{\circ}C$ and $80^{\circ}C$.

Recovery of Tungsten from WC/Co Hardmetal Sludge by Alkaline Leaching Hydrometallurgy Process (WC/Co 초경합금 가공 슬러지로부터 알칼리침출 정련공정에 의한 W 회수)

  • Lee, Gil-Geun;Kwon, Ji-Eun
    • Journal of Powder Materials
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    • v.23 no.5
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    • pp.372-378
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    • 2016
  • This study focuses on the development of an alkaline leaching hydrometallurgy process for the recovery of tungsten from WC/Co hardmetal sludge, and an examination of the effect of the process parameters on tungsten recovery. The alkaline leaching hydrometallurgy process has four stages, i.e., oxidation of the sludge, leaching of tungsten by NaOH, refinement of the leaching solution, and precipitation of tungsten. The WC/Co hardmetal sludge oxide consists of $WO_3$ and $CoWO_4$. The leaching of tungsten is most affected by the leaching temperature, followed by the NaOH concentration and the leaching time. About 99% of tungsten in the WC/Co hardmetal sludge is leached at temperatures above $90^{\circ}C$ and a NaOH concentration above 15%. For refinement of the leaching solution, pH control of the solution using HCl is more effective than the addition of $Na_2S{\cdot}9H_2O$. The tungsten is precipitated as high-purity $H_2WO_4{\cdot}H_2O$ by pH control using HCl. With decreasing pH of the solution, the tungsten recovery rate increases and then decrease. About 93% of tungsten in the WC/Co hardmetal sludge is recovered by the alkaline leaching hydrometallurgy process.

A Study on the Alkaline Degradation Properties of Silk Fabrics for Costume Heritage Restoration (유물 복원을 위한 실크 직물의 알칼리에 의한 열화 특성 연구)

  • Jeon Cho-Hyun;Kwon Young-Suk;Lee Sang-Joon;Cho Hyun-Hok
    • Textile Coloration and Finishing
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    • v.17 no.4 s.83
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    • pp.41-47
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    • 2005
  • Costume heritages of an excavated silk fabrics should be preserved without damage. In order to artificially restore the excavated silk fabrics, alkaline aqueous solution, as a simulated corpse, and two kinds of silk fabrics were used. Two kinds of silk fabrics were treated by aqueous alkaline solution according to strength retention value(100, 80, 60, 40, 20$\%$). The fine structure and physical properties of alkaline treated silk fabrics were investigated with various techniques such as wide-angle X-ray diffraction, tensile test, weight loss, shrinkage, SEM. and yellowness. As the alkaline treatment time increased tensile strength of silk fabrics decreased. However, weight loss and shrinkage slightly increased. The diffraction intensity of $\beta-form$ crystal declined and $\alpha-form$ crystal diffraction intensity disappeared with the treatment.

Corrosive Wear of Alloy 690 Tubes in Alkaline Water

  • Hong, Seung Mo;Jang, Changheui;Kim, In Sup
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.126-131
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    • 2009
  • The interaction between wear and corrosion can significantly increase total material losses in water chemistry environment. The corrosive wear tests of a PWR steam generator tube material (Alloy 690) against the anti vibration bar material (409 SS) were performed at room temperature. The tests were performed in alkaline water chemistry conditions. NaOH solution was selected for test condition to investigate the corrosive wear effect of steam generator tube material in alkaline pH condition without other factors. The flow induced vibration can caused tube damage and the corrosion can be occurred by water chemistry. The test results showed that, in the alkaline solution at pH 13.9, the corrosion current density was increased about ten times than that in the distilled water. And wear rate at pH 13.9 was increased about ten times from that at neutral condition. However, the wear rate was decreased with time. The decrease would be attributed to the change in roughness of specimen or sub-layer of the worn surface with time. From microstructure observation, severe abrasive shape and several wear debris were found. From those results, it could infer that the oxide film on Alloy 690 changed to easily breakable one in the alkaline water, and then abrasion with corrosion became the main wear mechanism.