• Applied Chemistry for Engineering
• /
• v.9 no.5
• /
• pp.689-697
• /
• 1998

In this work, we studied the equilibrium, rate and rate determining step of uranium adsorption on RGP resins of MR type prepared by varying the degree of crosslinking and the amount of diluent. The equilibrium of uranium adsorption on RGP resins were well explained by Frendrich isotherm as well as Langmuir isotherm model. The amount of adsorption and adsorption rate increase with the adsorption temperature. The heat of the adsorption was 11 kcal/mol. The adsorption rates of uranium on RGP resins were decreased in the order of RGP-10(50)>RGP-1(50)>RGP-2(50)>RGP-5(50)>RGP-0(50) and RGP-2(75)>RGP-2(100)>RGP-2(50)>RGP-2(30)>RGP-2(0). The diffusion resistance of uranium into RGP resin increased as follows; molecular diffusion < pore diffusion < surface diffusion. On the other hand, the surface diffusion was more dominative than the pore diffusion in intraparticle region. Thus, this result indicates that the adsorption mechanism of uranium on RGP resins is intraparticle diffusion controlled.

• Journal of Korean Ophthalmic Optics Society
• /
• v.17 no.4
• /
• pp.373-380
• /
• 2012

Purpose: The present study was performed to investigate a relationship between the stable centrations of spherical RGP lens and aspherical RGP lens on cornea and corneal eccentricity. Methods: Two RGP lenses with different designs were fitted in alignment, steep or flat on total 84 eyes having corneal eccentricity of 0.28~0.78. The stable centration of lenses on cornea was analyzed by taking photographs with a high-speed digital camera. Results: The stable centrations of spherical and aspherical RGP lenses in horizontal direction were decentrated to temporal side. More centration to median side was shown when corneal eccentricity was larger. The difference between the stable centrations of spherical and aspheric RGP lenses according to corneal eccentricity was bigger when the fitting state was flatter. The difference in the stable centrations of aspherical RGP lens was smaller than that of spherical RGP lens regardless of fitting status. The stable centrations of spherical and aspherical RGP lenses in vertical direction were located below corneal apex regardless of fitting status however, there was no significant difference analyzed by the variation of corneal eccentricity. However, there were many cases that RGP lenses were in upper eyelid with increasing corneal eccentricity. Conclusions: The consideration of corneal eccentricity is required for RGP lens fitting and manufacturing aspherical RGP lens since the stable centration of spherical RGP lens as well as aspherical RPG lens' centration was changed depending on corneal eccentricity.

• Applied Chemistry for Engineering
• /
• v.9 no.5
• /
• pp.680-688
• /
• 1998

The macroreticular (MR) type glycidylmethacrylate (GMA)-divinylbenzene (DVB) copolymer (polyglycidylmethacrylate) beads (RG) were prepared by a suspension polymerization using 0~100 vol % of 2,2,4-trimethylpentane (TMP) as a diluent. Macroreticular type cation exchange resins containing phosphoric acid groups (RGP) were prepared by the reaction of GMA-DVB copolymer and poly (glycidyl methacrylate) bead (RG) with phosphoric acid in the presence of benzene. In this study, the effect of degree of crosslinking and the amount of the diluent on physical properties and adsorbability of uranium of RGP resins were investigated respectively. The chemical and physical properties of RGP resins were affected by both of the amount of the diluent and the degree of crosslinking. The effect of degree of crosslinking on the adsorbed amount of uranium for RGP resins were decreased in the order of $$RGP-10(50){\sim_=}RGP-1(50)>RGP-2(50)>RGP-5(50)>RGP-0$$. The effect of the diluent amount were as follows RGP-2(100)>RGP-2(75)>RGP-2(50)>RGP-2(30)>RGP-2(0). The crosslinking degree effect on uranium adsorbability depended on pore structure, cation exchange capability and swelling ratio. On the other hand, the effect of the diluent amount were relied on surface area and pore structure raher than cation exchange capability.

• Journal of Korean Ophthalmic Optics Society
• /
• v.11 no.1
• /
• pp.27-34
• /
• 2006

We investigated the question whether the efficacy of cleaning tear components on RGP lens and preserving the superior wettability of RGP lens depended on the different type of contact lens care system - RGP lens care solution, SCL care solution, combined solution both for SCL and RGP lens or saline solution. The removal efficacy of the deposited protein was examined by Lowry protein assay and Scanning Electro Microscope(SEM) and residual lipid concentration on RGP lens was determined by High Pressure Liquid Chromatology(HPLC). Wettability was assessed with an equilibrium water-in-air contact angle method. When cared by RGP lens solution, it was demonstrated that 62 percent out of the adhered protein on RGP lens were removed and the removal efficacy of RGP lens solution was not only 4 times than saline solution and the alternative but also higher twice than SCL solution. Contrarily, the SCL solution had the most excellent removal efficacy of the adhered protein on SCL. These results suggest that the cleaning efficacy is thought to be affected by the other factors like the viscosity of care solutions, which mutual contact between RGP lens and care solutions is on the increase due to the viscosity enhancer in RGP lens care solution. RGP lens solution had the greatest removing efficacy to cholesterol and the residual cholesterol concentration was decreased to 50%. It is significant for RGP lens to preserve the superior wettability which means the predictive value for comfortable wearing and it showed that the RGP lens solution offered the most excellent efficacy to maintain the surface wettability. Combined solution both for SCL and RGP lens had weak efficacy of cleaning and maintaining wettability for RGP lens compared to RGP lens care solution.

• Journal of Korean Ophthalmic Optics Society
• /
• v.17 no.1
• /
• pp.37-45
• /
• 2012

Purpose: The change of alignment between RGP lens and cornea according to the lens design was investigated by comparing the areas of fluorescein pattern in central and peripheral regions analyzed by astigmatic degree and corneal type when spherical and aspherical RGP lenses fitted in alignment. Methods: The fluorescein patterns of 90 eyes (19-30 years, $25.12{\pm}3.52$) having with-the-rule astigmatism were analyzed after spherical and aspherical RGP lenses fitted in alignment. Then, their fluorescent areas in central and peripheral regions were calculated and compared for the quantitative evaluation. Results: The case showing concordant base curve between spherical and aspherical RGP lenses in alignment fitting was 72% however, the possibility to have same base curves between spherical and aspherical RGP lenses in alignment fitting was to be less in the case of symmetric bowtietyped cornea and high astigmatism. The fluorescent area in peripheral region of aspherical RGP lens in alignment fitting was smaller than it of spherical RGP lens. Peripheral fluorescent areas in both RGP lenses decreased according to the increase of astigmatic degree and peripheral area in symmetric bowtie-typed corea was smaller than round-typed cornea's peripheral area. In the case of same astigmatic degree, peripheral fluorescent area of aspherical RGP lens was smaller in both corneal types. Conclusions: The results above suggest the changing degree in the alignment between RGP lens and cornea can be varied according to lens design, corneal astigmatism and corneal type. Thus, the results obtained from the quantitative analysis of the alignment between lens design and cornea may be used as the basic information about the establishment of guidelines for RGP lens fitting, the development of proper lens design, and different tear volume in partial regions.

• Journal of Korean Ophthalmic Optics Society
• /
• v.12 no.4
• /
• pp.37-41
• /
• 2007

The aim of this study is to establish RGP lens care system using RGP lens multi-purpose solution(MPS) and cleaner. Each RGP lens was incubated in Pseudomonas aeruginosa standard strain, and the numbers of P. aeruginosa colony remaining after treatment by using MPS and/or cleaner including surface activating components were estimated. Soaking only in MPS for 30 min reduced the number of P. aeruginosa up to 50%. 95% of P. aeruginosa was eliminated at RGP lenses soaked in MPS for 4 hr, but P. aeruginosa was not detected at RGP lenses soaked for 6 hr. When only cleaner was used for RGP lens care, 70% of P. aeruginosa was eliminated. This result showed that using cleaner had more effective at removing P. aeruginosa than soaking in MPS for 30 min. When soaking in MPS for 30 min after using cleaner reduced the number of P. aeruginosa up to 36% of that which soaking only in MPS for 30 min. This result suggested that using cleaner could be helpful to improve the disinfection efficacy of short time soaking in MPS.

• Journal of Korean Ophthalmic Optics Society
• /
• v.11 no.1
• /
• pp.71-75
• /
• 2006

The aim of this study was to analyze the surface ultrastructure of RGP contact lenses post-use The RGP contact lenses, to investigate, were selected after one month, six months and one year of wear by the subjects. The anterior and posterior surfaces of these RGP contact lenses were inspected by a scanning electron microscope. The results were the following: 1. After one month of RGP contact lens use the anterior and posterior surfaces appeared clean and clear as originally. 2. After six months the anterior surface had several scars, dips, cracks and scratches. Upon the posterior surface appeared several foreign bodies and microorganisms. 3. After one year there was large scale damage and many foreign bodies were observed. Therefore, extended use of RGP contact lenses has shown increasing physical damage and extensive foreign body accumulation upon the ultrastructure of the lens surface.

• Journal of Korean Ophthalmic Optics Society
• /
• v.20 no.2
• /
• pp.141-150
• /
• 2015

Purpose: In the present study, a difference in tear volume between the cornea and the rigid gas permeable (RGP) lens relative to corneal shape and corneal astigmatism was investigated by the alignment fitting status of spherical and aspherical RGP lenses. Methods: Spherical and aspherical RGP lenses were fitted with alignment in 77 subjects (135 eyes) who were in their 20~30s. Tear volume stained with fluorescein was qualitatively analyzed by dividing cornea into center, mid-peripheral and peripheral parts. Results: For the spherical RGP lens fitting, tear volume differences were found in each part in all corneal types. For the aspherical RGP lens fitting, tear volume differences were in each corneal part in symmetric bow tie- and asymmetric bow tie-type corneas. However, the tear was equally distributed from the center to the peripheral part in round- and oval-type corneas. In the group with corneal astigmatism lower than 1.25 D, tear volume between center and peripheral parts, and mid-peripheral and peripheral parts, was different when a spherical RGP lens was fitted. However, tear volume in each part was not different in the group with corneal astigmatism over 1.50 D. Moreover, the tear volumes of the central and mid-peripheral parts were proportionally increased with increasing corneal astigmatism in both spherical and aspherical RGP lenses. Furthermore, aspherical RGP lenses showed greater increments than spherical RGP lenses. Conclusions: The results revealed that the difference in tear volume between aspherical RGP lens and cornea was less than spherical RGP lens, and the difference in tear volume varied according to corneal shape and astigmatism. In addition, the method of measuring relative tear volume between RGP lens and cornea that was established in the present study can be used to evaluate tear volume between contact lens and cornea.

• Journal of Korean Ophthalmic Optics Society
• /
• v.14 no.1
• /
• pp.31-38
• /
• 2009

Purpose: This study was to evaluate corneal topography, contrast sensitivity and ocular response of a RGP, back surface aspherical contact lens compared with a spherical contact lens. Methods: A total 37 subjects were fitted with a spherical lens in right eye and an aspherical in the left eye and were evaluated for changes in corneal topography and contrast sensitivity over a 2-month period. Results: Thirty-four of 37 subjects completed the 2-month study. The corneal topography did not show differences between spherical and aspherical RGP lenses. The eyes fitted with the aspherical lenses demonstrated a greater reduction in contrast sensitivity compared with their spherical counterparts under photopic condition. Subjects preferred comfort and ocular responses provided by the spherical lens. Conclusions: Corneal topography when comparing spherical and back surface aspherical RGP lenses did not show any significant difference in the subjects. Spherical RGP lens yields better contrast sensitivity and preference than aspherical RGP lens at photopic condition. Further investigation of aberrations induced by contact lens design is warranted to explain the observed differences in visual performance.

• Journal of Korean Ophthalmic Optics Society
• /
• v.12 no.4
• /
• pp.71-76
• /
• 2007

The aim of this study was to investigate level of understanding of symptoms appearing after wearing rigid gas permeable contact lens for optometrists, and if they were educated high about rigid gas permeable contact lens, they could increase the probability of wearing success of rigid gas permeable contact lens as dividing into an adaptative symptoms and an abnormal symptoms. For 96 optometrists a questionnaire about apparatuses, protocol and experience for prescription of rigid gas permeable contact lens and level of understanding of symptoms appearing after wearing rigid gas permeable contact lens was performed. Results showed that level of understanding of rigid gas permeable contact lens was very low, and education was performed for optometrists.