• Korean Journal of Fisheries and Aquatic Sciences
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• v.12 no.3
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• pp.167-173
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• 1979

It is preented the removable moving screen media-activated sludge (REMSMAS) process by using the biological fixed-film systems. The substrate removal kinetic difference between the aeration-only completed mixing activated sludge (CMAS) process and REMSMAS process were observed. The substrate removal kinetics were developed based on the attached and suspended microbial growths. The units of the aeration-only CMAS process were continously operated with the normal detention time of 4.5, 6, 9.5 and 12 flours studies after steady-state condition and the operating of the REMSMAS units conducted with the normal detention time of 6 and 12 hours studies in nonsteady-state condition. The feed solution was diluted 18 times to the raw starch wastewater in of order to maintain the proper COD (950mg/l) and BOD (450mg/l) concentration. Design parameters related to the suspended microbial growths were caculated by the equations used in the aeration-only CMAS model and these parameters used to evalute the kinetic constants in the REMSMAS process. The kinetic constant values of $Y_2,\;K_d,(\mu_{max})_s\;and\;K_s$ from Monod equations were respectively 0.78, 0.027/hr, 1.1/hr and 95mg/l in the aeration-only CMAS process. The value of the aera capacity (F) appeared to be $9.1\;mg/cm^2-day$ and the mean value of the saturation constant $(K_g)$ appeared to be 53.5 mg/l in the REMSMAs process. Also, the substrate removal .ate of the REMSMAS process was higher than that of the normal activated sludge process when this system was operated in steady-state condition. However, the rate was reduced as the critical operating day was approached.

• Journal of Applied Biological Chemistry
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• v.54 no.2
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• pp.79-83
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• 2011

Over-application of nitrogen fertilizer keeps increasing the salinity in the soils of greenhouse in domestic agriculture. In order to remove the excess amounts of soil nitrate, soil microorganisms which have high capacity of nitrate uptake were isolated from the upland soils and their nitrate uptake activities were measured. Strain GS2 was able to remove 50 mM nitrate within 12 h. After sequence comparison analysis of 16S rRNA gene, the strain was identified and named as Bacillus sp. GS2. When the growth and nitrate uptake activities were measured, maximal values were obtained at $30-40^{\circ}C$ and $37^{\circ}C$, respectively; however, both were optimal at pH 6-8. In the media containing 50 mM nitrate, Bacillus sp. GS2 removed 43 mM nitrate which is corresponding to 86% removal. Similar amounts of nitrate removal were observed at the nitrate concentrations up to 300 mM, showing a saturation in nitrate uptake at concentrations above 50 mM. These results imply that Bacillus sp. GS2 can be a good candidate for the microbial remediation of accumulated environmental nitrate because of its excellent growth and nitrate uptake activity.

• Journal of Microbiology and Biotechnology
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• v.27 no.6
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• pp.1138-1149
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• 2017

The use of microalgal biomass is an interesting technology for the removal of heavy metals from aqueous solutions owing to its high metal-binding capacity, but the interactions with bacteria as a strategy for the removal of toxic metals have been poorly studied. The goal of the current research was to investigate the potential of Burkholderia tropica co-immobilized with Chlorella sp. in polyurethane discs for the biosorption of Hg(II) from aqueous solutions and to evaluate the influence of different Hg(II) concentrations (0.041, 1.0, and 10 mg/l) and their exposure to different contact times corresponding to intervals of 1, 2, 4, 8, 16, and 32 h. As expected, microalgal bacterial biomass adhered and grew to form a biofilm on the support. The biosorption data followed pseudo-second-order kinetics, and the adsorption equilibrium was well described by either Langmuir or Freundlich adsorption isotherm, reaching equilibrium from 1 h. In both bacterial and microalgal immobilization systems in the co-immobilization of Chlorella sp. and B. tropica to different concentrations of Hg(II), the kinetics of biosorption of Hg(II) was significantly higher before 60 min of contact time. The highest percentage of biosorption of Hg(II) achieved in the co-immobilization system was 95% at pH 6.4, at 3.6 g of biosorbent, $30{\pm}1^{\circ}C$, and a mercury concentration of 1 mg/l before 60 min of contact time. This study showed that co-immobilization with B. tropica has synergistic effects on biosorption of Hg(II) ions and merits consideration in the design of future strategies for the removal of toxic metals.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.657-662
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• 2005

Iron sulfide(FeS) is significantly produced through both abiotic and biotic processes in natural sediments and pore waters. In this study, chromium(VI) reaction with iron sulfide at various initial concentrations and at pH values of 4 and 8 was conducted to better understand the interactions between Cr(VI) and Fe(II) species dissolved from iron sulfide in both the aqueous and solid phases. Also, the removal efficiency of iron sulfide was compared with zero valent iron and other iron bearing oxides such as ${\alpha}-Fe_2O_3$, ${\alpha}-FeOOH$ and $Fe_3O_4$. The Cr(VI) removal rate by iron sulfide was higher at pH 4 than at pH 8 because more dissolved Fe(II) existed at pH 4 than at pH 8. Chromium and iron(oxyhydroxide) could be identified on the iron sulfide surface with transmission microscopy imaging and energy dispersive spectroscopy. The removal capacity of iron sulfide was much higher than zero valent iron and other iron oxide minerals due to the synergic effect of hydrogen sulfide and ferrous iron.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.7
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• pp.714-721
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• 2010

This research was undertaken to evaluate the feasibility of lanthanum hydroxide for fluoride removal from aqueous solutions. A batch sorption experiments were conducted to study the influence of various factors such as pH, contact time, initial fluoride concentration and temperature on the sorption of fluoride on lanthanum hydroxide. The optimum fluoride removal was observed in the $pH_{eq}{\leq}8.8$. Sorption equilibrium of fluoride on lanthanum hydroxide was better described by the Freundlish isotherm model than by the Langmuir isotherm model. The adsorption energy obtained from D-R model was 9.21 kJ/mol indicating an ion-exchange process as primary adsorption mechanism. The pseudo-second-order kinetic model described well the experimental kinetic data. Thermodynamic parameters such as ${\Delta}Go^{\circ}$, ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ indicated that the nature of fluoride sorption is spontaneous and endothermic. The used lanthanum hydroxide could be regenerated by washing with NaOH solution. Also, the results applied to real ground water indicate that fluoride selectivity and removal capacity of lanthanum hydroxide were superior to those of PA anion-exchange resin.

• Journal of the Korean Wood Science and Technology
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• v.42 no.4
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• pp.450-459
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• 2014

Crushed pinewood and oakwood were studied as an adsorbent for Pb(II) removal from aqueous solution. Batch adsorption experiments were carried out to describe the effects of contact time, initial Pb(II) concentration, pH, competing cations, and adsorbent dosage on the Pb(II) adsorption process. Kinetic studies revealed that the Pb(II) adsorption process for pinewood and oakwood followed both pseudo first and pseudo second order model. The Fruendlich model best described equilibrium adsorption data with correlation coefficients ($R^2$) of 0.956 and 0.950 for pinewood and oakwood. The maximum adsorption capacity of Pb(II) onto pinewood and oakwood was found to be 16.853 and 27.989 mg/g, respectively. The Pb(II) adsorption onto both pinewood and oakwood was increased as pH increased in the pH range 3-9. The presence of cations such as $Na^+$, $Ca^{2+}$, and $Al^{3+}$ decreased Pb(II) adsorption. The Pb(II) removal was greater in seawater than deionized water, resulting from the presence of $CO{_3}^{2-}$ and $OH^-$ ions in seawater. This study showed that pinewood and oakwood have a potential application in the remediation of Pb(II) contaminated water.

• Membrane Journal
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• v.20 no.2
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• pp.142-150
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• 2010

A series of anion exchange composite membranes were prepared and characterized for electrodialysis processes used in the removal of nitrate nitrogen and ions in groundwater. The membranes were prepared as follows; first, fabric substrates were fully impregnated with monomer mixtures of vinylbenzylchloride (VBC), divinylbenzene (DVB), Styrene (ST) and $\alpha,\alpha$-Azobis(isobutyronitrile) (AIBN). Second, they were thermally polymerized to yield crosslinked poly (VBCST- DVB)/fabric composite membranes. Finally, the membranes were treated with trimethylamine (TMA) / acetone to give $-N^+(CH_3)_3^-$-containing poly(VBC-ST-DVB)/fabric membranes. The basic membrane properties such as ion exchange capacity (IEC), electric resistance and water content of the resulting membranes were measured as a function of VBC/DVB and TMA/Acetone content. As a result, the composite membranes showed lower electric resistance and higher IEC than commercial anion exchange membranes (AMX, Astom). Electrodialysis tests using the prepared membranes were carried out for the removal of various ions such as $NaNO_3$, $MgSO_4$ and NaF for 60 minutes. The results showed that the ions were removed below 1 mg/L within about 15 minutes which indicates that the anion exchange membranes prepared here could be applied to the electrodialysis process. as can be seen in the following that the ion conductivity values were almost no change after 15 minutes electrodialysis.

• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.537-542
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• 1999

Removal of sulfur compounds in the petroleum products is essential for the prevention of sulfur oxides. However, conventional methods involving catalytic reactions are found to have some limitations in complete removal of harmful sulfur compounds and to require relatively high cost. Recently, desulfurization process using microorganisms is known to be promising in terms of excellent sulfur removal efficiency and reasonably low treatment cost. For the biodesulfurization process to be effective, the solubilization of sulfur compounds into aqueous solution is a prerequisite. In this study, polyoxyethylene nonionic surfactants were used in order to enhance the solubilization of sulfur spectrophotometer. The solubilization of sulfur compounds was found to increase with temperature and to bo abruptly increased at above 1 wt % surfactant solutions. It was also observed that the longer the hydrophobic chain of the surfactant molecule, the higher solubilizing power of a nonionic surfactant. It was found that the Tergitol series surfactants showed higher solubilizing capacity than Neodol series presumably due to the disruption of the regular packing in the hydrocarbon region of the surfactant aggregates.

• Korean Journal of Environmental Agriculture
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• v.28 no.1
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• pp.69-74
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• 2009

In Korea, large amounts of chestnut shell as by-products are produced from food industries. However, most of the by-products exist with no disposal options. Biosorption uses biomass that are either abundant or wastes from industrial operations to remove toxic metals from water. Objective of this research was to evaluate the feasibility of using chestnut shell as by-products for removal of metal ions(Pb, Cu and Cd) from aqueous solution. The chestnut shell was tested for its efficiency for metal removal by adopting batch-type adsorption experiments. The adsorption selectivity of chestnut shell for metals was Pb > Cu > Cd at solution pH 5.5. The Langmuir isotherm adequately described the adsorption of chestnut shell for each metal. Using The maximum adsorption capacity predicted using Langmuir equation was 31.25 mg $g^{-1}$ 7.87 mg $g^{-1}$ and 6.85 mg $g^{-1}$ for Pb, Cu and Cd, respectively. Surface morphology, functional group and existence of metals on chestnut shell surface was confirmed by FT-IR, SEM and EDX analysis. The chestnut shell showed an outstanding removal capability for Pb compared to various adsorbents reported in the literatures. The overall results suggested that chestnut shell might can be used for biosorption of Pb from industrial wastewater.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.1 no.1
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• pp.65-72
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• 2003

Adsorption and desorption characteristics of methyl iodide at high temperature conditions up to 25$0^{\circ}C$ by TEDA-impregnated activated carbon and silver-ion exchanged zeolite(AgX-10), which are used for radioiodine retention in nuclear facility, were experimentally evaluated. In the range of temperature from 3$0^{\circ}C$ to 25$0^{\circ}C$, the adsorption capacity of base activated carbon decreased sharply with increasing temperature but that of TEDA-impregnated activated carbon showed higher value even at high temperature ranges. Especially, the residual amount of methyl iodide after desorption on TEDA-AC represented 30% lower value than that on AgX-10. However, it can be used as an adsorbent for the removal of methyl iodide up to 15$0^{\circ}C$ if it is preventing explosion by Ignition. The breakthrough curves of methyl iodide in the fixed bed packed with AgX-10 uP to 40$0^{\circ}C$ were compared upon the effects of bed temperatures, bed depth and input concentration of methyl iodide. Removal mechanism of methyl iodide on AgX-10 was proposed, based on the analysis of by-product gas generated from adsorption reaction.