• 제목/요약/키워드: Red-shift

검색결과 294건 처리시간 0.034초

자연 성장된 InAs/AlAs 양자점의 Photoreflectance 특성 (Self-Assembled InAs/AlAs Quantum Dots Characterization Using Photoreflectance Spectroscopy)

  • 김기홍;심준형;배인호
    • 한국진공학회지
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    • 제18권3호
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    • pp.208-212
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    • 2009
  • MBE법으로 성장된 InAs/AlAs 양자점(quantum dots; QD) 구조의 광학적 특성을 photoreflectance(PR) 이용하여 조사하였다. Wetting layer(WL) 두께에 따른 전체 장벽의 폭이 달라짐에 따라 GaAs 완충층 및 WL 신호의 세기가 변화되었다. QD 층이 식각된 시료의 상온 PR측정 결과로부터 $1.1{\sim}1.4\;eV$ 영역의 완만한 신호는 InAs QDs과 WL에 관련된 신호임을 알았다. 온도 $450{\sim}750^{\circ}C$범위에서 열처리 시켰을 때 WL층의 PR 신호가 red shift하였는데, 이는 열처리 후 InAs WL와 AlAs층 사이에 Al과 In의 내부 확산에 의해 양자점의 크기가 균일하게 재분포 되고, WL의 임계 두께가 증가하였음을 나타낸다.

다중 피리딘 구조를 가지는 형광염료의 금속 이온 반응성에 대한 연구 (Selective Metal Ion Sensing of Bipyridine-Bisterpyridine containing Fluorescent Dyes)

  • 조혜진;김아롱;정수연;박종승
    • 한국염색가공학회지
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    • 제25권4호
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    • pp.254-261
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    • 2013
  • In this study, we synthesized a new fluorescent polypyridyl dye 2 containing a 2,2'-bipyridine in the center and two 2,2':6',2"-terpyridines at both ends. When exposed to various metal ions, the dye 2 showed selective fluorescence responses. In the presence of $Cu^{2+}$ and $Ni^{2+}$, it exhibited a highly effective fluorescence quenching, leading to large $K_{sv}$ values of up to $10^5$. In response to most other metal ions including $Al^{3+}$, in contrast, its fluorescence changes little, showing a small Ksv value at $10^2$. Meanwhile, the compound 2 revealed a differentiated fluorescence response to $Zn^{2+}$, which is evidenced by a large red shift of > 100 nm. Such a red shift from the ion binding is attributed to the planarization of the bipyridyl unit extending the effective conjugation length in conjunction. A polypyridyl compound will find important usefulness in chemosensor application due to its selective binding to metal ions. Subsequent research concerned with modified derivatives is currently going on, as a way to provide high solubility even after metal-complexing.

주거용 13.5W COB LED 다운라이트 방열판 설계에 따른 열적 특성 분석 (Thermal Characteristics of the design on Residential 13.5W COB LED Down Light Heat Sink)

  • 권재현;이준명;김효준;강은영;박건준
    • 한국정보전자통신기술학회논문지
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    • 제7권1호
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    • pp.20-25
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    • 2014
  • 차세대 친환경 조명인 LED소자는 온도가 올라갈수록 LED의 발광효율이 떨어지고 $80^{\circ}C$이상 올라갈수록 수명이 감소하고 스펙트럼선의 파장이 본래의 파장보다 장파장 쪽으로 이동하는 Red Shift현상 및 $T_j$ 상승에 따라 광 출력이 감소되는 큰 문제점이 대두되고 있어 열을 최소화 할 수 있는 방열설계 연구가 진행 중이다. COB Type LED의 경우 보드에 LED 칩을 직접 결합시켜 열 저항을 낮췄지만 주거용 13.5W의 경우 방열판을 통해 발열 문제를 해결해야한다. 본 논문에서는 주거용 13.5W COB LED 다운라이트에 맞게 Heat Sink를 설계하고, 그 설계한 Heat Sink와 13.5W COB를 패키징하여 Solidworks flow simulation을 통해 최적의 Fin두께를 선정하여 접촉식 온도계를 사용한 열적 특성을 분석 하고 평가 하였다.

The Spitzer First Look survey Verification Field : Deep Radio and multi-wavelength properties

  • 김기훈;김성은;;김한성;김연화
    • 천문학회보
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    • 제37권2호
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    • pp.74.1-74.1
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    • 2012
  • We observed the radio sources found from the First Look Survey (FLS) field at the 1.4 GHz radio continuum emission with the Very Large Array (VLA) using the A configuration. We identify point sources and multi component sources at ${\geq}4{\sigma}$ level. We also present the submillimeter properties of the selected radio sources in the FLS field from the Herschel/SPIRE 250/350/500/${\mu}m$ and AzTEC 1.1mm surveys. The counterparts of the radio sources at submillimeter for these called 'submillimeter galaxies (SMGs)' are detected at infrared wavelength with the Spitzer MIPS 24 & 70 ${\mu}m$ sources. Based on the MMT/HECTOSPEC red-shift survey, IRS spectroscopy, and SDSS photometric red-shift survey, the radio sources are likely to be the extragalactic sources. Here, we use the star formation rate (SFR) derived from the MIPS 24 and 70 ${\mu}m$ luminosity to compare the measured SFR from the VLA 1.4 GHz luminosity. These results show that a tight correlation between the SFR from the radio luminosity and the MIPS $24{\mu}m$ rather than that from the MIPS $70{\mu}m$ luminosity. Radio and IR correlation is also used to indicate the radio and IR properties of star-formation in the galaxies and active galactic nuclei (AGNs). Using the counterpart sources selected at IR and radio wavelengths, we employ the IR/radio flux ratios to determine the properties and population of the selected galaxies.

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HVPE법을 이용하여 PSS와 AlN Buffered PSS 위에 성장시킨 GaN 박막의 결정 특성 (Crystalline Properties of GaN Layers Grown on PSS and AlN Buffered PSS by HVPE Method)

  • 이원준;박미선;이원재;김일수;최영준;이혜용
    • 한국전기전자재료학회논문지
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    • 제31권6호
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    • pp.386-391
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    • 2018
  • An epitaxial GaN layer was grown on a cone-shape-patterned sapphire substrate (PSS) (Sample A) and an AlN-buffered PSS (Sample B) with two growth steps under the same process conditions by employing the hydride vapor phase epitaxy (HVPE) method. We have investigated the characteristics of the GaN layer grown on two kinds of substrates at each growth step. The cross-sectional SEM image of the GaN layer grown on the two types of substrates showed growth states of GaN layers formed during the 1st and 2nd growth steps with different growth durations. Dislocation density was obtained by calculation using the FWHM value of the rocking curve for (002) and (102). Sample A showed 2.62+08E and 6.66+08E and sample B exhibited 5.74+07E and 1.65+08E for two different planes. The red shift was observed is photoluminescence (PL) analysis and Raman spectroscopy results. GaN layers grown on AlN-buffered PSS exhibited better optical and crystallographic properties than GaN layers grown on PSS.

아이오노머 필름에 흡수된 비이온계 염료의 분자간 상호작용에 관한 연구 (Molecular Interactions of Soaked Nonionic Dye in Ionomer Films)

  • 이상흠;이원선;이상준;김성수;김인선;송기국
    • 폴리머
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    • 제25권5호
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    • pp.671-678
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    • 2001
  • Sodium 또는 zinc로 중화된 poly(ethylene-co-methacrylic acid)의 아이오노머는 ethylene 사슬 부분들로만 이루어진 결정상, acid 그룹이 존재하는 amorphous 영역, 그리고 ionic aggregate의 세 가지 상으로 나누어진다. Soaking에 의하여 흡수된 nonionic dye 분자들은 결정상을 제외한 amorphous 부분이나 ionic aggregate 분근에 존재하는데, 주위 사슬의 극성에 따라 dispersion force (ethylene 사슬 부분), polar force (acid 부분), ionic dipole (ionic aggregate 부분)의 세 가지 다른 힘의 영향 아래 놓이게 된다. 극성이 적은 ethylene 사슬부분의 dispersion force 영향 아래에 존재하는 Nile Red의 UV/Vis 흡수피크는 500nm 부근에서, polar한 acid 그룹의 영향을 받는 dye 피크는 525 nm, 그리고 ionic aggregate의 영향에 의한 dye는 Na+-아이오노머의 경우 550 nm, divalent이어서 더 큰 ionic dipole을 가지는 $Zn^{2+}$-아이오노머의 경우 610nm에서 각각 피크가 나타났다.

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교수학습방법에 따른 3개 간호대학생의 비판적 사고성향과 임상수행능력 (Critical Disposition and Clinical Competency in 3 Nursing Colleges with Different Education Methods)

  • 양선희;이옥철;이우숙;윤진;박창승;이숙정
    • 한국간호교육학회지
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    • 제15권2호
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    • pp.149-158
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    • 2009
  • Purpose: This study investigated critical thinking disposition and clinical competency of senior nursing students in 3 nursing colleges whose education methods were different; lecture based education, partially problem based learning (PBL) applied education or whole problem based learning applied education. Method: Participants were 399 diploma nursing students, and 92 undergraduate nursing students. The instruments used for this study were critical thinking disposition scales and clinical competency scales. Results: There was no statistical difference on critical thinking disposition except healthy skepticism between the 3 colleges. Clinical competency of the lecture based college was the highest. A significant positive correlation between critical thinking disposition and clinical competency were found in students whose scores of critical thinking disposition were greater than the median. Conclusion: This finding indicates that there is a need for further research on diverse nursing students who are studying by a various methods, prior to acceptance of a paradigm shift in nursing education from conventional lecture based methods to PBL applied methods.

Expression Patterns of Growth Related Genes in Juvenile Red Spotted Grouper (Epinephelus akaara) with Different Growth Performance after Size Grading

  • Mun, Seong Hee;You, Jin Ho;Oh, Hyeon Ji;Lee, Chi Hoon;Baek, Hea Ja;Lee, Young-Don;Kwon, Joon Yeong
    • 한국발생생물학회지:발생과생식
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    • 제23권1호
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    • pp.35-42
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    • 2019
  • Fish shows great difference in growth rate between individuals during larval development and early growth. This difference seriously reduces the production efficiency in fish culture. Growth hormone (GH)/Insulin-like growth factor 1 (IGF1) system is said to play some pivotal roles in fish growth. In this study, we investigated differences of GH, IGF1 and GHR gene expressions in juvenile red spotted grouper (Epinephelus akaara) with different growth performance. Red spotted groupers were reared under the same environmental condition (water temperature $24{\pm}1^{\circ}C$, natural light) for 96 days after hatching. They were divided into 3 groups by size (fast growing, middle growing and slow growing groups: FGG, MGG, and SGG, respectively). RNA was extracted from the brain, liver and muscle tissues from each group, and target gene expression was examined by real-time PCR. In the brain with pituitary gland, expression of GH gene in FGG was significantly higher than the expression in SGG, but the expression of IGF1 and GHR genes in the muscle was highest in SGG. Difference of GHR and IGF1 mRNA in the liver between groups with different growth performance was less clear than that in other tissues, although level of IGF1 mRNA was higher in SGG than in MGG. These results suggest that hormonal governing of growth is not the same in fast growing and slow growing fish, and size grading could cause a shift of hormonal state and growth pattern in this species.

Long-term administration of red ginseng non-saponin fraction rescues the loss of skeletal muscle mass and strength associated with aging in mice

  • Cho, Da-Eun;Choi, Gwang-Muk;Lee, Yong-Seok;Hong, Joon-Pyo;Yeom, Mijung;Lee, Bombi;Hahm, Dae-Hyun
    • Journal of Ginseng Research
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    • 제46권5호
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    • pp.657-665
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    • 2022
  • Background: Sarcopenia is a new and emerging risk factor aggravating the quality of life of elderly population. Because Korean Red Ginseng (RG) is known to have a great effect on relieving fatigue and enhancing physical performance, it is invaluable to examine its potential as an anti-sarcopenic drug. Methods: Anti-sarcopenic effect of non-saponin fraction of Korean Red Ginseng (RGNS) was evaluated in C2C12 myoblasts treated with C2-ceramide to induce senescence phenotypes, and 22-month-old mice fed with chow diet containing 2% RGNS (w/w) for 4 further months. Results: The RGNS treatment significantly alleviated cellular senescence indicated by intracellular lipid accumulation, increased amount of lysosomal β-galactosidase, and reduced proliferative capacity in C2C12 myoblasts. This effect was not observed with saponin fraction. In an aged mouse, the 4-month-RGNS diet significantly improved aging-associated loss of muscle mass and strength, assessed by the weights of hindlimb skeletal muscles such as tibialis anterior (TA), extensor digitorum longus (EDL), gastrocnemius (GN) and soleus (SOL), and the cross-sectional area (CSA) of SOL muscle, and the behaviors in grip strength and hanging wire tests, respectively. During the same period, an aging-associated shift of fast-to slow-twitch muscle in SOL muscle was also retarded by the RGNS treatment. Conclusions: These findings suggested that the long-term diet of RGNS significantly prevented aging-associated muscle atrophy and reduced physical performance, and thus RGNS has a strong potential to be developed as a drug that prevents or improves sarcopenia.

LuxR-Type SCO6993 Negatively Regulates Antibiotic Production at the Transcriptional Stage by Binding to Promoters of Pathway-Specific Regulatory Genes in Streptomyces coelicolor

  • Tsevelkhoroloo, Maral;Li, Xiaoqiang;Jin, Xue-Mei;Shin, Jung-Ho;Lee, Chang-Ro;Kang, Yup;Hong, Soon-Kwang
    • Journal of Microbiology and Biotechnology
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    • 제32권9호
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    • pp.1134-1145
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    • 2022
  • SCO6993 (606 amino acids) in Streptomyces coelicolor belongs to the large ATP-binding regulators of the LuxR family regulators having one DNA-binding motif. Our previous findings predicted that SCO6993 may suppress the production of pigmented antibiotics, actinorhodin, and undecylprodigiosin, in S. coelicolor, resulting in the characterization of its properties at the molecular level. SCO6993-disruptant, S. coelicolor ΔSCO6993 produced excess pigments in R2YE plates as early as the third day of culture and showed 9.0-fold and 1.8-fold increased production of actinorhodin and undecylprodigiosin in R2YE broth, respectively, compared with that by the wild strain and S. coelicolor ΔSCO6993/SCO6993+. Real-time polymerase chain reaction analysis showed that the transcription of actA and actII-ORF4 in the actinorhodin biosynthetic gene cluster and that of redD and redQ in the undecylprodigiosin biosynthetic gene cluster were significantly increased by SCO6993-disruptant. Electrophoretic mobility shift assay and DNase footprinting analysis confirmed that SCO6993 protein could bind only to the promoters of pathway-specific transcriptional activator genes, actII-ORF4 and redD, and a specific palindromic sequence is essential for SCO6993 binding. Moreover, SCO6993 bound to two palindromic sequences on its promoter region. These results indicate that SCO6993 suppresses the expression of other biosynthetic genes in the cluster by repressing the transcription of actII-ORF4 and redD and consequently negatively regulating antibiotic production.