• 제목/요약/키워드: Red-mud

검색결과 159건 처리시간 0.033초

Strength properties of composite clay balls containing additives from industry wastes as new filter media in water treatment

  • Rajapakse, J.P.;Gallage, C.;Dareeju, B.;Madabhushi, G.;Fenner, R.
    • Geomechanics and Engineering
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    • 제8권6호
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    • pp.859-872
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    • 2015
  • Pebble matrix filtration (PMF) is a water treatment technology that can remove suspended solids in highly turbid surface water during heavy storms. PMF typically uses sand and natural pebbles as filter media. Hand-made clay pebbles (balls) can be used as alternatives to natural pebbles in PMF treatment plants, where natural pebbles are not readily available. Since the high turbidity is a seasonal problem that occurs during heavy rains, the use of newly developed composite clay balls instead of pure clay balls have the advantage of removing other pollutants such as natural organic matter (NOM) during other times. Only the strength properties of composite clay balls are described here as the pollutant removal is beyond the scope of this paper. These new composite clay balls must be able to withstand dead and live loads under dry and saturated conditions in a filter assembly. Absence of a standard ball preparation process and expected strength properties of composite clay balls were the main reasons behind the present study. Five different raw materials from industry wastes: Red Mud (RM), Water Treatment Alum Sludge (S), Shredded Paper (SP), Saw Dust (SD), and Sugar Mulch (SM) were added to common clay brick mix (BM) in different proportions. In an effort to minimize costs, in this study clay balls were fired to $1100^{\circ}C$ at a local brick factory together with their bricks. A comprehensive experimental program was performed to evaluate crushing strength of composite hand-made clay balls, using uniaxial compression test to establish the best material combination on the basis of strength properties for designing sustainable filter media for water treatment plants. Performance at both construction and operating stages were considered by analyzing both strength properties under fully dry conditions and strength degradation after saturation in a water bath. The BM-75% as the main component produced optimum combination in terms of workability and strength. With the material combination of BM-75% and additives-25%, the use of Red Mud and water treatment sludge as additives produced the highest and lowest strength of composite clay balls, with a failure load of 5.4 kN and 1.4 kN respectively. However, this lower value of 1.4 kN is much higher than the effective load on each clay ball of 0.04 kN in a typical filter assembly (safety factor of 35), therefore, can still be used as a suitable filter material for enhanced pollutant removal.

비소로 오염된 달천광산 토양의 자연저감 능력에 대한 pH-Eh영향 (Effects of pH-Eh on Natural Attenuation of Soil Contaminated by Arsenic in the Dalchen Mine Area, Ulsan, Korea)

  • 박맹언;성규열;이민희;이평구;김민철
    • 자원환경지질
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    • 제38권5호
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    • pp.513-523
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    • 2005
  • 울산 달천광산의 지하수 및 토양 중에 함유되어 있는 비소의 오염현황을 파악하고, pH와 산화-환원 전위 값의 변화에 따른 자연저감 능력을 평가하였다. 달천광산 지역 비소 오염의 주 근원광물인 유비철석의 광미 내 함량은 최대 $2\%$이며, 비독사석, 니콜라이트, 램멜스버가이트, 거스도르파이트, 코발트석과 황철석 등의 비소함유광물 역시 비소오염의 근원이 되고 있으며, 비소함량은 광물에 따라 다양한 차이를 보인다 광미장 내 유비철석과 황철석의 표면이 부분적으로 철산화물과 철비산염으로 산화된 것을 관찰할 수 있어, 풍화반응이 상당히 진행되었음을 알 수 있다. 지하수 내 비소의 함량과 pH는 뚜렷한 상관관계를 보이지 않지만, 포화대 및 비포화대의 지하수의 비소 농도는 Eh가 감소함에 따라 농도가 감소하는 정(+)의 상관관계를 보인다. RMB(Red Mud Bauxite)는 비소제거 효율이 우수하여 달천광산 지역의 비소로 오염된 지하수 및 토양을 복원 시 자연저감 촉진제로 이용될 수 있을 것이다.

성공적인 학습의 역할수행을 위한 의복의 적합성에 관한 연구 -교사/교수의 의복행동을 중심으로- (A Study on the Clothing Appropriateness for the Role Behavior af Achieving a Successful Learning and Teaching Efficiency)

  • 한명숙
    • 대한가정학회지
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    • 제25권2호
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    • pp.39-54
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    • 1987
  • One's Clothing Satisfaction, has a great influence on his role behavior in a society. Especially, as for the teacher's and the professors whose role is teaching, it can not be too emphaszed. Above all, high school girls and college women are the most likely to be influenced by their teachers' clothing behavior, to whom they pay their respect in every way. From this point of view, this study was aimed at explaining, the correlation between the teachers/professors' clothing behaviors and the learning efficiency. On clothing behaviors assessed 30 items related with the learning efficiency, selected from the instruments of preceding studies, and modified by the factors dealing with modesty, color, and design. The questionnaires were composed of two major categories: those for students and for teachers/progessors. The subjects of this study were included students and teachers/professors of high school and universities in Seoul. The data were analyzed statically by mean, standard Deviation, and F-test. The results of this study were summerized as follows; 1. The clothing behaviors of the teachers/professors influenced on the learning efficiency. Namely teachers' clothing satisfaction is in direct proportion to them teaching efficiency and students' learning efficiency. 2. Among the clothing behavior variables, modesty had a great influence on the learning efficiency, especially as for that of teachers more than professors. 3. The influence of the teachers'/professors' clothing behaviors on the learning efficiency showed no significance between high school girls and college women, but some significance between the grades of collegians. 4. As for the teachers'/professors' clothing behavior, male teachers/professors gave priority to design and female teachers/professors to modesty, color showed no significance between them irrespective of age. 5. As for the clothing behavior variabels, both the teachers/professors and the students showed some significance. In class the teachers/professors highly responded to their own clothing behaviors than the students. 6. According to priority the most favorable clothing colors for male teachers/professors are navy blue, gray, indigo blue, and black, and the most disgusting ones red, mud yellow, violet, pink, and green. The most favorable clothing colors for female teachers/professors are beign, white, pale yellow, and black, and the most disgusting ones red, mud yellow, and yellow and yellow according to priority. It is that teachers/professors should wear modestly and in color harmony to invite the desirable students' will to study. Teachers'/professors' colorful appearance and heavy toilet bring about a drop in the students' will to study.

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베이어법으로 합성된 Al(OH)3에 함유된 미량 Na 성분의 제거 (Removal of Sodium Contained in Al(OH)3 Synthesized by Bayer Process)

  • 최희영;김도형;박노국;이태진;강미숙;이원근;김헌덕;박준우
    • 청정기술
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    • 제18권1호
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    • pp.63-68
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    • 2012
  • 본 연구에서는 베이어공정에 의해서 수산화알루미늄($Al(OH)_3$)을 합성하였으며, 고순도 알루미나를 합성하기 위하여 염산 및 초산과 같은 산성용액을 사용하여 $Al(OH)_3$에 함유된 나트륨을 제거하였다. 호주의 퀸즐랜드 주에서 생산된 보크사이트가 베이어공정에 의해 알루미나를 합성하기 위해 사용되었으며, 보크사이트는 attrition mill을 이용하여 10 ${\mu}m$ 이하의 분말로 분쇄하여 사용되었다. 보크사이트에 함유된 알루미나 성분을 용출하기 위하여 분쇄된 보크사이트를 5 N의 NaOH 수용액으로 처리하였으며, 고압반응기 내에서 보크사이트로부터 알루미나의 용출은 $140^{\circ}C$, 3.4 atm에서 수행되었다. 용출 후 고체시료인 레드 머드는 여과에 의해서 액체시료와 분리되었다. 보크사이트와 여과된 레드 머드에 함유된 알루미늄 함량과 구조변화를 XRD와 EDX로 분석하였다. 또한 분리된 용액에 함유된 알루미나는 씨드 물질로 사용된 $Al(OH)_3$의 첨가에 위해서 $Al(OH)_3$로 결정화되었다. 결정화 과정에서 얻어진 $Al(OH)_3$는 증류수에 의해서 수차례 수세과정으로 정제되었다. 또한 산성 용액에 의해서 $Al(OH)_3$에 함유된 나트륨이 제거되는 것을 확인되었다. $Al(OH)_3$ 분말의 순도는 물에 의한 세정으로 99.3%로 생산되었고, 산 처리에 의해서 나트륨의 함량은 약 0.009% 정도로 감소되었다.

대가야 고아동 고분벽화 제작기술에 관한 연구 (Study on the Manufacturing Technology of Mural Tomb in Goa-dong of Daegaya Period)

  • 이화수;이한형;이경민;한경순
    • 보존과학회지
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    • 제30권4호
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    • pp.457-466
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    • 2014
  • 고대 대가야시대(6세기) 고분벽화에 사용된 제작기술을 연구하기 위해 벽화 구조와 재질에 대한 정밀분석을 실시하였다. 벽화는 석실을 축조 후 벽면과 천정에 모르타르를 바르고 그 위에 바탕칠층을 조성하여 채색하였다. 천장을 제외한 사면의 벽면에는 모르타르 위로 대부분 진흙이 덧발려져 있다. 모르타르는 모래는 사용되지 않았고, 순수한 칼슘성분의 물질들로 이루어져 있다. 또한 소성(燒成)이 완전히 진행되지 않은 불규칙한 크기의 패각들이 혼합되어 있으며, 모르타르의 석회질은 굴 껍질을 소성하여 얻어진 것으로 추정되었다. 바탕칠층은 백토(kaolinite($Al_2Si_2O_5(OH)_4$) 또는 halloysite($Al_2Si_2O_5(OH)_4{\cdot}2H2_O$))를 사용하였으며, 채색에 사용된 적색안료는 진사(cinnabar(HgS) 또는 vermilion), 녹색은 공작석(malachite($Cu_2CO_3(OH)_2$)) 그리고 백색은 연백(lead white($PbCO_3{\cdot}Pb(OH)_2$))이 쓰인 것으로 나타났다. 모르타르 위로 조성된 토양층은 주로 중립사 이하 크기의 입도가 낮은 점토질을 사용하여 얇고 치밀하게 조성하였으며, 모르타르층이 박락되고 상당기간이 경과 된 후 보수목적으로 마감한 것으로 추정된다. 굴 껍질을 소성하여 많든 석회를 모르타르로 사용한 것은 한국 고대 고분벽화 제작에 있어 유래 없는 사례이며, 내구성이 매우 떨어지는 특성을 지니고 있어 가야인들의 모르타르 제작기술이 동일시기의 고구려인들에 비해 상대적으로 떨어졌던 것으로 추측된다.

SO3를 다량 함유한 폐석고보드 미분말을 첨가한 3성분계 무기결합재의 길이변화 특성 (The Length Change Characteristic of the Ternary System Inorganic Composites adding the Waste Gypsum Board Micro Powder containing SO3 the great quantity)

  • 김윤미;박종필;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2012년도 추계 학술논문 발표대회
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    • pp.65-66
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    • 2012
  • The cement used in the construction industry of the manufacturing process, large amounts of the greenhouse gas, CO2 and is currently being studied for cement substitutes that reduce greenhouse gas issue. Therefore, the this study as a replacement for cement industrial by-product of blast furnace slag, red mud, silica fume and alkali-activator, using only inorganic composites without high-temperature calcination process were manufactured. The waste gypsum board micro powder added to compensate for the shrinkage cracks, the compressive strength and flow, and length change characteristics were investigated. Consequently, The setting time was shortened as GB added And liquidity was reduced. GB 2%, 7 days curing the added strength of specimens was the highest. Came out, and change the length of the Plain least.

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만리포 및 대천 해수욕장 수질 및 식물플랑크톤 (Water Quality and Phytoplankton in the Waters of Manripo and Daechon Beaches)

  • 여환구
    • 한국산학기술학회논문지
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    • 제12권6호
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    • pp.2872-2878
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    • 2011
  • 2010년 여름철 만리포의 수질은 COD(화학적산소요구량)가 개장전부터 폐장 이후까지 지속적으로 2.0 mg/l 이하로 측정되어 양호한 상태였고 SS(부유물질)의 량이 7월 조사에서 30mg/l를 초과하였으나 해수욕에는 무리가 없었을 것으로 판단된다. 식물플랑크톤은 대발생이나 적조 등의 현상이 나타나지 않았다. 대천의 수질은 8월 조사에서 COD값이 평균 2.0mg/l를 초과하기도 하였으나 전체적으로는 2.0mg/l 이하로 나타나 역시 해수욕장 수질로서는 양호하다. 다만 SS가 전체적으로 다소 높은 값을 보이기는 하나 이는 대천해수욕장의 저질특성에 기인한 머드(뻘)의 영향인 것으로 보이며 해당 해수욕장의 특징으로 설명될 수 있다. 식물플랑크톤 역시 규조류가 우점하는 보편적인 해수의 특징을 보였다.

Present State and Prospect on Reutilization of Metal - Bearing Solid Wastes in China

  • Chai, Liyuan;Chen, Weiliang;Min, Xiaobo;He, Dewen;Zhang, Chuanfu
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.183-187
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    • 2001
  • Present states on reutilization of metal-bearing solid wastes in China including metal-containing gangue, red mud, nonferrous metallurgical slag or residue, arsenical slag, steel - iron slag, waste batteries, were described in detail. The wastes pile up at a large quantity, resulting in seriously potential harm to environment. Most of these wastes, however, contain valuable metals, which are regarded as important secondary resources for extracting metals. Waste slag and batteries with a high grade of metals are treated by a hydro-based and / or pyre-based method for extracting valuable metals. While gangue and waste slag with a low grade are as a raw material in architecture field. In the future, a novel technology, such as high-grads magnetization separation technique and biological technique, will be designed to treat these wastes for protecting environment and recycling valuable components. These wastes, furthermore, are synthetically reutilized to produce various architectural materials, including glass and ceramics.

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PVA섬유혼입 무기결합재의 수중양생온도에 따른 강도특성 (Strength Characteristic according to the Water Curing Temperature of the Inorganic Binder Mixed PVA Fiber)

  • 이진우;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2013년도 추계 학술논문 발표대회
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    • pp.194-195
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    • 2013
  • Recently, it is the tendency that the CO2 gas generated in the manufacturing process is increased every year in case of the portland cement used in the most of constructions and civil engineering field. The method that uses the mineral admixtures as the cement substitute material in order to be more serious and as much as it occupies 7% of the global CO2 gas outlet amount such as 1 ton produces the cement and it ejects the CO2 gas of 0.4~1.0 ton, etc conclude this problem is examined. Therefore, PVA fiber was mixed into the inorganic binder recycling the blast furnace slag, which is the industrial byproduct with the purpose studying the Geo polymer which doesn't use the cement at all silica fume, red mud, and etc. In addition, the water curing temperature was differentiated and the strength characteristic of the curing body tried to be examined.

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섬유의 종류에 따른 폐유리와 무기결합재 인조석재의 역학적 특성 (Mechanical Properties of the artificial Stone According to the Ternary System Inorganic Composite and Waste Glass and Fiber type)

  • 유용진;김헌태;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2013년도 춘계 학술논문 발표대회
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    • pp.321-322
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    • 2013
  • Recently, the exhaustion of resource and environmental damage is serious due to the global warming because of the CO2 exhaust and each type the natural aggregate picking described below. meanwhile, The rest is the actual condition gone to the dumping ground that there is nearly no use which the waste glass can recycle and it is recycled. This research applied the waste glass as the cement substitute material the inorganic binder and coares aggregate substitute material. It utilizes the substitute material of the cement according to it and natural aggregate and tries to develop the environment-friendly artificial stone. The inorganic binder used the blast furnace slag, red mud, and fly ash. The straight type steel fiber, PVA fiber, PA fiber, and cellulosic fiber were used with a kind of fiber. As to the experimental item according to it, the compressive strength is the flexural strength and compressive strength.

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