• Title/Summary/Keyword: Recycling of wastes

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Current Status of Ilmenite Beneficiation Technology for Production of TiO2 (TiO2 제조를 위한 일메나이트 처리기술 현황)

  • Sohn, Ho-Sang;Jung, Jae-Young
    • Resources Recycling
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    • v.25 no.5
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    • pp.64-74
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    • 2016
  • Titanium and iron are closely related in nature, although titanium is the ninth most abundant element in the Earth's crust. Iron in titanium ores must be removed for use as feedstocks in the manufacture of titanium dioxide pigments and pure $TiCl_4$ for metal titanium. In this study, various beneficiation processes of ilmenite for production of $TiO_2$ have been reviewed and compared. Most of these processes involve a combination of pyrometallurgy and hydrometallurgy. These beneficiation processes of ilmenite generate considerable quantities of wastes primarily in the form of iron salt, iron oxide and acidic effluents. Therefore, it is important that recovery of acid value from waste and conversion of iron bearing waste to useful materials for development of new beneficiation processes of ilmenite.

Manufacture of Artificial stone using Wasts Stone and Powder Sludge (폐석 및 석분 슬러지를 활용한 인조석판재의 제조)

  • 손정수;김병규;김치권
    • Resources Recycling
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    • v.4 no.1
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    • pp.4-11
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    • 1995
  • The amounts of waste stone and stone powder sludge that occurred in the quarry and processing plant of s stone plates, have been increased with the development of stone industry. The manufactunng process of 따tificial s stone was studied to reduce the outlet of these wastes and utilIze them as raw materials for architecture, interior decoration and art work. In order to compare the properties of artiflcial stone with those of natural building-stone, the physi$\alpha$II properties of artificial stone such as specific gravity, absorption ratio, elastic wave velocity, compressive s strength, tensile strength, shore hardness, elasticity and Poission's ratio were measured. From the mesaured d data of physical properties, it was found that physical propertIes of artificial stone were controlled by homogeneous m mixing ratio of constituents, molding pressure, and amount of binder. Also, from the thermo-gravimetric analysis, it was found that artIfIcial stone manufactured had a good thermal stability up to $300^{\circ}C$. It was concluded that t the optimum conditions for manufacturing process of artificial stone were $200kg/\textrm{cm}^2$ of molding pressure, 12-15 w weight % of binder amounts.

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Enzymatic Hydrolysis of Gelatin Layers of X-Ray Films and Release of Silver Particles Using Keratinolytic Serine Proteases from Purpureocillium lilacinum LPS # 876

  • Cavello, Ivana A.;Hours, Roque A.;Cavalitto, Sebastian F.
    • Journal of Microbiology and Biotechnology
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    • v.23 no.8
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    • pp.1133-1139
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    • 2013
  • Enzymatic decomposition of gelatin layers on used X-ray films and repeated utilization of the enzyme for potential application in silver recovery were investigated using keratinolytic serine proteases from Purpureocillium lilacinum LPS # 876. At pH 9.0, the enzymatic reaction was enhanced by the increase of enzyme concentration or by the increase of the temperature up to $60^{\circ}C$. Under the conditions of 6.9 U/ml, $60^{\circ}C$, and pH 9.0, hydrolysis of the gelatin layers and the resulting release of silver particles were achieved within 6 min. The protective effect of polyols against thermal denaturation was investigated. The presence of glycerol and propylene glycol increased enzyme stability. When the reusability of the enzyme for gelatin hydrolysis was tested, it could be seen that it could be effectively reused for more cycles when glycerol was added, compared with the enzyme without protective agents. The results of these repeated treatments suggested that a continuous process of recycling silver from used X-ray is feasible. Keeping in mind that recycling is (at the present time) needed and imperative, it can be remarked that, in this research, three wastes were successfully used: hair waste in order to produce serine proteases; glycerol in order to enhance enzyme thermal stability; and used X-ray films in order to recover silver and PET films.

Effect of Sulfate and Heavy Metals on Methanogenic Activation of in the Anaerobic Digestion of Tannery Wastes (피혁폐수의 혐기성 소화시 황산염과 중금속이 메탄균 활성에 미치는 영향)

  • Shin, Hang Sik;Oh, Sae Eun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.1
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    • pp.13-21
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    • 1996
  • For treating tannery wastewater containing high sulfate and heavy metals, test was performed to assess their performance, competition between SRB (sulfate reducing bacteria) and MPB (methane producing bacteria), and the activity of MPB according to change of chromium concentrations. COD removal efficiency was above 70% at VLR (volumetric loading rate) of 2.0 gCOD/I.day and HRT (hydraulic retention time) of 18hrs at $35^{\circ}C$. In the competition between SRB and MPB, about 15% of the removed COD was utilized by SRB in the begining, but it became 43% at the end. It indicated that MPB was strongly suppressed by the occurrence of significant sulfate reduction since a large electron flow was uptaken by SRB. For the entire experiment, removal efficiencies of chromium concentration were more than 90%. Despite high removal efficiencies of chromium concentration, performance of reactor did not change significantly during the experimental periods. Expecially, chromium (III) is tannery wastewater is less toxic than chromium (VI).

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Application Plan of Sludge Reduction and Improvement of Ananerobic Digestion Rate Using VFAs from Food Waste (증산제를 통한 혐기소화율 개선 및 슬러지 감량 활용방안)

  • Lee, Kawng Hun;Kim, Gil Su;Sun, Beong Keon;Choi, Chan Sup;Cho, Gin Woo;Shin, Jae Hoon;Jeong, Tae Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.3
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    • pp.47-54
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    • 2018
  • This study examined the improvement of anaerobic digestion rate and sludge reduction as a result of the addition of anaerobic digestion with thickened sludge and solution of VFAs obtained from food waste. The methane production rate of the digestion system was 2.21 times higher when anaerobic digestion reactor injected into anaerobes with VFAs from food wastes of 5 percent. Also, The reduction of the amount of concentrated sludge injected will proceed rapidly because of the TCOD concentration in the digestion reactor was more than twice higher. Indirectly it was shown that the increased production system contributed significantly to the methane production efficiency.

Anaerobic Biodegradation of Lignin by BMP Test and Measurement of Lignin-derived Compound Using GC & GC/MS (BMP법에 의한 리그닌의 혐기성 분해 및 GC와 GC/MS을 이용한 리그닌 분해산물 측정)

  • Kim, Seog-Ku
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.3
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    • pp.46-51
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    • 2008
  • The traditional view of the fate of lignin under anaerobic conditions is that it is recalcitrant because molecular oxygen is required for depolymerization. The presence of lignin is apparently the most important factor affecting the biodegradability of ligneous materials. The initial step in the degradation of ligneous material to smaller intermediates is catalyzed by enzymes secreted by microorganisms and is generally regarded as the rate limiting step in the microbial mineralization of organic matter. Biochemical methane potential (BMP) test, typically used to assess anaerobic biodegradability of liquid wastes with added nutrients and bacteria, have been adapted to assess initial biodegradation of ligneous material under anaerobic conditions. A method based on selective inhibition of microorganism activity, by 3% toluene, has been used to measure using the initial degradation rate of ligneous material and the accumulation of lignin-derived compounds.

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Synthesis of Cement Raw Materials by Melting of Industiral Wastes(II) (폐기물의 용융처리에 의한 시멘트 원료의 합성(II))

  • Hwang, Y.;Sohn, Y. U.;Chung, H. S.;Lee, H. K.;Park, H. S.
    • Resources Recycling
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    • v.6 no.1
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    • pp.29-34
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    • 1997
  • The feasibility of using the industrial inorganic waste materials such as l~mestone sludge. Soundly sand. coal fly 'ash, and chemical glasses as a raw material for cement clinker by melting treatmeut was iovestigated. The slag wh~ch is obtained from thc melts of the mixtnres of waste materials is composed of P-C,S(ZCaO - SIOJ and C,AS(ZCaO . AI,O, . SiO,) phases. The effect of melting tempcrabre, coaling condition and CIS ratio on the fo~mation of P-C,S phasc was examed. In order to obtain thc P-CiS phase which is useful in thc utilhtion as a clinkcr malcrid, it B found that sudl considerations as low melting temperature as possible of the wastc mixhire, quenching the melts and law CIS ratio of the mlxhlre are necessary.

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A Study on the Preparation of Wood-Polymer Composites with Recycled PE films (재활용 PE수지를 이용한 Wood-Polymer Composites 제조에 관한 연구)

  • Kim, Ryeun-Kwan;Kang, Min;Kim, Hea-Tae;Song, Byung-Sun;Yoon, Tae-Ho
    • Resources Recycling
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    • v.8 no.4
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    • pp.57-63
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    • 1999
  • Wood-Polymer Composites (WPC) m s prepared irom recycled films of agricullural use and wood wastes, and LLDPE and neal PE resin mlxlurr war also utilized in order to cornpiue the praperlies. Molc~ca nhydride (MA) and dicumyl peroxide were used as an adheslon pmmoler and an il~lliatotor~, .espcmivelyT. ensile prapenies of W Cw zrc measured via lenslle test as a funclieu of woad lille~m d MA contmt, and rractu1.e surface was also mvestigaled wilh SEM. As the content of wwd tiller mcreased, clongauon deneased bul modulus increased However, tensile slrength OI WPC increased only when MA war used, and 1 wt.% of MA may be hgh enough to increase the tensile properties. The tensilc ptopcrlies af WPC prepwed from recycled PE films were &nost same as thosc of neal PE resin mixture.

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The Effects of Substitution Rate of Incinerated Sewage Sludge Ash on the Concrete Materials (건설재료로서 하수슬러지 소각재 적정 대체율 도출에 관한 연구)

  • Kim, Chun ho;Kim, Nam wook
    • Resources Recycling
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    • v.25 no.1
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    • pp.10-15
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    • 2016
  • In recent years, in terms of environmental protection and efficient use of the land, efficient utilization of byproducts and wastes generated in industrial areas are emerging. In this study, for the effective utilization of using ever increasing amount of utilizing sewage sludge incineration ash to increase sewage sludge, it is evaluated the use of as an construction material. After making concrete specimens, it is evaluated compressive strength, carbonation and environmental resistance. From the experimental results, compared with concrete without sewage sludge it is obtained satisfactory results for compressive strength and carbonation and results of the leaching test also satisfies the standard value. So, it is sufficient possibility using of concrete aggregate and the replacement rates is judged to be about 10%.

A Study on the Facility for Domestic Waste Problems of high Temperatured Combustion and the Alteration of heating surface (폐기물소각로의 고온 연소에 따른 문제와 연소실 전열면 변경에 대한 연구)

  • Kim, Seong-Jung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.3
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    • pp.60-67
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    • 2010
  • Korea's large-scale incinerating facilities of domestic waste were built in the late 1980's. It was found that most of the incinerators were designed during the period and even the ones constructed afterwards have been built without any changes or modifications. However, the nature of waste fed into incinerators is undergoing a radical change due to government policies on waste collection, which is upheld by a research into changes in the heating value of domestic wastes. As a result, refractories and stokers are being damaged in many of the facilities due to overheating. On the other hand, the formation of clinkers on boilers' heating surface, which curbs he at transfer, results in problems such as a fall in used heating value and a rise in the temperature of combustion chambers. Methods are being deployed to resolve the problems-such as spraying water on piles of waste, incinerating food waste by mixing together what has been separately collected, spraying water on combustion chambers, etc. Such actions are not a fundamental solution, nor redesigning and rebuilding incineration facilities is cost-effective. This research seeks to develop a fundamental solution to address the situation.