• Journal of Korean Society of Environmental Engineers
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• v.30 no.4
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• pp.453-458
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• 2008

Laboratory experiments were conducted to investigate disinfection as well as removal of color and residual organics from reclaimed municipal wastewater by electrochemical processes with Nb/Pt anode installed. RNO was rapidly bleached by OH$\cdot$ and the second order rate constants of RNO removal were $\frac{0.223l}{mg{\cdot}min}$, $\frac{1.679l}{mg{\cdot}min}$ and $\frac{2.322l}{mg{\cdot}min}$ with for 5 A, 10 A, and 15 A, respectively, with r$^2$ of > 96%. In batch electrochemical processes, after 15 min at currency of 15 A and initial pH of 5, 7,5 and 9, COD$_{Mn}$ was below 4 mg/L, color unit below 5 degree and general bacteria was not detected, the concentration of which are suitable for drinking water regulation. In the continuous electrochemical process, with HRT of 3.7$\sim$49.2 min, free chlorine were 0.2$\sim$0.7 mg/L, general bacteria was not detected, color unit below 5 degree and THMs was 0.017 mg/L. Therefore, electrochemical process with Nb/Pt anode was employed satisfactory to meet for reusing biologically treated water as well as disinfection.

• KSBB Journal
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• v.25 no.1
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• pp.33-40
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• 2010

Conventional disinfectants and disinfection method are expensive, hazardous and often require long periods of exposure. Recently, there is growing interest in complex disinfection process as a disinfection technique in medical instruments such as endoscope, hand piece bur to improve the disinfection efficiency and conveniency. The aim of this study was to evaluate the performance of a new complex process for the purpose of disinfection of Escherichia coli in water. Three single process (electrolysis, UV and ultrasonic process) was combined dual and triple disinfection process. The order of disinfection performance for E. coli in dual process lie in: Electrolysis + UV > Electrolysis + Ultrasonic > UV + Ultrasonic process. Disinfection efficiency of E. coli and degradation of N, N-Dimethyl-4-nitrosoaniline (RNO, indicating material of OH radical formation) of dual process was higher than that of the triple process (Electrolysis + UV + Ultrasonic process). In electrolysis + UV process, disinfection tendency was well agreed with RNO degradation tendency.

• Journal of Korean Society on Water Environment
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• v.27 no.5
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• pp.617-624
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• 2011

In order to confirm the creation of the OH radical which influences to RNO bleaching processes, it experimented using laboratory reactor of dielectric barrier discharge plasma (DBDP). The experiments performed in about 4 kind process variables (diameter of ground electrode, diameter of discharge electrode, diameter of quartz tube and effect of air flow rate) which influence to process. In order to examine optimum conditions of design factors as shown in Box-Behnken experiment design, ANOVA analysis was conducted against four factors. The actual RNO removal at optimized conditions under real design constraints were obtained, confirming Box-Behnken results. Optimized conditions under real design constraints were obtained for the highest desirability at 1, 1 mm diameter of ground and discharge electrode, 6 mm diameter of quartz tube and 5.05 L/min air flow rate, respectively.

• Journal of Environmental Science International
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• v.20 no.9
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• pp.1115-1124
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• 2011

There is an increasing incidence in health problems related to environmental issues that originate from inadequate treatment of sewage. This has compelled scientists to engage in innovative technologies to achieve a effective disinfection process. Electrolysis has emerged as one of the more feasible alternatives to conventional disinfection process. The objectives of the present paper were to investigate the effect of chemical characteristics on oxidant formation and Escherichia coli (E. coli) disinfection in synthetic sewage effluents. The influence of parameters such as COD, SS, T-N and T-P were investigated using laboratory scale batch reactor. The results showed that the higher COD, T-N and T-P concentration, the lower N, N-Dimethyl-4-nitrosoaniline (RNO, indicator of the generation of OH radical) degradation and E. coli disinfection was observed. The order of effect of RNO degradation and E. coli disinfection was T-P > COD > T-N > SS. When 4 parameter of water quality were worked simultaneously, oxidants formation and disinfection was decreased with increase of the concentration of sewage. To increase of the disinfection performance, the increase of disinfection time or electric power was need.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.12
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• pp.647-655
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• 2016

Lead dioxide ($PbO_2$) is an electrode material that is effective for organic pollutant degradation based on hydroxyl radical ($^{\bullet}OH$) attack. Representative parameters for $PbO_2$ electrodeposition are summarized to current, temperature, reaction time, concentration of Pb(II) and electrolyte agent. In this study, $Ti/PbO_2$ electrodes were fabricated by electrodeposition method under controlled reaction time, current density, temperature, concentration of $HNO_3$ electrolyte. Effects of deposition parameters on $^{\bullet}OH$ evolution were investigated in terms of electrochemical bleaching of p-Nitrosodimethylaniline (RNO). As major results, the $^{\bullet}OH$ evolution was promoted at the $PbO_2$ that was deposited in longer reaction time (1-90 min), lower current density ($0.5-50mA/cm^2$), higher temperature ($5-65^{\circ}C$) and lower $HNO_3$ concentration (0.01-1.0 M). Especially, the $PbO_2$ which was deposited in 0.01 M of lowest $HNO_3$ concentration by applying $20mA/cm^2$ for above 10 min was most effective on $^{\bullet}OH$ evolution. The performance gap between $PbO_2$s that was best and worst in $^{\bullet}OH$ evolution was about 41%. Among the properties of $PbO_2$ related on $^{\bullet}OH$ evolution performance, conductivity of $Ti/PbO_2$ significantly influenced on $^{\bullet}OH$ evolution. The increase in conductivity promoted $^{\bullet}OH$ evolution. In addition, the increase in crystal size of $PbO_2$ interfered $^{\bullet}OH$ evolution at surface of some $PbO_2$ deposits.

• Proceedings of the Korean Society of Crop Science Conference
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• 1995.05a
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• pp.96-97
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• 1995

• Journal of Environmental Science International
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• v.23 no.6
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• pp.1175-1182
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• 2014

In this study, we examined the effect of cathode from electrolysis reactor for treating ballast water. We are going to select a suitable cathode for seawater electrolysis after considering the effect on the generation of the oxidant of cathode and the electrode deposition materials adhering to the surface of cathode. Anode is Ru-Ti-Pd electrode and cathode are Ti, Pt, JP520 (Ni-Pt-Ce) electrodes. Using the cathode of the three types, experiments were conducted to examine the effects of TRO (total residual oxidants) generation concentration and RNO (N, N-Dimethyl-4-nitrosoaniline, indicator of the generation of OH radical) degradation concentration (in 1, 35 psu), ohmic drop, FESEM(field emission scanning electron microscope) observation of cathode surface and EDX (energy dispersive X-ray spectroscopy) measurements of attached fouling material. The results showed that TRO generation concentration and RNO degradation concentration in according to each type of cathode are not different. The attached fouling materials were observed on the surface of Ti and the JP520 electrode by the observation of SEM after electrolysis for two hours, but it was not observed on the surface of Pt electrode. When considering the surface ohmic drop of cathode and the attached fouling materials, Pt electrode was judged as the excellent cathode.

• Journal of Environmental Science International
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• v.28 no.3
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• pp.291-301
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• 2019

This study was conducted to investigate the effect of salt concentration and turbidity on the inactivation of Artemia sp. by electrolysis, UV photolysis, electrolysis+UV process to treat ballast water in the presence of brackish water or muddy water caused by rainfall. The inactivation at different salt concentrations (30 g/L and 3 g/L) and turbidity levels (0, 156, 779 NTU) was compared. A decrease in salt concentration reduced RNO (OH radical generation index) degradation and TRO (Total Residual Oxidant) production, indicating that a longer electrolysis time is required to achieve a 100% inactivation rate in electrolysis process. In the UV process, the higher turbidity results in lower UV transmittance and lower inactivation efficiency of Artemia sp. Higher the turbidity resulted in lower ultraviolet transmittance in the UV process and lower inactivation efficiency of Artemia sp. A UV exposure time of over 30 seconds was required for 100% inactivation. Factors affecting inactivation efficiency of Artemia sp. in low salt concentration are in the order: electrolysis+UV > electrolysis > UV process. In the case of electrolysis+UV process, TRO is lower than the electrolysis process, but RNO is more decomposed, indicating that the OH radical has a greater effect on the inactivation effect. In low salt concentrations and high turbidity conditions, factors affecting Artemia sp. inactivation were in the order electrolysis > electrolysis+UV > UV process. When the salt concentration is low and the turbidity is high, the electrolysis process is affected by the salt concentration and the UV process is affected by turbidity. Therefore, the synergy due to the combination of the electrolysis process and the UV process was small, and the inactivation was lower than that of the single electrolysis process only affected by the salt concentration.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 1999.05a
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• pp.411-414
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• 1999

70 ${\AA}$-thick oxides nitridied at various conditions were reoxidized at pemperatures of 900$^{\circ}C$ in dry-O$_2$ ambients for 5～40 mininutes. The gate oxide interface porperties as well as the oxide substrate interface properties of MOS(Metal Oxide Semiconductor) capacitors with various nitridation conditions, reoxidation conditions and pure oxidation condition were investigated. We stuided I$\sub$g/-V$\sub$g/ characteristics, $\Delta$V$\sub$g/ shift under constant current stress from electrical characteristics point of view and breakdown voltage from leakage current point of view of MOS capacitors with SiO$_2$, NO, RNO dielectrics. Overall, our experimental results show that reoxidized nitrided oxides show inproved charge trapping porperites, I$\sub$g/-V$\sub$g/ characteristics and gate $\Delta$V$\sub$g/ shift. It has also been shown that reoxidized nitridied oxide's leakage currented voltage is better than pure oxide's or nitrided oxide's from leakage current(1${\mu}$A) point of view.

• Proceedings of the KIEE Conference
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• 2005.11a
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• pp.210-213
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• 2005

This article describes an estimate method of the spark plug gap by measuring breakdown voltage. Breakdown voltage is the function of spark plug gap, pressure, temperature and humidify. However. It is dominated mainly by the spark plug gap. This technique is applied to in-line process test of the spark plug gap in automobile engine production. Breakdown voltage of normal spark plugs slightly scatters in ordinary conditions and if there is dust or burr in the gap, breakdown voltage gets lower. This technique saves repairing time for bad spark plug and attributes to improve the quality of automobile engine.