• Journal of the Korean Chemical Society
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• v.18 no.5
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• pp.329-340
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• 1974

Sulfadiazine, $C_{10}H_{10}N_4O_2S$, forms monoclinic crystals of space group $P21}c$ from a mixture of acetone and ethanol with $a=13.71{\pm}0.04,\;b=5.84{\pm}0.03,\;c=15.11{\pm}0.05{\AA},\;{\beta}=115.0{\pm}0.3^{\circ}$, and four molecules per cell. Three dimensional photographic data were collected with $CuK\alpha$ radiation. The structure was determined using Patterson and Fourier synthesis methods and refined by block diagonal least-squares methods with isotropic thermal parameter for all non-hydrogen atoms. The final R value was 0.15 for the 1517 observed independent reflections. The dihedral angle between the planes through the benzene ring and the pyrimidine ring is $76^{\circ}$. The conformational angle formed by the projection of the S-C(5) bond with that of N(1)-C(1) where the projection is taken along the S-N(1) bond is $77^{\circ}$. The imino nitrogen atom, N(1), and pyrimidine nitrogen atom, N(3), form intermolecular $N-H{\cdots}N$ hydrogen bond between the molecules related by center of symmetry. Amino nitrogen atom, N(4), forms two intermolecular $N-H{\cdots}O$ hydrogen bonds, with O(1) and O(2) atoms of different molecules separated by b. A two dimensional network of hydrogen bonds form infinite molecular sheets parallel to the (100) plane. Adjacent sheets are bound together by van der Waals forces.

• Journal of the Korean Chemical Society
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• v.40 no.3
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• pp.161-166
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• 1996

6-ethyl-5,6-dihydrouracil($C_6H_10N_2O_2$) is monoclinic, space group $$P2_{1}c}$$ with a=10.302(2), b=10.419(3), $c=7.095(1)\AA$, $\beta=106.6(0)$, Z=4, $V=729.7(3)\AA$^3$$, $D_c=1.29 g/cm^3,\;{\lambda}(MoK\alpha)=0.71073\AA$, $\mu=0.010cm^{-1}$, F(000)=304, and R=0.054 for 1070 unique observed reflection with F>4.0 $\sigma(F).$ The structure was solved by direct methods and refined by full-matrix least-squares refinement with the fixed C-H bond length at $0.96\AA.$ The hydrouracil molecule makes an envelope conformation with the ethyl substituent oriented to an axial position attainable to a varying degree of steric strain. There are two intermolecular hydrogen-bondings via N-H---O interactions, being nearly parallel to the 100 plane. The shortest distance between molecules is $3.187\AA$ of C(4) and O(8) (-x,-y, 1-z).

• Journal of the Korean Chemical Society
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• v.36 no.6
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• pp.812-817
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• 1992

Fluorometholone $(C_{22}H_{29}FO_4)$, M.W. = 376.5, monoclinic, $P2_1$, a = 6.410(4), b = 13.431(3), c = 10.996(3)$\AA$, $\beta$ = 92.81$(3)^{\circ}$, Z = 2, F(000) = 404, T = 292K, $\lambda$(Mo-$K_\alpha$) = 0.7107$\AA$, $\mu$ = 0.57$cm^{-1}$, $D_c$ = 1.32 $g/cm^3$, $D_m$ = 1.31 $g/cm^3$ and final R = 0.032 for 1769 observed reflections. All bond lengths and angles are within normal limits. Ring A is almost planar, B ring has a highly symmetrical chair conformation and C ring is in a distorted chair conformation. Ring D is in a intermediate conformation between 13$\alpha$-14$\beta$-half-chair and 13$\alpha$-envelope. Torsion angle C(16)-C(17)-C(20)-O(20) of $-7.9^{\circ}$ is a lower value than those of $-31.9^{\circ}$ and $-16.5^{\circ}$ for 9-fluoro-6-methylprednisolone I and II respectively.

• Journal of Korea Foresty Energy
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• v.22 no.1
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• pp.8-16
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• 2003

The Phyllostachys pubescens planted in the Nambu forest Experiment was used for this study. The growth ages of the P. pubescens were 1, 2 and 3 years, respectively. The experiment was carried out every month in between June of 2001 and May of 2002. The p. pubescens were divided into upper, middle and lower parts according to the growing points. The static modulus of elascity($MOE_d$) and dynamic modulus of elascity($MOE_d$) were investigated for the physical and mechanical properties of the P. pubescens. The density, MOEs and $MOE_d$according to the growing points were highest in the upper part of the P. pubescens. Generally, density and MOEs and $MOE_d$ of the P pubescens for 3 years grows larger every month. However, moisture content, MOEs and $MOE_d$ of the P. pubescens for 1, 2 years had nothing to do with growth ages and felling time. In the case of the relationships between average MOEs and $MOE_d$ the correlation coefficient was 0.88 in between June of 2001 and May of 2002. Also, $MOE_d$ showed about 18.5% higher than MOEs. Generally, the equally expressed in research that was known that $MOE_d$ of wood is higher than MOEs of wood. Therefore, the $MOE_d$ using a resonance frequency mode is useful as a nondestructive evaluation(NDE) method for predicting the MOE of the P. pubescens.

• Journal of the Korean Chemical Society
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• v.18 no.2
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• pp.97-109
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• 1974

The crystal and molecular structure of sulfaguanidine monohydrate, $C_7H_{10}N_4O_2S{\cdot}H_2O$, was determined from visually estimated intensity data from Weissenberg photographs. The crystal data are monoclinic, space group $P2_1$/c with four molecules in a unit cell of dimensions, ${\alpha}=7.57{\pm}0.03,\;b=5.44{\pm}0.02,\;c=24.76{\pm}0.06{\AA},\;{\beta}=91.0{\pm}0.2^{\circ}$. The structure has been solved by an interpretation of a Patterson map and with a help of a direct procedure on a projection. The parameters were refined isotropically by block-diagonal least-squares methods using 1542 observed independent reflections to give R = 0.14. By hydrogen bonding a guanidyl nitrogen of a sulfaguanidine molecule is linked to the sulfonyl oxygens of the other molecules indirectly through two different water molecules. The role of water molecule is both a donor and an acceptor in hydrogen-bonding formation and these hydrogen bonds are tetrahedrally oriented. The hydrogen-bonding networks form infinite molecular layers parallel to (001) plane.

• The Journal of Korean Academy of Sensory Integration
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• v.17 no.3
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• pp.14-25
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• 2019

Objective : This study aims to verify the content validity and inter-rater reliability of the Korean version of the Peabody Developmental Motor Scale 2 (PDMS-2) and to identify the concurrent validity by comparing it with the Korean version of the Bruininks-Oseretsky Test of Motor Proficiency-2 (BOT-2). Methods : PDMS-2 was translated by the researcher and an eighth-year clinical occupational therapist. The content consistency of the Korean version of the PDMS-2 was verified by three professors with experience using it. After the verification of the content consistency of the PDMS-2 by the five clinical occupational therapists and the additional revision, the Korean version of the PDMS-2 was completed. The researcher and another occupational therapist evaluated the Korean version of PDMS-2 in 50 children and measured the inter-rater reliability. Concurrent validity was measured by comparing the results of the Korean version of PDMS-2 and Korean version of BOT-2. Results : The content consistency test showed overall agreement of mean 3.45, and the content understanding test showed a high level of understanding of mean 3.69. The inter-rater reliability and concurrent validity of the Korean version of the PDMS-2 showed a statistically significant correlation. Conclusion : The Korean version of the PDMS-2 showed high content understanding, reliability, and validity. It can assist clinicians and researchers who work in fields related to child treatment or development.

• Journal of the Korean Chemical Society
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• v.36 no.4
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• pp.536-539
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• 1992

Eight-membered ring spiro orthocarbonate (C$_{25}H_{20}O_4$, M$_r$ = 384) is monoclinic, space group C2/c, with a = 15.319(4), b = 9.057(3), c = 13.168(3)${\AA}$, ${\beta}$ = 98.53(3)$^{\circ}$, Z = 4, F(000) = 808, T = 290 K, ${\mu}$(Mo-K${\alpha}$) = 0.55 cm$_1$, D$_c$ = 1.36 g/cm$^3$ and D$_m$ = 1.40 g/cm$^3$. The intensity data were collected with Mo-K${\alpha}$ radiation (${\lambda}$ = 0.7107 ${\AA}$) on an automatic four-circle diffractometer with a graphite monochromater. The structure was solved by direct methods and refined by full matrix least-squares methods. The final R value was 0.052 for 1412 observed reflections. The molecule has C$_2$point symmetry. The eight-membered ring has a chair conformation with pseudo-C$_s$ symmetry. The naphthyl ring is planar with the C-C bond lengths being in the range of 1.352∼1.444${\AA}$ and bond angles of 117.2∼123.5$^{\circ}$. The bond lengths of C(1)-C(9), C(8)-C(9) and C(9)-C(10) are somewhat longer than those of the other C-C bonds.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.2
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• pp.67-75
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• 2019

The diaphragm used for CFT columns has a small amount of steel to be used, but has a disadvantage that welding is difficult and openings are required because the steel tube and four sides must be welded. The improved diaphragm to be examined in this study was cut into four corners by cutting the center hole for concrete filling. In the improved diaphragm, the width of the center hole is the same as that of the previous diaphragm, but the width of the diaphragm contacting the steel tube is reduced, thereby reducing the welding length by about 70% compared to the previous diaphragm. The in-plane strain of each specimen was analyzed when the same load was applied to the interior diaphragm through a simple tensile test. Using the general FEM program(ANSYS 19.2), the analysis was performed under the same conditions as the actual simple tensile test, and the load transfer between the improved diaphragm and the previous diaphragm was compared. When the width of the diaphragm is equal to or smaller than the flange width, stress is concentrated from the end of the diaphragm, and when the flange width is larger, stress is concentrated at the center.

• Journal of Korea Water Resources Association
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• v.55 no.10
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• pp.749-759
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• 2022

The paradigm of water cycle management in the watershed is changing due to the increase in abnormal climate phenomena caused by climate change and the increase in impervious area due to urbanization. Research is continuously underway based on Low Impact Development technology that can suppress water cycle distortion. In this study, factors that can reflect water cycle distortion were selected before applying LID, and the PSR index for each 148 watershed was calculated for the the Nakdonggang River basin. As of 1975, the PSR index is calculated by calculating the pressure index P, which represents the rate of change in impervious surface area to 2019, the phenomenon index S, which represents the rate of change in water cycle for each subwatershed, and the Low Impact Development area countermeasure index R. The lower PSR index value, the higher the priority management watershed, and the water cycle recovery priority management watershed was calculated in the order of 1, 2, 87, 90, 91, and 147. It is expected that the efficient application of low-impact development factors in accordance with the order of priority management of water cycle by subwatershed in the large area will contribute to the recovery of water cycle distortion.

• Journal of the Korean Wood Science and Technology
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• v.32 no.2
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• pp.40-49
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• 2004

Phyllostachys pubescens planted in the Nambu Forest Experiment station in Jinju city of Gyongnam province was used, to investigate the physical and mechanical property of bamboo in this study. The ages of the P. pubescens were 1, 2 and 3 years, respectively. This experiment was carried out in August and January. The P. pubescens were divided into upper, middle and lower parts according to the growing points. The physical and mechanical properties of the P. pubescens were investigated before and after treatment of hot water and microwave irradiation. 1. The upper part of the P. pubescens indicated the highest static MOE according to the growing points. The range of the static MOE was from 70,000 to 110,000kgf/cm². 2. When P. pubescens were treated with hot water of 95℃, the ratio of softening was about 10~30%. 3. As microwave irradiation time was increased, the MOE values was decreased in both green and water-saturated bamboos. For the irradiation time of 20 and 30 seconds, the static MOE of P. pubescens was decreased up to about 50% comparing with non-treated.