• Electronic Materials Letters
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• 제14권6호
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• pp.689-699
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• 2018

Nanostructured Ni doped $Bi_2S_3$ ($Bi_{2-x}Ni_xS_3$, $0{\leq}x{\leq}0.07$) is explored as a candidate for telluride free thermoelectric material, through a combination process of mechanical alloying with subsequent consolidation by cold pressing followed with a sintering process. The cold pressing method was found to impact the thermoelectric properties in two ways: (1) introduction of the dopant atom in the interstitial sites of the crystal lattice which results in an increase in carrier concentration, and (2) introduction of a porous structure which reduces the thermal conductivity. The electrical resistivity of $Bi_2S_3$ was decreased by adding Ni atoms, which shows a minimum value of $2.35{\times}10^{-3}{\Omega}m$ at $300^{\circ}C$ for $Bi_{1.99}Ni_{0.01}S_3$ sample. The presence of porous structures gives a significant effect on reduction of thermal conductivity, by a reduction of ~ 59.6% compared to a high density $Bi_2S_3$. The thermal conductivity of $Bi_{2-x}Ni_xS_3$ ranges from 0.31 to 0.52 W/m K in the temperature range of $27^{\circ}C$ (RT) to $300^{\circ}C$ with the lowest ${\kappa}$ values of $Bi_2S_3$ compared to the previous works. A maximum ZT value of 0.13 at $300^{\circ}C$ was achieved for $Bi_{1.99}Ni_{0.01}S_3$ sample, which is about 2.6 times higher than (0.05) of $Bi_2S_3$ sample. This work show an optimization pathway to improve thermoelectric performance of $Bi_2S_3$ through Ni doping and introduction of porosity.

• 농업생명과학연구
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• 제45권4호
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• pp.121-133
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• 2011

Effects of roasting on vitamin E content, color, microstructure and moisture of peanuts, and vitamin E content in peanut oils prepared from the roasted peanuts were investigated. Runner-type peanuts were roasted at 140, 150, and $160^{\circ}C$ for 10-20 min. As roasting temperature and time increased, the CIELAB $L^*$ value of peanuts decreased while $a^*$ and $b^*$ values increased, resulting in formation of the golden brown color of roasted peanuts. Moisture ratio (M/Mo) and color $b^*$ value of peanuts roasted at 140 to $160^{\circ}C$ showed a correlation of $b^*=21.61\;(M/Mo)^2-40.62\;(M/Mo)+34.12$ ($R^2=0.9123$). Overall changes in the tocopherol contents of peanuts and peanut oils were significantly affected by roasting temperature and time (p<0.05). Roasting at $140^{\circ}C$ caused a slight increase in the levels of tocopherols of peanuts over roasting time up to 20 min (p<0.05). There was no significant change in the tocopherol levels of peanuts during roasting at $150^{\circ}C$ for 20 min (p>0.05). At $160^{\circ}C$, the levels of tocopherols significantly decreased during the initial 10 min of roasting (p<0.05) while there was no extended loss after 10 min, resulting in about 5, 12, 20, and 10% losses of ${\alpha}$-, ${\beta}$-, ${\gamma}$- and ${\delta}$-T, respectively. After 20 min, total tocopherols decreased by 18%. However, tocopherol contents of pressed peanut oils significantly decreased at all roasting temperatures (p<0.05). After roasting peanuts at $160^{\circ}C$ for 20 min, about 84% of initial ${\alpha}$-T in peanut oils was retained. ${\alpha}$-T was the most stable to roasting while ${\gamma}$-T was the least. Swollen epidermal cells on the inner surface and broken cell walls of parenchyma tissue of peanut cotyledon were observed in peanuts after roasting at $160^{\circ}C$ for 15 min. Severe changes in microstructure of peanut by roasting would contribute to vitamin E stability because of exposure of oil droplets in peanuts to oxygen.

• 한국식품저장유통학회지
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• 제12권4호
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• pp.361-366
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• 2005

Recoverable oil 농도별 처리에 따른 MOS(metal oxide sensor) 전자코를 이용한 향기 패턴 분석 결과 오일 함량이 증가함에 따라 제 1 주성분 값의 분포가 $0.05{\sim}-0.1$ 부근으로 이동하는 경향을 나타내었으며, 주성분 분석의 discrimination index가 89로서 첨가 농도에 따른 향기 패턴이 명확히 구별되고 있는 것으로 나타났다. 저장기간에 따른 향미 변화는 거의 없었으며 약간 감소하는 경향을 나타내었다. 저장기간에 따른 recoverable oil 잔존량을 분석한 결과 $0.01\%$와 $0.03\%$의 경우 14일까지는 완만한 감소를 나타냈으며, 21일까지는 거의 변화가 없었으나 $0.05\%$의 경우 7일까지 급격히 감소되어지고 21일까지 완만한 감소를 나타내었다. 저장기간에 따른 총체적 관능검사 결과 $0.03\%$ 처리구의 경우 0일차부터 14일차까지 거의 변화가 없었으며, 14일차 이후 급격한 감소를 나타내었다. 오렌지 풍미에 대한 관능검사 결과에서도 $0.03\%$ 처리구의 경우 14일째까지 거의 변화가 없었으나 14일째 이후 급격한 감소를 나타내었다.

• 한국터널지하공간학회 논문집
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• 제23권5호
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• pp.325-337
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• 2021

도로와 철도터널에서는 비상시 대피를 위한 시설이 필수적이며, 제연 및 화재 진압을 위한 설비와 승객의 피난 통로가 그것이다. 장대 병설터널에서는 횡갱을 배치하여 화재 발생 반대편 터널로 대피하도록 계획된다. 병설 쉴드터널에서는 횡갱의 시공을 위해 기 시공된 본선터널의 영구 구조물인 세그먼트 라이닝을 철거하여 원지반을 노출하여야 한다. 현대의 대부분의 쉴드TBM이 막장을 격벽으로 차단한 폐쇄형 쉴드TBM임을 감안할 때, 원지반이 노출되는 횡갱의 시공은 쉴드터널의 시공단계에서 위험도가 높은 과정 중 하나이다. 특히, 지하수위 아래의 토사 쉴드터널의 횡갱 시공에서는 세그먼트 철거 및 굴착 중 토사지반의 안정성 확보를 위한 차수 및 굴착공법에 대한 면밀한 검토가 요구된다. 본 사례 연구에서는 토사지반에서 대구경 강관추진을 활용한 횡갱 굴착 공법의 시공 중 유의사항을 소개하고 시공 후 계측결과를 분석하였다. 본 사례 연구에서 소개되는 횡갱 굴착공법은 그라우팅으로 보강된 토사지반에 대구경 강관 추진 후 내부 굴착하는 공법으로써, 두 가지 메커니즘에 의해 토사지반에서 굴착 중 막장의 안정성을 확보한다. 첫 번째는 대구경 강관을 추진하여 막장 전방 토사지반의 전주면을 강관에 의해 선 지보 한다. 두 번째는 대구경 강관 추진으로 내부로 압입된 토사의 Plugging 효과에 의해 막장 전면의 지지효과를 얻을 수 있다. 추진력에 의한 강관의 변형 및 강관의 관통 완료 후 응력발생 계측결과로부터 대구경 강관 추진에 의한 횡갱 굴착공법이 토사지반에서 충분한 시공성과 안정성을 확보함을 확인하였다. 본 사례 연구의 토사 쉴드터널의 횡갱 시공공법은 유사한 현장조건에서 널리 활용될 수 있을 것으로 판단된다.

• 한국초전도ㆍ저온공학회논문지
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• 제21권1호
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• pp.18-24
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• 2019

This study was carried out to investigate the effect of milling of boron (B), which is one of raw materials of $MgB_2$, on the critical current density ($J_c$) of $MgB_2$. B powder used in this study is semi-amorphous B (Pavezyum, Turkey, 97% purity, 1 micron). The size of B powder was reduced by planetary milling using $ZrO_2$ balls (a diameter of 2 mm). The B powder and balls with a ratio of 1:20 were charged in a ceramic jar and then the jar was filled with toluene. The milling time was varied from 0 to 8 h. The milled B powders were mixed with Mg powder in the composition of (Mg+2B), and the powder mixtures were uniaxially pressed at 3 tons. The powder compacts were heat-treated at $700^{\circ}C$ for 1 h in flowing argon gas. Powder X-ray diffraction and FWHM (Full width at half maximum) were used to analyze the phase formation and crystallinity of $MgB_2$. The superconducting transition temperature ($T_c$) and $J_c$ of $MgB_2$ were measured using a magnetic property measurement system (MPMS). It was found that $B_2O_3$ was formed by B milling and the subsequent drying process, and the volume fraction of $B_2O_3$ increased as milling time increased. The $T_c$ of $MgB_2$ decreased with increasing milling time, which was explained in terms of the decreased volume fraction of $MgB_2$, the line broadening of $MgB_2$ peaks and the formation of $B_2O_3$. The $J_c$ at 5 K increased with increasing milling time. The $J_c$ increase is more remarkable at the magnetic field higher than 3 T. The $J_c$ at 5 K and 4 T was the highest as $4.37{\times}10^4A/cm^2$ when milling time was 2 h. The $J_c$ at 20 K also increased with increasing milling time. However, The $J_c$ of the samples with the prolonged milling for 6 and 8 h were lower than that of the non-milled sample.

• 보존과학회지
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• 제37권2호
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• pp.120-134
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• 2021

조선 말기 방한용 깔개인 모담(毛毯)이 창덕궁 성정각의 해체 공사 중 발견되었다. 문헌기록에 비해 현전하는 조선시대 모직물 유물이 많지 않아 유물로서 가치가 높다. 특히 1907년 창덕궁 성정각을 수리한 기록이 있어, 모담은 19세기 말 또는 20세기 초에 제작된 것으로 생각된다. 출토 모담은 자적색 계열의 바탕 직물로 위에 황색, 홍색 등으로 선염한 색사를 표면에만 삽입하여 문양을 시문하였다. 모담의 식서부분은 S연의 면사가 확인되었으며, 지경사는 Z연의 황마사, 지위사는 S연의 황마사, 문경사는 S연의 모사를 사용했다. 특히 무늬는 루프파일의 색사로, 색사의 경계면에서 일부 컷 파일이 확인되나 지위사로 고정되어 표면에 거의 드러나지 않는 다. 황마사와 모사를 사용한 것은 18세기 중엽 유럽의 브뤼셀 카펫의 영향을 받은 것으로 짐작된다. 모담의 문양을 밝히는 데 한계가 있으며 다만 문양이 부분적으로 반복됨을 알 수 있다. 이상의 연구내용을 도출하기 위해 문헌과 회화자료 외에 현미경 분석, 적외선 분광분석을 실시하였다. 또한 유물에 사용된 염료를 밝히기 위해 색도측정을 토대로 자외-가시광 분광분석을 실시하여 천연 염색한 직물 샘플에 대한 교차분석을 시도하였다. 그 결과 모담의 녹색 모사는 쪽을 사용하지 않았으며, 자적색의 바탕조직은 소목으로 염색한 것으로 추정할 수 있다.

• Animal Bioscience
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• 제34권1호
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• pp.109-118
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• 2021

Objective: The objective of this study was to determine net energy (NE) of expeller-press (EP-RSM) and solvent-extracted rapeseed meal (SE-RSM) and to establish equations for predicting the NE in rapeseed meal (RSM) fed to growing pigs. Methods: Thirty-six barrows (initial body weight [BW], 41.1±2.2 kg) were allotted into 6 diets comprising a corn-soybean meal basal diet and 5 diets containing 19.50% RSM added at the expense of corn and soybean meal. The experiment had 6 periods and 6 replicate pigs per diet. During each period, the pigs were individually housed in metabolism crates for 16 days which included 7 days for adaption to diets. On day 8, pigs were transferred to respiration chambers and fed their respective diet at 2,000 kJ metabolizable energy (ME)/kg BW0.6/d. Feces and urine were collected, and daily heat production was measured from day 9 to 13. On days 14 and 15, the pigs were fed at 890 kJ ME/kg BW0.6/d and fasted on day 16 for evaluation of fasting heat production (FHP). Results: The FHP of pigs averaged 790 kJ/kg BW0.6/d and was not affected by the diet composition. The NE values were 10.80 and 8.45 MJ/kg DM for EP-RSM and SE-RSM, respectively. The NE value was positively correlated with gross energy (GE), digestible energy (DE), ME, and ether extract (EE). The best fit equation for NE of RSM was NE (MJ/kg DM) = 1.14×DE (MJ/kg DM)+0.46×crude protein (% of DM)-25.24 (n = 8, R2 = 0.96, p<0.01). The equation NE (MJ/kg DM) = 0.22×EE (% of DM)-0.79×ash (% of DM)+14.36 (n = 8, R2 = 0.77, p = 0.018) may be utilized to quickly determine the NE in RSM when DE or ME values are unavailable. Conclusion: The NE values of EP-RSM and SE-RSM were 10.80 and 8.45 MJ/kg DM. The NE value of RSM can be well predicted based on energy content (GE, DE, and ME) and proximate analysis.

• 유기물자원화
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• 제30권4호
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• pp.151-163
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• 2022

본 연구는 친환경 농산물 생산을 위한 양분관리 자재로 유기질비료 처리에 따른 옥수수 재배 토양의 비옥도 및 토양 호흡에 미치는 영향을 분석하였다. 시험장소는 국립농업과학원 유기농업과 시험포장에서 수행하였으며 처리구는 퇴비 (Com), 발효비료 (FOF), 혼합 유박 (PC), 무비구 (NF)로 처리구당 3반복 완전임의 배치하였다. 처리량은 174kg N/ha로 옥수수 표준시비량의 질소기준에 준하여 처리하였다. 옥수수 정식 8주 후 토양분석 결과, 퇴비는 토양의 탄소 (C)와 질소 (N)를 각각 7.48 및 0.76g/kg으로 증가시켰고, 다른 처리구는 시험 전과 차이가 없었다. 또한 시험 후 토양의 화학적 특성은 무비구를 제외하고 유의한 차이는 없었다. 토양 CO₂ 발생량은 발효비료 처리가 다른 처리구보다 31-76% 증가시켰으며 두 번의 제초작업 후 CH₄ 발생량의 차이는 없었다. 토양의 N₂O 배출량은 발효비료 처리가 다른 처리구보다 87-96% 감소되었다. 미생물 밀도 조사 결과, 시험 전에 비해 시험 후 토양의 사상균 및 방선균 밀도를 각각 25%, 16% 증가되었다. 따라서 친환경 농산물 생산을 위한 발효비료 등 유기질 비료는 자원을 순환하며 토양 생산성을 유지하는데 기여할 것이다.

• 동남아시아연구
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• 제20권3호
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• pp.223-262
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• 2010

This paper has been written to find facts about the image of earth goddess broadly found in the Southeast Asia. The research findings are as follows: Firstly, the image of earth goddess wringing her hair is phenomenally discovered in both Buddhist temple murals and independent shrines in Thailand. This phenomenon is common in other Indochinese Buddhist countries such as Myanmar, Laos and Cambodia. Secondly, the life of Buddha including the story of the victory over Mara is found in such Buddhist canons as Mahavastu, Buddhacarita, Lalitavistara, Nidanakatha and Patamasambodhi. Among the canons, the story of the victory over Mara is described in differently ways. Earth becomes personified as the goddess in later version. The main cause to expel Mara's army also changes from sound to water. Patamasambodhi is most closely associated with the iconography of the earth goddess of Southeast Asia. Thirdly, Vessantara Jataka and Indian ancient customs tell us that a merit maker performs a rite of pouring water on the earth as an evidence for merit-making. This rite is a key to understanding the meaning of the scene where the earth goddess expels Mara's army into the flood by wringing her hair. The earth goddess is personified from the earth upon which the merit water is poured. Water soaked in her hair is the very holy water poured by the Buddha whenever he made a merit in his former lives. The amount of water flowed from the hair of the earth goddess representing the amount of his merit making was so huge and enough to defeat the Mara's army and for the Buddha to reach the Enlightenment. This legend explains the significance of the notion of merit in the Theravada Buddhist countries such as Thailand and Myanmar where the water pouring rites still take place and the images of the hair wringing earth goddess are commonly discovered. Fourthly, the first image of the earth goddess as the witness of merits for the Buddha appeared in some Gandharan Buddhist sculptures in the form of devotional gesture with her both hands pressed together and the upper half of her body above the ground. The appearance is in accordance with the description of her in the Lalitavistara canon. In later periods, the form changed into various types and finally the image of the earth goddess wringing her hair appeared in Southeast Asia around 11 century C.E. Some researchers argue this image form of the earth goddess shows the influence from China or India. However, the arguments are considered to be hypothetical as they have no strong evidence to prove. Finally, the modern image of earth goddess shows richer and more dynamic expression compared with its predecessors. Especially, outstanding is the standing earth goddess images found in the scene of the victory over Mara in many temple murals of central region of Thailand. The earth goddess in her voluptuous body shape is usually depicted as wringing her hair with her arms wide open in a posture of S curve. This appearance strongly reminds us of the postures of Salabhanjika and Tribhanga originated from Indian art. The adoption presumably has been made to signify her fertile and affluent characteristics.

• 대한금속재료학회지
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• 제49권2호
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• pp.167-173
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• 2011

Nickel cobalt ferrite($Ni_{0.5}Co_{0.5}Fe_2O_4$) powder was prepared through the ceramic route by the calcination of a stoichiometric mixture of NiO, CoO and $Fe_2O_3$ at $1100^{\circ}C$. The pressed pellets of $Ni_{0.5}Co_{0.5}Fe_2O_4$ were isothermally reduced in pure hydrogen at $800{\sim}1100^{\circ}C$. Based on the thermogravimetric analysis, the reduction behavior and the kinetic reaction mechanisms of the synthesized ferrite were studied. The initial ferrite powder and the various reduction products were characterized by X-ray diffraction, scanning electron microscopy, reflected light microscope and vibrating sample magnetometer to reveal the effect of hydrogen reduction on the composition, microstructure and magnetic properties of the produced Fe-Ni-Co alloy. The arrhenius equation with the approved mathematical formulations for the gas solid reaction was applied to calculate the activation energy($E_a$) and detect the controlling reaction mechanisms. In the initial stage of hydrogen reduction, the reduction rate was controlled by the gas diffusion and the interfacial chemical reaction. However, in later stages, the rate was controlled by the interfacial chemical reaction. The nature of the hydrogen reduction and the magnetic property changes for nickel cobalt ferrite were compared with the previous result for nickel ferrite. The microstructural development of the synthesized Fe-Ni-Co alloy with an increase in the reduction temperature improved its soft magnetic properties by increasing the saturation magnetization($M_s$) and by decreasing the coercivity($H_c$). The Fe-Ni-Co alloy showed higher saturation magnetization compared to Fe-Ni alloy.