• Title/Summary/Keyword: Polymer electrode

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Development and Performance Evaluation of Polymer Micro-actuator using Segmented Polyurethane and Polymer Composite Electrode (세그먼트화 폴리우레탄을 이용한 고분자 마이크로 액츄에이터의 제작 및 고분자 전극의 상태에 따른 구동성능)

  • Jung Young Dae;Park Han Soo;Jo Nam Ju;Jeong Hae Do
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.2
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    • pp.180-187
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    • 2005
  • This paper is focused on the development of the flexible electrode for disc-type polymer actuators using Segmented Polyurethane(SPU). This paper consists of two parts. The one is about the mechanical property such as elastic modulus. these parameters mainly affect behaviors of polymer actuators and the other is about the electro-chemical property such as the surface resistance of the composite electrode affects the strength of electrostatic force, results in the deformation of polymer actuators. The Young's modulus was measured by UTM. As result, by increasing the modulus of a body of polymer actuators, the maximum displacement of polymer actuators are decreased. The surface resistance of the electrode was measured by 4 point probe system. Compared with the conductive silver grease, the displacement of polymer actuators using carbon black(CB) composite electrodes is comparably small but CB composite electrode should be the practical approach for the improvement of the performance of all-solid actuators, compared with another types of electrode materials.

Address Electrode for PDP by Ink-Jet Method

  • Park, Lee-Soon;Im, Moo-Sik;Jung, Young-Chul
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.775-777
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    • 2003
  • Several methods are available for the fabrication of electrode pattern for the plasma display panel(PDP) including screen printing and photolithographic method. Piezo type ink-jet printing method is considered to the method of choice for electrode patterning in manufacturing of PDP. Both silver ink and absorbent layer paste formulation were developed for ink-jet printing of electrode pattern. The ink-jet printing of silver electrode with preformed absorbent layer was especially suitable for the patterning of address electrode for high resolution PDP.

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Viewing Angle Switching using Hybrid Aligned Nematic Liquid Crystal Display Driven by a Fringe-Field

  • Chin, Mi-Hyung;Jeong, Eun;Lim, Young-Jin;Kim, Jin-Ho;Srivastava, Anoop Kumar;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1386-1389
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    • 2008
  • Conventional viewing angle switching electrode requires pixel division and additional liquid crystal panel. Hence the conventional viewing angle switching has low aperture ratio and high thickness. In this paper we proposed new viewing angle switching using hybrid aligned nematic mode by fringe-field electrode field (named HAN-FFS) with single liquid crystal panel. The fringe-field switching electrode is located at the bottom, and the additional common electrode is located at the top of the cell to control viewing angle. The proposed device is free from additional liquid crystal panel and pixel division. Consequently, the suggested structure has not only high aperture ratio but also show an excellent potential for viewing angle switching.

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Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터 의 개발)

  • 오길훈;김한주;최원경;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Co-Electrodeposition of Bilirubin Oxidase with Redox Polymer through Ligand Substitution for Use as an Oxygen Reduction Cathode

  • Shin, Hyo-Sul;Kang, Chan
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3118-3122
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    • 2010
  • The water soluble redox polymer, poly(N-vinylimidazole) complexed with Os(4,4'-dichloro-2,2'-bipyridine)$_2Cl]^+$ (PVI-[Os(dCl-bpy)$_2Cl]^+$), was electrodeposited on the surface of a glassy carbon electrode by applying cycles of alternating square wave potentials between 0.2 V (2 s) and 0.7 V (2 s) to the electrode in a solution containing the redox polymer. The coordinating anionic ligand, $Cl^-$ of the osmium complex, became labile in the reduced state of the complex and was substituted by the imidazole of the PVI chain. The ligand substitution reactions resulted in crosslinking between the PVI chains, which made the redox polymer water insoluble and caused it to be deposited on the electrode surface. The deposited film was still electrically conducting and the continuous electrodeposition of the redox polymer was possible. When cycles of square wave potentials were applied to the electrode in a solution of bilirubin oxidase and the redox polymer, the enzyme was co-electrodeposited with the redox polymer, because the enzymes could be bound to the metal complexes through the ligand exchange reactions. The electrode with the film of the PVI-[Os(dCl-bpy)$_2Cl]^+$ redox polymer and the co-electrodeposited bilirubin oxidase was employed for the reduction of $O_2$ and a large increase of the currents was observed due to the electrocatalytic $O_2$ reduction with a half wave potential at 0.42 V vs. Ag/AgCl.

Electrochemical detection effect of hormone in body by using polymer coated boron doped diamond electrode (고분자 막이 코팅된 Boron doped diamond 전극에 의한 호르몬의 전기화학적 검출 효과)

  • Hwang, Jin-Hee;Cho, Eun-In;Park, Soo-Gil;Okajima, Takeyoshi;Ohsaka, Takeo;Fujishima, Akira
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.611-614
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    • 2003
  • The electrochemical oxidation of ascorbic acid(AA), serotonin(SE) and epinephrine(EP) have been performed at poly N,N-dimethylaniline(PDMA) film coated diamond electrode. This cationic polymer film is electrochemically deposited on boron-doped diamond electrode surface. Unlike the bard electrode, the polymer film-coated diamond electrode can well separate the oxidation potential of AA by 200mV. Thus this electrode can be successfully used for the simultaneoud detection of both species. Increases in the concentration of AA do not affect the reponse of EP and SE.

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Behavior of $Li^{+}$ in PAN/PVDF based Polymer Electrolyte for Lithium Polymer Battery (리튬 폴리머전지용 PAN/PVDF계 고분자 전해질의 리튬 이온 거동)

  • 이재안;김상기;김종욱;구할본;박계춘
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.540-543
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    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity, impedance spectroscopy and electrochemical properties of PAN/PVDF electrolytes as a function of a mixed ratio were reported for PAN/PVDF based polymer electrolyte films, which were prepared by thermal gellification method of preweighed PAN/PVDF, plasticizer and Li salt. The conductivity of PAN/PVDF electrolytes was $10^{-3}$S/cm. $PAN_{10}$$PVDF_{10}$$LiClO_4$$PC_{5}$$EC_{5}$ electrolyte has the better conductivity compared to others. The interfacial resistance behavior between the lithium electrode and PAN/PVDF based polymer electrolyte has also been investigated and compare with that between the lithium electrode and the PAN/PVDF based polymer electrolyte.

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Electrochemical Properties of Polypyrrole/Polyfuran Polymer Composite Electrode (피롤/퓨란 고분자 복합체 전극의 전기화학적 성질)

  • Cha, Seong Keuck
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.664-671
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    • 1998
  • Poly pyrrole polymer(ppy) has an excellent electrical conductivity and can be easily polymerized on anode to give various morophology according to doped anion on electroactive sites. To improve the properties of brittleness, ageing and hydrophobisity, poly furan polymer(pfu) having a high initiation potential was anodically implanted in this porous ppy film matrix to get the Pt/ppy/pfu(x)type of polymer composite electrode. Cyclic voltammetry and electrochemical impedance methods were used to these electrode, where $PF_6^-,\; BF_4^-$, and $ClO_4^-$ ions were employed as dopants. The composition of the pfu(x) at the electrode was changed from 0 to 1.10, but the range was useful only at 0.1 to 0.2 as the redox electrode. The polymer composite electrode doped with $PF_6^-$ was better in charge transfer resistance by a factor of 40 times and in double layer capacitance by a factor of 20 times than others. The charge transfer in the polymer film of the electrode was influenced on frequency change and equivalent circuit of this electrode had Warburg impedance including mass transfer.

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The Possibility of 1,3,4-Oxadiazole Containing Polymer as a New Polymer Electrode in Redox Supercapacitor

  • Ryu, Kwang-Sun;Chang, Soon-Ho;Kwon, Soon-Ki;Kim, Yun-Hi;Hwang, Do-Hoon
    • Macromolecular Research
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    • v.10 no.1
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    • pp.40-43
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    • 2002
  • Poly(1', 4'-phenylene-1", 4"-(2"-(2""-ethyl-hexyloxy)) phenylene-1",4"-phenylene-2,5-oxadiazolyl) (PPEPPO) was synthesized and its electrochemical characteristics was investigated as electrode material in redox supercapacitor. The cyclic voltammetry (CV) shows there was scarcely a redox reaction and further suggests n-doping is difficult to occur in this system. However, the discharge curve between 3.0 to 0.01 V is continuously decreased like a straight line, similar to the discharge pattern of EDLC. The initial specific discharge capacitance is ~6.4 F/g, while the specific capacitance of 1000th cycle is ~0.1 F/g. The PPEPPO can be used as the electrode of supercapacitor, emissive material, as well as charge-transporting material in polymer LED.ansporting material in polymer LED.

Transflective liquid crystal display with single cell gap and simple structure

  • Kim, Mi-Young;Lim, Young-Jin;Jeong, Eun;Chin, Mi-Hyung;Kim, Jin-Ho;Srivastava, Anoop Kumar;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.340-343
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    • 2008
  • This work reports the simple fabrication of the single cell gap transflective liquid crystal display (LCD) using wire grid polarizer. The nano sized wire grid polarizer was patterned on common electrode itself, on the reflective part of FFS (Fringe field switching) mode whereas the common electrode was unpatterned at transmissive part. However, this structure didn't show single gamma curve, so we further improved the device by patterning the common electrode at transmissive part. As a result, V-T curve of proposed structure shows single gamma curve. Such a device structure is free from in-cell retarder, compensation film and reflector and furthermore it is very thin and easy to fabricate.

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