• Title/Summary/Keyword: Physicochemical change

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Denitrification Rates in Tributaries of the Han River in Relation to Landuse Patterns and Microtopology (한강 지류 토지 이용 특성과 하천 내의 미지형에 따른 탈질량과 조절 인자)

  • Kim, Young-Joo;Kwon, Min-Jung;Kang, Ho-Jeong
    • Journal of Wetlands Research
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    • v.14 no.1
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    • pp.139-146
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    • 2012
  • Stream ecosystems carry out significant functions such as water purification, especially denitrification. However, rapid landuse change since industrialization has altered ecological functions of streams. In this study, we aimed to investigate denitrification rates and their determinant factors in streams with different landuse patterns, and how denitrification rates vary with microtopology within streams. Ten fifth streams of each landuse were selected, and each stream was divided into four microtopological sites within streams - riparian zone, subsoil, and both head and tail parts of sand bars. In situ denitrification rates and physicochemical properties of soil were examined. Denitrification rates of agricultural, urban, and forest streams were $289.62{\pm}70.69$, $157.01{\pm}37.06$, $31.38{\pm}18.65mg$ $N_2O-N\;m^{-2}\;d^{-1}$ respectively. There were no significant differences in denitrification rates depending on microtopology, but the rates in riparian zone were the highest, and the rates in the head parts of sandbars were lower than those of tail parts. The determinant factors for denitrification rates included water temperature, silt and clay contents of soil, inorganic nitrogen, and organic carbon, and these factors all showed positive correlations with denitrification rates. Through this study, we find that landuse pattern in watershed region affects denitrification rates that is one of considerable functions of streams. In addition, estimation of denitrification rates taking into account for microtopology would contribute to developing ecological management and restoration strategy of streams.

Basic Research to Develop PGM-free DeNOx Catalyst for LNT (LNT용 PGM-free DeNOx 촉매 개발을 위한 기초연구)

  • Jang, Kil Nam;Han, Kwang Seon;Hong, Ji Sook;You, Young-Woo;Hwang, Taek Sung
    • Clean Technology
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    • v.21 no.2
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    • pp.117-123
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    • 2015
  • This inquiry was conducted to develop DeNOx catalyst for LNT. In order to develop appropriate catalysts, four catalysts, which do not use PGM (Platinum Group Metal), were carefully selected : Al/Co/Mn, Al/Co/Ni/Mn, Al/Co/Mn/Ca, Al/Co/Ni mixed metal oxides during preliminary experiments. Also, XRD, EDS, SEM, BET and TPD tests were carried as well to evaluate both physicochemical properties of such four catalysts. As a result of the experiment, four catalysts were composed of spinel-shaped crystals and had more than enough pore volume and size to have oxidation-reduction reaction of NOx gases. Additionally, through TPD test, all four types of catalysts were proved to possibly have an oxidation-reduction acid site and NO oxidation activities similar to commercial catalysts. Based on the results above, if we have further change in the composition components and active ingredients according to the catalysts that were chosen in this investigation, then we are more welcomed to expect to have an enhanced DeNox catalyst for LNT.

Potential Detection of γ-Irradiated Panicum miliaceum by Viscosity Measurement during Storage (점도 측정법을 이용한 기장(Panicum miliaceum)의 저장 중 감마선 조사 검지 가능성)

  • 최맑음;권중호;김현구
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.4
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    • pp.531-538
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    • 2003
  • To elucidate the physicochemical change of Panicm miliaceum powders caused by irradiation and identify detection of irradiation, viscosity, TBA value, Hunter color and total viable count were measured after irradiation of Panicum miliaceum powder. Panicum miliaceum powders from Korea and China were irradiated at 0, 2.5, 5, 7.5, 10, 15 kGy using a $Co^{60}$ irradiator and stored for 9 months at $0^{\circ}C$ and $20^{\circ}C$. All samples resulted in decrease for viscosity and specific parameter values by increasing dosage at 50 rpm after irradiation. These values showed dose-dependent relationship (above $r^2$=0.92) between non-irradiated and irradiated samples during storage. These results suggest that the detection of irradiated Panicum miliaceum at various doses is possible by using viscometric method during storage. Total viable count, TBA value and Hunter color were determined as assistant indices for the samples viscosity measured. Total viable count, TBA values showed dose-dependent relationship (2.5 ~15 kGy). The difference in viscosity along with total viable count, TBA values between non-irradiated samples little or some changed with the lapse of post-irradiation time, but was still distinguishable each other more than 6 months at $0^{\circ}C$ and $20^{\circ}C$ for Panicum miliaceum powders from Korea and China.

Vertical Variations of Water Environments and Phytoplankton Community during the 2009 Autumn in the Coast of Dokdo, Korea (2009년 추계 독도연안의 수환경과 식물플랑크톤 군집의 수심별 변화)

  • Kim, Yun-Sam;Park, Kyung-Woo;Park, Jung-Won;Jeune, Kyung-Hee;Kim, Mi-Kyung
    • Korean Journal of Environmental Biology
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    • v.28 no.4
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    • pp.202-211
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    • 2010
  • The variations of physico-chemical factors and the species compositions of phytoplanktons were investigated to analyze the marine ecosystem at the depths during summer in the coast of Dokdo (stations DOK 1-3). The mean values of conductivity (48.9 mS $cm^{-1}$), salinity (32.9 psu) and total suspended solids (57.9 mg $L^{-1}$) were the highest in DOK 1. The biomass (Chl-a) of phytoplanktons was the highest in the surface of DOK 1 (2.61 ${\mu}gL^{-1}$). By the means of physicochemical factors (salinity, turbidity, Chl-a, TN, TP and Si), the water estimated in the coast of Dokdo was more eutrophicated than that in 2008. The phytoplanktons were a total of 42 species in Dokdo, which were composed of 33 species (78.6%) for Bacillariophyceae and 9 species (21.4%) for Dinophyceae. The standing crops of phytoplanktons were the highest ($18{\times}10^3$ cells $L^{-1}$) in the surface of DOK 2 and in the surface of DOK 3, while they were the lowest ($2{\times}10^3$ cells $L^{-1}$) at depth of 40 m of DOK1 and at depth of 30 m of DOK 3. The dominant species of phytoplanktons were Chaetoceros castracanei ($6{\times}10^3$ cells $L^{-1}$) in the surface, Rhizosolenia alata f. gracillima ($3{\times}10^3$ cells $L^{-1}$) at depth of 20 m and Protocentrum compressum ($4{\times}10^3$ cells $L^{-1}$) at the depth of 30 m of DOK 1. At the surface of DOK 2, the dominant species was Bacillaria paxillifer ($6{\times}10^3$ cells $L^{-1}$), while it was Hemiaulus indicus ($12{\times}10^3$ cells $L^{-1}$) at the surface of DOK 3. The DOK 1, which is affected by upwelling, whirlpool and circulation due to the East Korean Warm Current, was the most eutrophicated water body among three stations. The monitoring of marine ecosystem in the coast of Dokdo should be continued to propose the alternatives for water quality and species conservation and to purify the eutrophicated water body due to artificial pollutants as well as natural effectors by the global warming, the climatic change, etc.

STUDIES ON ENVIRONMENTAL FACTORS IN MARINE BIVALVE CULTURE (패류양식을 위한 적지환경요인에 관한 연구)

  • LEE Choonkoo;CHANG Nam Kee;CHOI Shin Sok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.2 no.1
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    • pp.33-40
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    • 1969
  • 1. Physicochemical properties of sea water and soil of Korean tidal flats densely populated with species of Mactra veneriformis, Cyclina sinensis, Meretrix lusoria, and Tapes philippinarum, were investigated in order to find out the index of environmental factors in marine bivalve culture. 2. The turbidity varied with the change in concentrations of organic matter, silicate, and the exchangeable copper in sea water. All of these concentrations in Inchon, Kunsan, and Hansando were higher than those in Yusoo. In the 5 areas investigated the lowest were ditected at Kangnung. 3. The minerals and organic matter content in sea water dia not vary significantly among the different bivalve beds. And it was presumed that the soil texture was one of the most important environmental factors for the density of the bivalves in tidelands. 4. The soil texture index of the different bivalve beds was obtained as follow: 5. There were no significant differences of pH, the exchangeable calcium, and the exchangeable copper contents of bottom soils in the 4 different bivalve beds. As important factors in these areas, it seems that the amount of chemical properties might not affect the distribution of bivalve species. 6. Among the 4 beds the soil organic matter content was highest at the T. philippinarum bed and varied with the total nitrogen content. 7. Among the different bivalve beds, it was significant that the water holding capacity and available phosphorus content were highest at the M. veneriformis bed.

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Effect of Desalting on the Physicochemical and Sensory Characteristics of Danmuji (탈염 공정이 단무지의 물리화학적 및 관능적 특성에 미치는 영향)

  • 오훈일;박종면;장정희
    • The Korean Journal of Food And Nutrition
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    • v.10 no.4
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    • pp.439-445
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    • 1997
  • Radish roots were salted in 4 different salt concentrations (5, 10, 15, 20%) for 3 months followed by desalting. The effects of desalting process on salt concentration, Ca content, texture and sensory characteristics were investigated during 3 days of desalting period at $25^{\circ}C$. NaCl content in danmuji salted in lower NaCl concentrations decreased rapidly and a linear relationship was found between the decrease in NaCl content and the logarithmic value of desalting time. Changes in Ca content of danmuji also exhibited a similar trend to that of NaCl content. Hardness of radish root tended to increase wit an increase in desalting time up to 2 days of desalting and then decreased slightly at the 3rd day of desalting. The results of sensory evaluation revealed that regardless of salt concentration used acidic, salty odor and taste of danmuji decreased significantly during desalting, however, there was very little change in yeast-moldy odor and taste with the intensity being very low in danmuji salted in higher salt concentrations. Among the textural properties, the crispness of danmuji salted in 5, 10 and 20% NaCl concentrations increased up to 2 days of desalting and decreased slightly thereafter, whereas that of radish salted in 15% NaCl concentration increase continously during 3 days of desalting. Total acceptibility was best in danmuji salted in 20% NaCl concentration and desalted for 3 days.

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Change in chemical composition of maturing barley kernels (보리곡립의 성숙중 이화학적 특성변화)

  • Seog, Ho-Moon;Kim, Jong-Sang;Hong, Hee-Do;Kim, Sung-Soo;Kim, Kyung-Tack
    • Applied Biological Chemistry
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    • v.36 no.6
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    • pp.449-455
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    • 1993
  • Some chemical properties were investigated for barley kernels at different growth stages. Crude fat, crude protein, starch, alcohol-insoluble solids(AIS), and ${\beta}-glucan$ increased until $31{\sim}36\;days$ from ear emergence and thereafter remained relatively constant, whereas ash and crude fiber contents were gradually decreased through the whole period of maturation. As barley kernels became mature, their water contents kept decreasing, and the content of milky stage barley kernel at $31{\sim}36th\;days$ from ear emergence ranged from $40{\sim}50%$. Free sugars including glucose, fructose, sucrose, raffinose, maltose, and kestose were identified in the growing kernels. Glucose, sucrose and kestose decreased with maturation while raffinose slightly increased. Barley kernels on the 43rd day from ear emergence contained 0.62% sucrose, 0.46% raffinose, 0.33% kestose, 0.19% glucose, 0.17% fructose, 0.04% maltose. Analysis of minerals for barley kernels at different growth stages showed that the growing kernels contained K, P, Mg, Ca, Na, Fe, Zn, Mn, Cu in decreasing order. Vitamin $B_1$ content tended to increase with kernel growth, showing maximum value of $350\;{\mu}g\;per\;100\;g$ dry weight on 36th day from ear emergence.

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Emulsifying Properties of Concentrated Red Ginseng Extract: Influence of Concentration, pH, NaCl (홍삼농축액 함유 유화액의 유화특성에 관한연구)

  • You, Kawn-Mo;Jang, Hyeon-Ho;Lee, Eui-Seok;Lee, Ki-Teak;Hong, Soon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.504-514
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    • 2017
  • This study was carried out to investigate the emulsifying properties of concentrated red ginseng extract (CRGE). First, we determined the interfacial tension of CRGE at the oil-water interface. Second, oil-in-water emulsions were prepared with CRGE and then their physicochemical properties such as fat globule size, zeta-potential, dispersion stability, and microscopic characteristics were determined. It was found that interfacial tension gradually decreased with increasing CRGE concentration, indicative of some surface activity. In emulsions, fat globule size was decreased as CRGE concentration increased, showing a critical value ($d_{43}$$0.39{\mu}m$) at ${\geq}3.5wt%$ of CRGE. In addition, pH and NaCl also influenced on fat globule sizes; they were increased in acidic conditions ($pH{\leq}3$) or in higher NaCl concentration (${\geq}0.4M$) and these results were interpreted in view of the change in zeta potentials. The dispersion stability by separation analyzer ($LUMiFuge^{(R)}$) showed that it was more stable in emulsions with higher CRGE concentration (i.e., ${\geq}3.5wt%$). In conclusion, CRGE was surface-active and it could be used as an emulsifier in preparation of food emulsions.

Study on The Thermochemical Degradation Features of Empty Fruit Bunch on The Function of Pyrolysis Temperature (반응온도에 따른 팜 부산물(empty fruit bunch)의 열화학적 분해 특성에 관한 연구)

  • Lee, Jae Hoon;Moon, Jae Gwan;Choi, In-Gyu;Choi, Joon Weon
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.3
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    • pp.350-359
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    • 2016
  • We performed fast pyrolysis of empty fruit bunch (EFB) in the range of temperature from $400{\sim}550^{\circ}C$ and 1.3 s of residence time. The effect of temperature on the yields and physicochemical properties of pyrolytic products were also studied. Elemental and component analysis of EFB showed that the large amount of potassium (ca. 8400 ppm) presents in the feedstock. Thermogravimetric analysis suggested that the potassium in the feedstock catalyzed degradation of cellulose. The yield of bio-oil increased with increasing temperature in the range of temperature from $400{\sim}500^{\circ}C$, while that of gas and biochar decreased and showed monotonous change each with increasing temperature. When the EFB was pyrolyzed at $550^{\circ}C$, the yield of bio-oil and char decreased while that of gas increased. Water content of the bio-oils obtained at different temperatures was 20~30% and their total acid number were less than 100 mg KOH/g oil. Viscosity of the bio-oils was 11 cSt (centistoke), and heating value varied from 15 to 17 MJ/kg. Using GC/MS analysis, 27 chemical compounds which were classified into two groups (cellulose-derived and lignin-derived) were identified. Remarkably the concentration of phenol was approximately 25% based on entire chemical compounds.

Physicochemical Identification Characteristics of Irradiated Brown Rice, Soybean and Sesame Seeds during Storage (방사선 조사된 현미, 대두 및 참깨의 저장기간에 따른 방사선 조사여부의 이화학적 판별 특성)

  • Lee, Jeong-Eun;Ahn, Jae-Jun;Kwon, Joong-Ho
    • Food Science and Preservation
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    • v.19 no.1
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    • pp.37-46
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    • 2012
  • The identification characteristics of irradiated (0.5, 1, 2, and 4 kGy) brown rice, soybean, and sesame seeds were investigated using photostimulated luminescence (PSL), thermoluminescence (TL), and hydrocarbon analysis during 12-month storage. PSL-based screening was possible for the irradiated soybean and sesame seed samples up to 6 and 12 months, respectively. The TL glow curve shape, intensity, and ratio enabled the clear dose-dependent discrimination of all the non-irradiated and irradiated samples. The TL intensity decreased during storage, but the TL glow curve did not change qualitatively, which provided enough information to confirm the irradiation treatment of the samples over the storage period. Radiation-induced hydrocarbons were found in all the irradiated samples even at 0.5 kGy, throughout the storage period. 8-Heptadecene ($C_{17:1}$) and 1,7-hexadecadiene ($C_{16:2}$) originated from oleic acid, and 6,9-heptadecadiene ($C_{17:2}$) and 1,7,10-hexadecatriene ($C_{16:3}$) originated from linoleic acid, can be used as radiation-induced markers in identifying irradiated brown rice, soybean, and sesame seeds.