• Title/Summary/Keyword: Photochemical effect

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Photosensitization Effect and Structure-Activity Relationship on Mutagenic Potential of Alkylating Agents by 4-(Nitrobenzyl)Pyridine (4-NBP) test (4-(Nitrobenzyl)Pyridine에 의한 알킬화합물들의 잠재적 변이원성에 대한 구조활성 및 광화학효과의 연구)

  • 김재현;엄애선;류재천
    • Environmental Mutagens and Carcinogens
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    • v.21 no.1
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    • pp.23-29
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    • 2001
  • The NBP assay was conducted to determine the photomutagenic or photocarcinogenic potential of alkylating agents. Using a 4-NBP in vitro technique, whereby photochemical treatment on CAS (Chemical Activation System) was performed to investigate the enhancement effect, 20 compounds were shown to undergo alkylating mechanisms with 4-NBP. Chemically meaningful results were obtained with different sets of 20 compounds for the alkylating activities due to the UV irradiation, demonstrating that all of the testing compounds showed increasing photoalkylating effects either in the presence or absence of CAS in comparison with previously reported data, except furoic acid and fumaric acid that showed decreasing effect in the presence of a CAS. Caffeine did not show a meaningful result either. However, these findings demonstrate the effects of potential photoalkylating activity in chemical activation system (CAS) and suggest a potential risk-ranking system for the in vivo assays.

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Effect of Dietary Grapeseed Oil on Serum Lipids in Spontaneously Hypertensive Rats (포도종자유 급여가 본태성고혈압쥐의 혈청지질 성분에 미치는 영향)

  • 최혁준
    • Journal of Nutrition and Health
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    • v.23 no.7
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    • pp.467-476
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    • 1990
  • This study was performed to investigate the effects of different fat diets on the serum lipid composition and on the morphology of liver tissue of the spontaneously hypertensive rats(SHR), Rats were fed for 17 weeks one of four fat diets, control(corn oil : beef tallow=1:1), beef tallow, grapeseed oil and soybean oil. Blood was withdrawn by heart puncture from each SHR, and used to determine the serum levels of total cholesterol, HDL-cholesterol, trigly ceride and phospholipid. No significant difference in body weight was observed in all diet groups. the total serum cholesterol was significantly lower in SHR fed grapeseed oil than that of other groups. The cholesterol lowering effect of grapeseed oil seemed to results from its high contents of phytosterol and linoleic acid. Also, serum HDL-cholesterol, triglyceride and phospholipid contents were low in all the groups. photochemical microscopic observations of the liver tissue revealed the congestion of sinosoid which is regarded as the characteristics of SHR, but no significant difference was observed among the groups.

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Estimation of Indirect Greenhouse Effect by Non-methane Volatile Organic Compounds (비메탄계 휘발성유기화합물에 의한 간접 온실효과의 산출)

  • Choi, Eun-Hwa
    • Journal of Environmental Science International
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    • v.21 no.2
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    • pp.165-179
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    • 2012
  • Indirect $CO_2$ effect due to non-methane volatile organic compound (NMVOC) emissions from solvent and product use and fugitive NMVOC emissions from fuels in the Republic of Korea and 13 Annex I countries under United Nations Framework on Climate Change were estimated and the proportions of them to total greenhouse gas (GHG) emissions ranged from 0.092% to 0.45% in 2006. Indirect greenhouse effect ($CO_2$, $CH_4$, and $O_3$) were estimated at 13 photochemical assessment monitoring sites in the Republic of Korea using concentrations of 8 NMVOCs of which indirect global warming potential (GWP) were available. The contribution of toluene to mixing ratio was highest at 11 sites and however, the contribution of toluene to indirect greenhouse effect was highest at nine sites. In contrast to toluene, the contributions of ethane, butane, and ethylene were enhanced. The indirect greenhouse effects of ethane and propane, of which ozone formation potentials are the lowest and the third lowest respectively among targeted 10 NMVOCs, ranked first and fourth highest respectively. Acetaldehyde has relatively higher maximum incremental reactivity and is classified as probable human carcinogen however, its indirect GWP ranked second lowest.

Growth and Physiological Responses of Pinus strobus to CaCl2 (염화칼슘에 의한 스트로브잣나무의 생장 및 생리반응)

  • Je, Sun-Mi;Kim, Sun-Hee
    • Journal of the Korean Institute of Landscape Architecture
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    • v.45 no.3
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    • pp.1-8
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    • 2017
  • The present study aimed to investigate the effect of calcium chloride($CaCl_2$) on the growth and physiological responses of Pinus strobus and the variables that are sensitive to $CaCl_2$. Thus, changes in the visible damage, growth of root collar diameter, plant water content, chlorophyll content and composition, maximum PS II photochemical efficiency, and electron transport rate of P. strobus was analyzed in relation to treatment witih $CaCl_2$. A $CaCl_2$ solution(0.5, 1.0 and 3.0%) was applied in the root zone before leaf unfolding. Leaf browning, defoliation, and drying were observed with $CaCl_2$ application and this pattern was aggravated as the $CaCl_2$ concentration increased and the treatment period became longer. The decrease of growth in root collar diameter and height and leaf water content were observed at $CaCl_2$ 1.0% and 3.0%. The total chlorophyll content indicated that photopigment, PS II photochemical efficiency and electron transport rate significantly decreased at $CaCl_2$ 3.0%. In conclusion, $CaCl_2$ affected leaf water content and led to a decrease of capability in light harvesting and photochemical responses. Also, as a result of the correlation between calcium chloride concentration and growth and physiological response parameters, it was found that the leaf moisture content and the ratio of chlorophyll a and b reflect the damage level of calcium chloride sensitively because their coefficient of determinations were relatively high.

Evaluation of Photochemical Reflectance Index (PRI) Response to Soybean Drought stress under Climate Change Conditions (기후변화 조건에서 콩 한발스트레스에 대한 광화학 반사 지수 반응 평가)

  • Sang, Wan-Gyu;Kim, Jun-Hwan;Shin, Pyeong;Baek, Jae-Kyeong;Lee, Yun-Ho;Cho, Jung-Il;Seo, Myung-Chul
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.21 no.4
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    • pp.261-268
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    • 2019
  • Climate change and drought stress are having profound impacts on crop growth and development by altering crop physiological processes including photosynthetic activity. But finding a rapid, efficient, and non-destructive method for estimating environmental stress responses in the leaf and canopy is still a difficult issue for remote sensing research. We compared the relationships between photochemical reflectance index(PRI) and various optical and experimental indices on soybean drought stress under climate change conditions. Canopy photosynthesis trait, biomass change, chlorophyll fluorescence(Fv/Fm), stomatal conductance showed significant correlations with midday PRI value across the drought stress period under various climate conditions. In high temperature treatment, PRI were more sensitive to enhanced drought stress, demonstrating the negative effect of the high temperature on the drought stress. But high CO2 concentration alleviated the midday depression of both photosynthesis and PRI. Although air temperature and CO2 concentration could affect PRI interpretation and assessment of canopy radiation use efficiency(RUE), PRI was significantly correlated with canopy RUE both under climate change and drought stress conditions, indicating the applicability of PRI for tracking the drought stress responses in soybean. However, it is necessary to develop an integrated model for stress diagnosis using PRI at canopy level by minimizing the influence of physical and physiological factors on PRI and incorporating the effects of other vegetation indices.

Issues and Tasks for Air Quality Management in the Greater Seoul Metropolitan Area (수도권 대기질 관리의 쟁점과 과제)

  • Ghim, Young-Sung
    • Journal of Environmental Policy
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    • v.4 no.1
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    • pp.1-19
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    • 2005
  • On January 1, 2005, the Special Act on Metropolitan Air Quality Improvement, known as the Blue Sky 21 Program, entered into force. This Special Act is aimed at reducing the annual average concentrations of $PM_{10}$ and $NO_2$ to $40{\mu}g/m^3$ and 22ppb, respectively, from their current levels of $76{\mu}g/m^3$ and 36ppb, within the next 10 years. While the main focus of the Act is to reduce $PM_{10}$ and $NO_2$ emissions, the government also anticipates that these reductions would lessen high ozone occurrences and improve visibility. However, reducing local PM emissions would not decrease $PM_{10}$ concentrations as much as expected since other significant sources, such as continental inflow and/or secondary formation from photochemical reactions, exist. This is corroborated by the fact that $PM_{10}$ in the greater Seoul Metropolitan area during the ozone season is mostly in the form of $PM_{2.5}$, which is secondarily formed on a regional scale. Furthermore, many modeling results indicate so-called '$NO_x$ disbenefits,' referring to the fostering of an increase in ozone concentrations from a decrease in $NO_x$ emissions, over an extensive area. In this paper, the current status of air quality in the Seoul Metropolitan area is reviewed, and several other issues, including the effect of long-range transport, photochemical characteristics, and tasks for successful implementation of the Special Act are discussed.

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Effect of Partial Shading by Agrivoltaic Systems Panel on Electron Transport Rate and Non-photochemical Quenching of Crop (영농형 태양광 패널의 부분 차광 생육 환경이 작물 전자전달효율과 비광화학적 형광소멸에 미치는 영향)

  • Cho, Yuna;Kim, Hyunki;Jo, Euni;Oh, Dohyeok;Jeong, Hoejeong;Yoon, Changyong;An, Kyunam;Cho, Jaeil
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.23 no.2
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    • pp.100-107
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    • 2021
  • An agrivoltaic system (AVS) is a system of innovation that comprises productions of photovoltaic power and agricultural crops on the same area. However, the decline in crop yield will be fatally occurred because the pigments of crop absorbs less light energy under AVS. In addtion, the photosynthetic capacity of crop grown under the partial shading of AVS is not well reported. In this study, the electron transport rate (ETR) and non-photochemical fluorescence quenching (NPQ) of soybean and rice under the AVS in Boseong and Naju was investigated using chlorophyll fluorescence measurement. The ETR value of soybean and rice under AVS were not significantly differed by location. It represents that the photophosphorylation rate of the crops is not critically different. It means that the decreases in total photosynthesis under AVS were mostly affected by the amount of light absorbed by leaves. Under AVS the photosynthesis of crops will be lower than field crops grown in open fields. This is because the crops under AVS observed higher NPQ, which means that the available energy cannot distribute to photophosphorylation reaction.

Photosynthetic Characteristics and a Sensitive Indicator for $O_3$-exposed Platanus orientalis (오존에 노출된 버즘나무의 광합성 특성과 민감성 지표)

  • Lee Jae-Cheon;Oh Chang-Young;Han Sim-Hee;Kim Pan-Gi
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.3
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    • pp.220-226
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    • 2005
  • We investigated the effect of $O_3$ on the photosynthetic characteristics of oriental plane (Platanus orientalis L.) that is used as a side tree or ornamental tree in Korea. Two-year-old oriental plane seedlings were transplanted to pots and transferred into a closed $O_3$ chamber, Photosynthetic pigment content and photosynthetic characteristics of leaves were measured every three weeks during 100 ppb $O_3$ fumigation. There was no visible foliar injury by $O_3$ exposure and the content of photosynthetic pigments did not show significant differences between control and $O_3$-treated seedlings. But photosynthetic rate, stomatal conductance, and water use efficiency in leaves of $O_3$-treated seedlings were reduced after six weeks of ozone fumigation. In addition, reduction of carboxylation efficiency and photochemical efficiency was observed in leaves of $O_3$-treated seedlings after three weeks and six weeks. In accordance with our results, carboxylation efficiency, the most sensitive parameter to $O_3$ stress, was considered to be a suitable indicator of $O_3$ sensitivity.

Meteorological Characteristics related to the Variation in Ozone Concentrations before, during, and after the Typhoon Period in the Korean Peninsula (한반도 태풍영향 전·중·후 시기동안 오존농도 변화에 관한 기상특성 분석)

  • Shin, Hyeonjin;Song, Sang-Keun
    • Journal of Environmental Science International
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    • v.26 no.5
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    • pp.621-638
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    • 2017
  • Meteorological characteristics related to variations in ozone ($O_3$) concentrations in the Korean peninsula before, during, and after Typhoon Talas (1112) were analyzed using both observation data and numerical modeling. This case study takes into account a high $O_3$ episode (e.g., a daily maximum of ${\geq}90ppb$) without rainfall. Before the typhoon period, high $O_3$ concentrations in the study areas (e.g., Daejeon, Daegu, and Busan) resulted from the combined effects of stable atmospheric conditions with high temperature under a migratory anticyclone (including subsiding air), and wind convergence due to a change in direction caused by the typhoon. The $O_3$ concentrations during the typhoon period decreased around the study area due to very weak photochemical activity under increased cloud cover and active vertical dispersion under a low pressure system. However, the maximum $O_3$ concentrations during this period were somewhat high (similar to those in the normal period extraneous to the typhoon), possibly because of the relatively slow photochemical loss of $O_3$ by a $H_2O+O(^1D)$ reaction resulting from the low air temperature and low relative humidity. The lowest $O_3$ concentrations during the typhoon period were relatively high compared to the period before and after the typhoon, mainly due to the transport effect resulting from the strong nocturnal winds caused by the typhoon. In addition, the $O_3$ increase observed at night in Daegu and Busan was primarily caused by local wind conditions (e.g., mountain winds) and atmospheric stagnation in the wind convergence zone around inland mountains and valleys.

Optical Sensing for Evaluating the Severity of Disease Caused by Cladosporium sp. in Barley under Warmer Conditions

  • Oh, Dohyeok;Ryu, Jae-Hyun;Oh, Sehee;Jeong, Hoejeong;Park, Jisung;Jeong, Rae-Dong;Kim, Wonsik;Cho, Jaeil
    • The Plant Pathology Journal
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    • v.34 no.3
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    • pp.236-240
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    • 2018
  • Crop yield is critically related to the physiological responses and disease resistance of the crop, which could be strongly affected by high temperature conditions. We observed the changes in the growth of barley under higher than ambient air-temperature conditions using a temperature gradient field chamber (TGFC) during winter and spring. Before the stem extension stage of barley growth, Cladosporium sp. spontaneously appeared in the TGFC. The severity of disease became serious under warmer temperature conditions. Further, the stomata closed as the severity of the disease increased; however, stomatal conductance at the initial stage of disease was higher than that of the normal leaves. This was likely due to the Iwanov effect, which explains that stressed plants rapidly and transiently open their stomata before longer-term closure. In this study, we tested three optical methods: soil-plant analysis development (SPAD) chlorophyll index, photochemical reflectance index (PRI), and maximum quantum yield (Fv/Fm). These rapid evaluation methods have not been used in studies focusing on disease stress, although some studies have used these methods to monitor other stresses. These three indicative parameters revealed that diseased barley exhibited lower values of these parameters than normal, and with the increase in disease severity, these values declined further. Our results will be useful in efficient monitoring and evaluation of crop diseases under future warming conditions.